Bis{(Z)-[(E)-2-(pyridin-2-ylmethylidene)hydrazin-1-ylidene][(pyridin-2-yl) methylsulfanyl]methanethiolato}nickel(II)
The title compound, [Ni(C13H11N4S 2)2], was obtained by the reaction of S-2- picolyldithiocarbazate and pyridine-2-carbaldehyde with nickel(II) acetate. The NiII atom is located on a twofold rotation axis and is bonded to four N atoms at distances of 2.037 (8) and 2.109 (9) Å, and to two S atoms at...
| Main Authors: | , , , , , |
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| Format: | Article |
| Language: | English English |
| Published: |
International Union of Crystallography
2013
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| Online Access: | http://psasir.upm.edu.my/id/eprint/30096/1/Bis.pdf |
| _version_ | 1825947639857807360 |
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| author | Khoo, Teng Jin Break, Mohammed Khaled Mohamed Tahir, Mohamed Ibrahim Crouse, Karen Anne Cowley, Andrew R. Watkin, David J. |
| author_facet | Khoo, Teng Jin Break, Mohammed Khaled Mohamed Tahir, Mohamed Ibrahim Crouse, Karen Anne Cowley, Andrew R. Watkin, David J. |
| author_sort | Khoo, Teng Jin |
| collection | UPM |
| description | The title compound, [Ni(C13H11N4S 2)2], was obtained by the reaction of S-2- picolyldithiocarbazate and pyridine-2-carbaldehyde with nickel(II) acetate. The NiII atom is located on a twofold rotation axis and is bonded to four N atoms at distances of 2.037 (8) and 2.109 (9) Å, and to two S atoms at a distance of 2.406 (3) Å, leading to a distorted octahedral coordination. The angle between the mean planes of the coordinating moieties of the two symmetry-related tridentate ligands is 83.3 (2)°. In the crystal, complex molecules are linked by weak C - H⋯S hydrogen bonds, π-π interactions between the pyridine rings [centroid-centroid distance = 3.775 (9) Å] and C - H⋯π interactions. The hydrogen-bonding interactions lead to the formation of layers parallel to (010); π-π interactions link these layers into a three-dimensional network. |
| first_indexed | 2024-03-06T08:16:29Z |
| format | Article |
| id | upm.eprints-30096 |
| institution | Universiti Putra Malaysia |
| language | English English |
| last_indexed | 2024-03-06T08:16:29Z |
| publishDate | 2013 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | upm.eprints-300962015-09-18T02:13:31Z http://psasir.upm.edu.my/id/eprint/30096/ Bis{(Z)-[(E)-2-(pyridin-2-ylmethylidene)hydrazin-1-ylidene][(pyridin-2-yl) methylsulfanyl]methanethiolato}nickel(II) Khoo, Teng Jin Break, Mohammed Khaled Mohamed Tahir, Mohamed Ibrahim Crouse, Karen Anne Cowley, Andrew R. Watkin, David J. The title compound, [Ni(C13H11N4S 2)2], was obtained by the reaction of S-2- picolyldithiocarbazate and pyridine-2-carbaldehyde with nickel(II) acetate. The NiII atom is located on a twofold rotation axis and is bonded to four N atoms at distances of 2.037 (8) and 2.109 (9) Å, and to two S atoms at a distance of 2.406 (3) Å, leading to a distorted octahedral coordination. The angle between the mean planes of the coordinating moieties of the two symmetry-related tridentate ligands is 83.3 (2)°. In the crystal, complex molecules are linked by weak C - H⋯S hydrogen bonds, π-π interactions between the pyridine rings [centroid-centroid distance = 3.775 (9) Å] and C - H⋯π interactions. The hydrogen-bonding interactions lead to the formation of layers parallel to (010); π-π interactions link these layers into a three-dimensional network. International Union of Crystallography 2013 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/30096/1/Bis.pdf Khoo, Teng Jin and Break, Mohammed Khaled and Mohamed Tahir, Mohamed Ibrahim and Crouse, Karen Anne and Cowley, Andrew R. and Watkin, David J. (2013) Bis{(Z)-[(E)-2-(pyridin-2-ylmethylidene)hydrazin-1-ylidene][(pyridin-2-yl) methylsulfanyl]methanethiolato}nickel(II). Acta Crystallographica Section E: Structure Reports Online, 69 (pt.6). m323-m324. ISSN 1600-5368 10.1107/S1600536813013032 English |
| spellingShingle | Khoo, Teng Jin Break, Mohammed Khaled Mohamed Tahir, Mohamed Ibrahim Crouse, Karen Anne Cowley, Andrew R. Watkin, David J. Bis{(Z)-[(E)-2-(pyridin-2-ylmethylidene)hydrazin-1-ylidene][(pyridin-2-yl) methylsulfanyl]methanethiolato}nickel(II) |
| title | Bis{(Z)-[(E)-2-(pyridin-2-ylmethylidene)hydrazin-1-ylidene][(pyridin-2-yl) methylsulfanyl]methanethiolato}nickel(II) |
| title_full | Bis{(Z)-[(E)-2-(pyridin-2-ylmethylidene)hydrazin-1-ylidene][(pyridin-2-yl) methylsulfanyl]methanethiolato}nickel(II) |
| title_fullStr | Bis{(Z)-[(E)-2-(pyridin-2-ylmethylidene)hydrazin-1-ylidene][(pyridin-2-yl) methylsulfanyl]methanethiolato}nickel(II) |
| title_full_unstemmed | Bis{(Z)-[(E)-2-(pyridin-2-ylmethylidene)hydrazin-1-ylidene][(pyridin-2-yl) methylsulfanyl]methanethiolato}nickel(II) |
| title_short | Bis{(Z)-[(E)-2-(pyridin-2-ylmethylidene)hydrazin-1-ylidene][(pyridin-2-yl) methylsulfanyl]methanethiolato}nickel(II) |
| title_sort | bis z e 2 pyridin 2 ylmethylidene hydrazin 1 ylidene pyridin 2 yl methylsulfanyl methanethiolato nickel ii |
| url | http://psasir.upm.edu.my/id/eprint/30096/1/Bis.pdf |
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