Transesterification reaction optimization and evaluation of biodiesel produced from seed oil of Colocynthis citrullus L.

This work presents Colocynthis citrullus L. (egusi) seed oil as a potential feedstock for biodiesel production. The transesterification process was optimized using response surface methodology (RSM) with three-level-three-factors face-centered central composite design employed. Catalyst (NaOH) amoun...

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Main Authors: Giwa, Solomon O., Abdullah, Luqman Chuah, Adam, Nor Mariah
Format: Article
Language:English
Published: American V - King Scientific Publishing 2014
Online Access:http://psasir.upm.edu.my/id/eprint/28870/1/Transesterification%20reaction%20optimization%20and%20evaluation%20of%20biodiesel%20produced%20from%20seed%20oil%20of%20Colocynthis%20citrullus%20L.pdf
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author Giwa, Solomon O.
Abdullah, Luqman Chuah
Adam, Nor Mariah
author_facet Giwa, Solomon O.
Abdullah, Luqman Chuah
Adam, Nor Mariah
author_sort Giwa, Solomon O.
collection UPM
description This work presents Colocynthis citrullus L. (egusi) seed oil as a potential feedstock for biodiesel production. The transesterification process was optimized using response surface methodology (RSM) with three-level-three-factors face-centered central composite design employed. Catalyst (NaOH) amount (0.25-1.8% (w/w), reaction temperature (45-65 °C) and oil-methanol molar ratio (4-10) were studied as important factors influencing the reaction. The optimum values (1:6.54 oil/methanol molar ratio, 1.22% (w/w) catalyst amount, and 65 ºC reaction temperature) predicted by the mathematical model generated using RSM gave ester yield of 84.46%, under experimental conditions. The fuel properties of egusi oil methyl ester (EOME) measured satisfied both ASTM D6751 and EN 14214 biodiesel standards with a kinematic viscosity of 3.87 mm2/s. Fatty acid profile and fuel properties of EOME were found similar to those of soybean, safflower and sunflower biodiesel.
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spelling upm.eprints-288702015-10-09T07:12:30Z http://psasir.upm.edu.my/id/eprint/28870/ Transesterification reaction optimization and evaluation of biodiesel produced from seed oil of Colocynthis citrullus L. Giwa, Solomon O. Abdullah, Luqman Chuah Adam, Nor Mariah This work presents Colocynthis citrullus L. (egusi) seed oil as a potential feedstock for biodiesel production. The transesterification process was optimized using response surface methodology (RSM) with three-level-three-factors face-centered central composite design employed. Catalyst (NaOH) amount (0.25-1.8% (w/w), reaction temperature (45-65 °C) and oil-methanol molar ratio (4-10) were studied as important factors influencing the reaction. The optimum values (1:6.54 oil/methanol molar ratio, 1.22% (w/w) catalyst amount, and 65 ºC reaction temperature) predicted by the mathematical model generated using RSM gave ester yield of 84.46%, under experimental conditions. The fuel properties of egusi oil methyl ester (EOME) measured satisfied both ASTM D6751 and EN 14214 biodiesel standards with a kinematic viscosity of 3.87 mm2/s. Fatty acid profile and fuel properties of EOME were found similar to those of soybean, safflower and sunflower biodiesel. American V - King Scientific Publishing 2014-06 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/28870/1/Transesterification%20reaction%20optimization%20and%20evaluation%20of%20biodiesel%20produced%20from%20seed%20oil%20of%20Colocynthis%20citrullus%20L.pdf Giwa, Solomon O. and Abdullah, Luqman Chuah and Adam, Nor Mariah (2014) Transesterification reaction optimization and evaluation of biodiesel produced from seed oil of Colocynthis citrullus L. Current Advances in Energy Research, 1 (1). pp. 26-34. ISSN 2374-5495; ESSN: 2374-5509 http://www.vkingpub.com/VkAdmin/Ll/LL.DE.asp?action=Paper_Information&id=175&at=Transesterification+Reaction+Optimization+and+Evaluation+of+Biodiesel+Produced+From+Seed+Oil+of+Colocynthis+Citrullus+L.&jn=Current%20Advances%20in%20Energy%20Research#sthash.
spellingShingle Giwa, Solomon O.
Abdullah, Luqman Chuah
Adam, Nor Mariah
Transesterification reaction optimization and evaluation of biodiesel produced from seed oil of Colocynthis citrullus L.
title Transesterification reaction optimization and evaluation of biodiesel produced from seed oil of Colocynthis citrullus L.
title_full Transesterification reaction optimization and evaluation of biodiesel produced from seed oil of Colocynthis citrullus L.
title_fullStr Transesterification reaction optimization and evaluation of biodiesel produced from seed oil of Colocynthis citrullus L.
title_full_unstemmed Transesterification reaction optimization and evaluation of biodiesel produced from seed oil of Colocynthis citrullus L.
title_short Transesterification reaction optimization and evaluation of biodiesel produced from seed oil of Colocynthis citrullus L.
title_sort transesterification reaction optimization and evaluation of biodiesel produced from seed oil of colocynthis citrullus l
url http://psasir.upm.edu.my/id/eprint/28870/1/Transesterification%20reaction%20optimization%20and%20evaluation%20of%20biodiesel%20produced%20from%20seed%20oil%20of%20Colocynthis%20citrullus%20L.pdf
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