Synthesis and characterization of ZnO flower-like multisheets grown on metal buffer layer

ZnO flower-like multisheets were synthesized on Si (1 1 1) and corning glass substrates with Cu and Au-Cu alloy buffer layers via vapor phase transport (VPT) method. The structures and morphologies of the products were investigated using X-ray diffraction (XRD) and field emission scanning electr...

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Main Authors: Kamalianfar, Ahmad, Abdul Halim, Shaari, Naseri, Mahmoud Goodarz, Navasery, Manizheh, Ud Din, Fasih, Zahedi, J. A. M., Lim, Kean Pah, Saion, Elias, Chen, Soo Kien, Monfared, A. Lavari
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Published: Electrochemical Science Group 2013
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author Kamalianfar, Ahmad
Abdul Halim, Shaari
Naseri, Mahmoud Goodarz
Navasery, Manizheh
Ud Din, Fasih
Zahedi, J. A. M.
Lim, Kean Pah
Saion, Elias
Chen, Soo Kien
Monfared, A. Lavari
author_facet Kamalianfar, Ahmad
Abdul Halim, Shaari
Naseri, Mahmoud Goodarz
Navasery, Manizheh
Ud Din, Fasih
Zahedi, J. A. M.
Lim, Kean Pah
Saion, Elias
Chen, Soo Kien
Monfared, A. Lavari
author_sort Kamalianfar, Ahmad
collection UPM
description ZnO flower-like multisheets were synthesized on Si (1 1 1) and corning glass substrates with Cu and Au-Cu alloy buffer layers via vapor phase transport (VPT) method. The structures and morphologies of the products were investigated using X-ray diffraction (XRD) and field emission scanning electron microscopy (FESEM). The flowers have several parallel petal-like nanosheets that are perpendicular to the main axis. The metal buffer layer affects the growth rates and initial nucleation of ZnO structures, resulting in different numbers and shapes of petals. The optical properties were studied with photoluminescence (PL) and Raman spectroscopy. The intensity of the visible emission peak for Cu coated silicon was the lowest, which may indicate that the surface of defects being covered with Cu atoms. The presence of the E1(LO) and A1(LO) phonon peaks in the Raman spectra reveal the status of c-axis and the surface of the samples. In addition, the growth mechanism of the ZnO flower-like multisheet structure was investigated based on the FESEM images for different growth times.
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spelling upm.eprints-304042014-11-14T04:10:42Z http://psasir.upm.edu.my/id/eprint/30404/ Synthesis and characterization of ZnO flower-like multisheets grown on metal buffer layer Kamalianfar, Ahmad Abdul Halim, Shaari Naseri, Mahmoud Goodarz Navasery, Manizheh Ud Din, Fasih Zahedi, J. A. M. Lim, Kean Pah Saion, Elias Chen, Soo Kien Monfared, A. Lavari ZnO flower-like multisheets were synthesized on Si (1 1 1) and corning glass substrates with Cu and Au-Cu alloy buffer layers via vapor phase transport (VPT) method. The structures and morphologies of the products were investigated using X-ray diffraction (XRD) and field emission scanning electron microscopy (FESEM). The flowers have several parallel petal-like nanosheets that are perpendicular to the main axis. The metal buffer layer affects the growth rates and initial nucleation of ZnO structures, resulting in different numbers and shapes of petals. The optical properties were studied with photoluminescence (PL) and Raman spectroscopy. The intensity of the visible emission peak for Cu coated silicon was the lowest, which may indicate that the surface of defects being covered with Cu atoms. The presence of the E1(LO) and A1(LO) phonon peaks in the Raman spectra reveal the status of c-axis and the surface of the samples. In addition, the growth mechanism of the ZnO flower-like multisheet structure was investigated based on the FESEM images for different growth times. Electrochemical Science Group 2013 Article PeerReviewed Kamalianfar, Ahmad and Abdul Halim, Shaari and Naseri, Mahmoud Goodarz and Navasery, Manizheh and Ud Din, Fasih and Zahedi, J. A. M. and Lim, Kean Pah and Saion, Elias and Chen, Soo Kien and Monfared, A. Lavari (2013) Synthesis and characterization of ZnO flower-like multisheets grown on metal buffer layer. International Journal of Electrochemical Science, 8 (6). 7724 - 7733. ISSN 1452-3981 http://www.electrochemsci.org/list13.htm#issue6
spellingShingle Kamalianfar, Ahmad
Abdul Halim, Shaari
Naseri, Mahmoud Goodarz
Navasery, Manizheh
Ud Din, Fasih
Zahedi, J. A. M.
Lim, Kean Pah
Saion, Elias
Chen, Soo Kien
Monfared, A. Lavari
Synthesis and characterization of ZnO flower-like multisheets grown on metal buffer layer
title Synthesis and characterization of ZnO flower-like multisheets grown on metal buffer layer
title_full Synthesis and characterization of ZnO flower-like multisheets grown on metal buffer layer
title_fullStr Synthesis and characterization of ZnO flower-like multisheets grown on metal buffer layer
title_full_unstemmed Synthesis and characterization of ZnO flower-like multisheets grown on metal buffer layer
title_short Synthesis and characterization of ZnO flower-like multisheets grown on metal buffer layer
title_sort synthesis and characterization of zno flower like multisheets grown on metal buffer layer
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