(Pyridin-4-yl)methyl N′-(3-phenylallylidene)hydrazinecarbodithioate.
In the title compound, C16H15N3S2, the central C2N2S2 residue is planar (r.m.s. deviation = 0.045 Å) and the pyridyl and benzene rings are inclined and approximately coplanar to this plane, respectively [dihedral angles = 72.85 (9) and 10.73 (9)°], so that, overall, the molecule adopts an L-shape....
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English English |
| Published: |
International Union of Crystallography
2013
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| Online Access: | http://psasir.upm.edu.my/id/eprint/29999/1/Pyridin.pdf |
| _version_ | 1825947620708712448 |
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| author | Low, May Lee S. A. Ravoof, Thahira Begum Mohamed Tahir, Mohamed Ibrahim Crouse, Karen Anne Tiekink, Edward R. T. |
| author_facet | Low, May Lee S. A. Ravoof, Thahira Begum Mohamed Tahir, Mohamed Ibrahim Crouse, Karen Anne Tiekink, Edward R. T. |
| author_sort | Low, May Lee |
| collection | UPM |
| description | In the title compound, C16H15N3S2, the central C2N2S2 residue is planar (r.m.s. deviation = 0.045 Å) and the pyridyl and benzene rings are inclined and approximately coplanar to this plane, respectively [dihedral angles = 72.85 (9) and 10.73 (9)°], so that, overall, the molecule adopts an L-shape. The conformation about each of the N=C [1.290 (3) Å] and C=C [1.340 (3) Å] bonds is E. Supramolecular chains along [1-10] are stabilized by N—H(...)N(pyridine) hydrogen bonding and these are connected into a double layer that stacks along the c-axis direction by C—H(...)π(pyridine) interactions. |
| first_indexed | 2024-03-06T08:16:11Z |
| format | Article |
| id | upm.eprints-29999 |
| institution | Universiti Putra Malaysia |
| language | English English |
| last_indexed | 2024-03-06T08:16:11Z |
| publishDate | 2013 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | upm.eprints-299992015-10-01T08:33:14Z http://psasir.upm.edu.my/id/eprint/29999/ (Pyridin-4-yl)methyl N′-(3-phenylallylidene)hydrazinecarbodithioate. Low, May Lee S. A. Ravoof, Thahira Begum Mohamed Tahir, Mohamed Ibrahim Crouse, Karen Anne Tiekink, Edward R. T. In the title compound, C16H15N3S2, the central C2N2S2 residue is planar (r.m.s. deviation = 0.045 Å) and the pyridyl and benzene rings are inclined and approximately coplanar to this plane, respectively [dihedral angles = 72.85 (9) and 10.73 (9)°], so that, overall, the molecule adopts an L-shape. The conformation about each of the N=C [1.290 (3) Å] and C=C [1.340 (3) Å] bonds is E. Supramolecular chains along [1-10] are stabilized by N—H(...)N(pyridine) hydrogen bonding and these are connected into a double layer that stacks along the c-axis direction by C—H(...)π(pyridine) interactions. International Union of Crystallography 2013 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/29999/1/Pyridin.pdf Low, May Lee and S. A. Ravoof, Thahira Begum and Mohamed Tahir, Mohamed Ibrahim and Crouse, Karen Anne and Tiekink, Edward R. T. (2013) (Pyridin-4-yl)methyl N′-(3-phenylallylidene)hydrazinecarbodithioate. Acta Crystallographica Section E: Structure Reports Online, 69 (pt.2). pp. 167-168. ISSN 1600-5368 10.1107/S1600536812051537 English |
| spellingShingle | Low, May Lee S. A. Ravoof, Thahira Begum Mohamed Tahir, Mohamed Ibrahim Crouse, Karen Anne Tiekink, Edward R. T. (Pyridin-4-yl)methyl N′-(3-phenylallylidene)hydrazinecarbodithioate. |
| title | (Pyridin-4-yl)methyl N′-(3-phenylallylidene)hydrazinecarbodithioate. |
| title_full | (Pyridin-4-yl)methyl N′-(3-phenylallylidene)hydrazinecarbodithioate. |
| title_fullStr | (Pyridin-4-yl)methyl N′-(3-phenylallylidene)hydrazinecarbodithioate. |
| title_full_unstemmed | (Pyridin-4-yl)methyl N′-(3-phenylallylidene)hydrazinecarbodithioate. |
| title_short | (Pyridin-4-yl)methyl N′-(3-phenylallylidene)hydrazinecarbodithioate. |
| title_sort | pyridin 4 yl methyl n 3 phenylallylidene hydrazinecarbodithio ate |
| url | http://psasir.upm.edu.my/id/eprint/29999/1/Pyridin.pdf |
| work_keys_str_mv | AT lowmaylee pyridin4ylmethyln3phenylallylidenehydrazinecarbodithioate AT saravoofthahirabegum pyridin4ylmethyln3phenylallylidenehydrazinecarbodithioate AT mohamedtahirmohamedibrahim pyridin4ylmethyln3phenylallylidenehydrazinecarbodithioate AT crousekarenanne pyridin4ylmethyln3phenylallylidenehydrazinecarbodithioate AT tiekinkedwardrt pyridin4ylmethyln3phenylallylidenehydrazinecarbodithioate |