Bis-(S-benzyl-β-N-(6-methylpyrid-2-yl)methylenedithiocarbazato) nickel(II).
The asymmetric unit of the title compound, [Ni(C15H 14N3S2)2], consists of two independent molecules with similar configurations. Each Ni2+ cation is coordinated in a cis-mode by two tridentate N,N′,S-chelating Schiff base ligands, creating a distorted octa-hedron [the smallest angle being 77.57 (7...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English English |
| Published: |
International Union of crystallography
2012
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| Online Access: | http://psasir.upm.edu.my/id/eprint/25274/1/Bis.pdf |
| _version_ | 1796970726363758592 |
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| author | Ravoof, Thahira Begum S A Omar, Siti Aminah Mohamed Tahir, Mohamed Ibrahim Crouse, Karen Anne |
| author_facet | Ravoof, Thahira Begum S A Omar, Siti Aminah Mohamed Tahir, Mohamed Ibrahim Crouse, Karen Anne |
| author_sort | Ravoof, Thahira Begum S A |
| collection | UPM |
| description | The asymmetric unit of the title compound, [Ni(C15H 14N3S2)2], consists of two independent molecules with similar configurations. Each Ni2+ cation is coordinated in a cis-mode by two tridentate N,N′,S-chelating Schiff base ligands, creating a distorted octa-hedron [the smallest angle being 77.57 (7)° and the widest being 168.97 (7)° for one molecule, and 78.04 (7) and 167.55 (7)° for the second molecule]. The dihedral angle between the mean coordination planes of the two ligands is 86.76 (7)° for one and 89.99 (7)° for the second molecule. π-π inter-actions between neighbouring pyridine rings with plane-to-plane distances of 3.540 (1) and 3.704 (1) Å are observed. |
| first_indexed | 2024-03-06T08:02:21Z |
| format | Article |
| id | upm.eprints-25274 |
| institution | Universiti Putra Malaysia |
| language | English English |
| last_indexed | 2024-03-06T08:02:21Z |
| publishDate | 2012 |
| publisher | International Union of crystallography |
| record_format | dspace |
| spelling | upm.eprints-252742015-10-30T07:14:19Z http://psasir.upm.edu.my/id/eprint/25274/ Bis-(S-benzyl-β-N-(6-methylpyrid-2-yl)methylenedithiocarbazato) nickel(II). Ravoof, Thahira Begum S A Omar, Siti Aminah Mohamed Tahir, Mohamed Ibrahim Crouse, Karen Anne The asymmetric unit of the title compound, [Ni(C15H 14N3S2)2], consists of two independent molecules with similar configurations. Each Ni2+ cation is coordinated in a cis-mode by two tridentate N,N′,S-chelating Schiff base ligands, creating a distorted octa-hedron [the smallest angle being 77.57 (7)° and the widest being 168.97 (7)° for one molecule, and 78.04 (7) and 167.55 (7)° for the second molecule]. The dihedral angle between the mean coordination planes of the two ligands is 86.76 (7)° for one and 89.99 (7)° for the second molecule. π-π inter-actions between neighbouring pyridine rings with plane-to-plane distances of 3.540 (1) and 3.704 (1) Å are observed. International Union of crystallography 2012 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/25274/1/Bis.pdf Ravoof, Thahira Begum S A and Omar, Siti Aminah and Mohamed Tahir, Mohamed Ibrahim and Crouse, Karen Anne (2012) Bis-(S-benzyl-β-N-(6-methylpyrid-2-yl)methylenedithiocarbazato) nickel(II). Acta Crystallographica Section E: Structure Reports Online, E68 (5). m664. ISSN 1600-5368 10.1107/S1600536812017333 English |
| spellingShingle | Ravoof, Thahira Begum S A Omar, Siti Aminah Mohamed Tahir, Mohamed Ibrahim Crouse, Karen Anne Bis-(S-benzyl-β-N-(6-methylpyrid-2-yl)methylenedithiocarbazato) nickel(II). |
| title | Bis-(S-benzyl-β-N-(6-methylpyrid-2-yl)methylenedithiocarbazato) nickel(II). |
| title_full | Bis-(S-benzyl-β-N-(6-methylpyrid-2-yl)methylenedithiocarbazato) nickel(II). |
| title_fullStr | Bis-(S-benzyl-β-N-(6-methylpyrid-2-yl)methylenedithiocarbazato) nickel(II). |
| title_full_unstemmed | Bis-(S-benzyl-β-N-(6-methylpyrid-2-yl)methylenedithiocarbazato) nickel(II). |
| title_short | Bis-(S-benzyl-β-N-(6-methylpyrid-2-yl)methylenedithiocarbazato) nickel(II). |
| title_sort | bis s benzyl 946 n 6 methylpyrid 2 yl methylenedithiocarbazato nickel ii |
| url | http://psasir.upm.edu.my/id/eprint/25274/1/Bis.pdf |
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