Composition and source identification of polycyclic aromatic hydrocarbons in mangrove sediments of Peninsular Malaysia : indication of anthropogenic input.

This is a comprehensive study of the composition, origin and sources of specific polycyclic aromatic hydrocarbons (PAHs) in sediments of mangrove estuary in the western part of Peninsular Malaysia. Mangrove sediments were analyzed for 17 PAHs by gas chromatography–mass spectrometry. Total PAH concen...

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Main Authors: Raza, Muhammad, Zakaria, Mohamad Pauzi, Hashim, Nor Rasidah, Yim, Un Hyuk, Kannan, Narayanan, Ha, Sung Yong
Format: Article
Language:English
English
Published: Springer Verlag 2013
Online Access:http://psasir.upm.edu.my/id/eprint/28923/1/Composition%20and%20source%20identification%20of%20polycyclic%20aromatic%20hydrocarbons%20in%20mangrove%20sediments%20of%20Peninsular%20Malaysia.pdf
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author Raza, Muhammad
Zakaria, Mohamad Pauzi
Hashim, Nor Rasidah
Yim, Un Hyuk
Kannan, Narayanan
Ha, Sung Yong
author_facet Raza, Muhammad
Zakaria, Mohamad Pauzi
Hashim, Nor Rasidah
Yim, Un Hyuk
Kannan, Narayanan
Ha, Sung Yong
author_sort Raza, Muhammad
collection UPM
description This is a comprehensive study of the composition, origin and sources of specific polycyclic aromatic hydrocarbons (PAHs) in sediments of mangrove estuary in the western part of Peninsular Malaysia. Mangrove sediments were analyzed for 17 PAHs by gas chromatography–mass spectrometry. Total PAH concentrations in the sediments ranged from 20 to 112 ng/g on a dry-weight basis. High molecular weight PAHs were abundant in the sediments. Parent PAH ratios revealed that pyrogenic input has important contribution to the sedimentary PAHs. Ratios of alkylated PAHs indicate that the sedimentary PAHs were influenced by petrogenic PAHs, which implies that petrogenic input has contribution to the sedimentary PAHs but that it is not a major factor in distribution of PAHs within the estuary. Combustion-derived PAHs show a positive and very strong correlation with total PAHs (R 2 = 0.926, p < 0.05). Total methylphenanthrenes show very weak correlation with total PAHs (R 2 = 0.0928, p < 0.05). The PAH concentrations were found to increase with distance from the upstream of the estuary to the coastal area of the Straits of Malacca. For the assessment of sediment contamination using biological thresholds, none of the individual studied PAH compounds exceeded the values of the effect range low–effect range median guideline and the threshold effects level–probable effects level guideline. This study demonstrates that the sediments of the mangrove ecosystem facing the Straits of Malacca and Sumatra are influenced by anthropogenic PAH inputs as a result of human activities such as biomass burning, vehicle emissions and boating activities.
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spelling upm.eprints-289232015-10-29T08:46:01Z http://psasir.upm.edu.my/id/eprint/28923/ Composition and source identification of polycyclic aromatic hydrocarbons in mangrove sediments of Peninsular Malaysia : indication of anthropogenic input. Raza, Muhammad Zakaria, Mohamad Pauzi Hashim, Nor Rasidah Yim, Un Hyuk Kannan, Narayanan Ha, Sung Yong This is a comprehensive study of the composition, origin and sources of specific polycyclic aromatic hydrocarbons (PAHs) in sediments of mangrove estuary in the western part of Peninsular Malaysia. Mangrove sediments were analyzed for 17 PAHs by gas chromatography–mass spectrometry. Total PAH concentrations in the sediments ranged from 20 to 112 ng/g on a dry-weight basis. High molecular weight PAHs were abundant in the sediments. Parent PAH ratios revealed that pyrogenic input has important contribution to the sedimentary PAHs. Ratios of alkylated PAHs indicate that the sedimentary PAHs were influenced by petrogenic PAHs, which implies that petrogenic input has contribution to the sedimentary PAHs but that it is not a major factor in distribution of PAHs within the estuary. Combustion-derived PAHs show a positive and very strong correlation with total PAHs (R 2 = 0.926, p < 0.05). Total methylphenanthrenes show very weak correlation with total PAHs (R 2 = 0.0928, p < 0.05). The PAH concentrations were found to increase with distance from the upstream of the estuary to the coastal area of the Straits of Malacca. For the assessment of sediment contamination using biological thresholds, none of the individual studied PAH compounds exceeded the values of the effect range low–effect range median guideline and the threshold effects level–probable effects level guideline. This study demonstrates that the sediments of the mangrove ecosystem facing the Straits of Malacca and Sumatra are influenced by anthropogenic PAH inputs as a result of human activities such as biomass burning, vehicle emissions and boating activities. Springer Verlag 2013 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/28923/1/Composition%20and%20source%20identification%20of%20polycyclic%20aromatic%20hydrocarbons%20in%20mangrove%20sediments%20of%20Peninsular%20Malaysia.pdf Raza, Muhammad and Zakaria, Mohamad Pauzi and Hashim, Nor Rasidah and Yim, Un Hyuk and Kannan, Narayanan and Ha, Sung Yong (2013) Composition and source identification of polycyclic aromatic hydrocarbons in mangrove sediments of Peninsular Malaysia : indication of anthropogenic input. Environmental Earth Sciences, 70 (6). pp. 2425-2436. ISSN 1866-6280; ESSN: 1866-6299 10.1007/s12665-013-2279-1 English
spellingShingle Raza, Muhammad
Zakaria, Mohamad Pauzi
Hashim, Nor Rasidah
Yim, Un Hyuk
Kannan, Narayanan
Ha, Sung Yong
Composition and source identification of polycyclic aromatic hydrocarbons in mangrove sediments of Peninsular Malaysia : indication of anthropogenic input.
title Composition and source identification of polycyclic aromatic hydrocarbons in mangrove sediments of Peninsular Malaysia : indication of anthropogenic input.
title_full Composition and source identification of polycyclic aromatic hydrocarbons in mangrove sediments of Peninsular Malaysia : indication of anthropogenic input.
title_fullStr Composition and source identification of polycyclic aromatic hydrocarbons in mangrove sediments of Peninsular Malaysia : indication of anthropogenic input.
title_full_unstemmed Composition and source identification of polycyclic aromatic hydrocarbons in mangrove sediments of Peninsular Malaysia : indication of anthropogenic input.
title_short Composition and source identification of polycyclic aromatic hydrocarbons in mangrove sediments of Peninsular Malaysia : indication of anthropogenic input.
title_sort composition and source identification of polycyclic aromatic hydrocarbons in mangrove sediments of peninsular malaysia indication of anthropogenic input
url http://psasir.upm.edu.my/id/eprint/28923/1/Composition%20and%20source%20identification%20of%20polycyclic%20aromatic%20hydrocarbons%20in%20mangrove%20sediments%20of%20Peninsular%20Malaysia.pdf
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