Dimethylsulphoxide Complexes of Vanadium(III)
Dimethylsulphaxide(DMSO) compkxsalts of vanadium(IIl) with theemfrincalformulae VCI,. 6DMSOand VBr,. 6DMSO were synthesized and investigated. The observed infra-red band positions of the v(S.O) stretch indicate that the ligand is coordinated to ·vanadium ion via oxygen. Far-infra-l-ed spectra lead...
| Main Authors: | , |
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| Format: | Article |
| Language: | English English |
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1992
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| Online Access: | http://psasir.upm.edu.my/id/eprint/2939/1/Dimethylsulphoxide_Complexes_of_Vanadium%28III%29.pdf |
| _version_ | 1796966445148536832 |
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| author | Sirat, Kamaliah W.Smith, Peter |
| author_facet | Sirat, Kamaliah W.Smith, Peter |
| author_sort | Sirat, Kamaliah |
| collection | UPM |
| description | Dimethylsulphaxide(DMSO) compkxsalts of vanadium(IIl) with theemfrincalformulae VCI,. 6DMSOand VBr,. 6DMSO
were synthesized and investigated. The observed infra-red band positions of the v(S.O) stretch indicate that the ligand is coordinated to ·vanadium ion via oxygen. Far-infra-l-ed spectra lead to the conclusion that no-1U of the halide ions are eoen·dinated to the metal ion. Diffuse reflectance spectra are consistent with vanadium in an octahedral environment. Accordingly, the chlarideand bromide salts areformulated as [V(DMSO)jCI, and [V[DMSOljBrp respectively |
| first_indexed | 2024-03-06T06:59:40Z |
| format | Article |
| id | upm.eprints-2939 |
| institution | Universiti Putra Malaysia |
| language | English English |
| last_indexed | 2024-03-06T06:59:40Z |
| publishDate | 1992 |
| record_format | dspace |
| spelling | upm.eprints-29392013-05-27T07:04:35Z http://psasir.upm.edu.my/id/eprint/2939/ Dimethylsulphoxide Complexes of Vanadium(III) Sirat, Kamaliah W.Smith, Peter Dimethylsulphaxide(DMSO) compkxsalts of vanadium(IIl) with theemfrincalformulae VCI,. 6DMSOand VBr,. 6DMSO were synthesized and investigated. The observed infra-red band positions of the v(S.O) stretch indicate that the ligand is coordinated to ·vanadium ion via oxygen. Far-infra-l-ed spectra lead to the conclusion that no-1U of the halide ions are eoen·dinated to the metal ion. Diffuse reflectance spectra are consistent with vanadium in an octahedral environment. Accordingly, the chlarideand bromide salts areformulated as [V(DMSO)jCI, and [V[DMSOljBrp respectively 1992 Article NonPeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/2939/1/Dimethylsulphoxide_Complexes_of_Vanadium%28III%29.pdf Sirat, Kamaliah and W.Smith, Peter (1992) Dimethylsulphoxide Complexes of Vanadium(III). Pertanika, 15 (2). pp. 137-142. English |
| spellingShingle | Sirat, Kamaliah W.Smith, Peter Dimethylsulphoxide Complexes of Vanadium(III) |
| title | Dimethylsulphoxide Complexes of Vanadium(III) |
| title_full | Dimethylsulphoxide Complexes of Vanadium(III) |
| title_fullStr | Dimethylsulphoxide Complexes of Vanadium(III) |
| title_full_unstemmed | Dimethylsulphoxide Complexes of Vanadium(III) |
| title_short | Dimethylsulphoxide Complexes of Vanadium(III) |
| title_sort | dimethylsulphoxide complexes of vanadium iii |
| url | http://psasir.upm.edu.my/id/eprint/2939/1/Dimethylsulphoxide_Complexes_of_Vanadium%28III%29.pdf |
| work_keys_str_mv | AT siratkamaliah dimethylsulphoxidecomplexesofvanadiumiii AT wsmithpeter dimethylsulphoxidecomplexesofvanadiumiii |