Adsorption of cadmium (II) ions from aqueous solution using palm oil fly ash (POFA)

The aim of this study is to conduct comprehensive studies of Cd (II) ions removal using a low-cost locally available adsorbent which is from agricultural waste. Batch adsorption experiments were conducted for the adsorption of Cd (II) ions from aqueous solution using palm oil fly ash (POFA). The par...

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Main Authors: Abdul Aziz, Abdul Shukor, Abd Manaf, Latifah, Che Man, Hasfalina, Hamdan, Mas Ernawati
Format: Conference or Workshop Item
Language:English
Published: Faculty of Engineering, Universiti Putra Malaysia 2012
Online Access:http://psasir.upm.edu.my/id/eprint/31954/1/31954.pdf
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author Abdul Aziz, Abdul Shukor
Abd Manaf, Latifah
Che Man, Hasfalina
Hamdan, Mas Ernawati
author_facet Abdul Aziz, Abdul Shukor
Abd Manaf, Latifah
Che Man, Hasfalina
Hamdan, Mas Ernawati
author_sort Abdul Aziz, Abdul Shukor
collection UPM
description The aim of this study is to conduct comprehensive studies of Cd (II) ions removal using a low-cost locally available adsorbent which is from agricultural waste. Batch adsorption experiments were conducted for the adsorption of Cd (II) ions from aqueous solution using palm oil fly ash (POFA). The parameters studied include contact time, pH, adsorbent dosage and adsorbate initial concentration. The results showed that the adsorption of Cd (II) ions was very fast initially and equilibration time was achieved after 210 min of contact time. The optimum pH was obtained at pH 9.0. High pH (≥ 9.0) favours the adsorption and removal of Cd (II) ions from aqueous solution. As the adsorbent dosage increased, the removal of Cd increased, whereas the adsorption capacity decreased. Higher initial concentration led to lower removal percentages but higher adsorption capacity. The adsorption behavior of Cd (II) ions fitted Langmuir and Freundlich isotherms well, but followed Langmuir isotherm more precisely, with a maximum adsorption capacity and R2 value of 15.823 mg/g and 1.0 respectively. The applicability of Langmuir isotherm suggested the formation of monolayer coverage of Cd (II) ions at the outer surface of the adsorbent. Therefore, this study demonstrated that POFA could be used successfully for adsorption of Cd (II) ions from aqueous solution.
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spelling upm.eprints-319542017-02-02T01:27:16Z http://psasir.upm.edu.my/id/eprint/31954/ Adsorption of cadmium (II) ions from aqueous solution using palm oil fly ash (POFA) Abdul Aziz, Abdul Shukor Abd Manaf, Latifah Che Man, Hasfalina Hamdan, Mas Ernawati The aim of this study is to conduct comprehensive studies of Cd (II) ions removal using a low-cost locally available adsorbent which is from agricultural waste. Batch adsorption experiments were conducted for the adsorption of Cd (II) ions from aqueous solution using palm oil fly ash (POFA). The parameters studied include contact time, pH, adsorbent dosage and adsorbate initial concentration. The results showed that the adsorption of Cd (II) ions was very fast initially and equilibration time was achieved after 210 min of contact time. The optimum pH was obtained at pH 9.0. High pH (≥ 9.0) favours the adsorption and removal of Cd (II) ions from aqueous solution. As the adsorbent dosage increased, the removal of Cd increased, whereas the adsorption capacity decreased. Higher initial concentration led to lower removal percentages but higher adsorption capacity. The adsorption behavior of Cd (II) ions fitted Langmuir and Freundlich isotherms well, but followed Langmuir isotherm more precisely, with a maximum adsorption capacity and R2 value of 15.823 mg/g and 1.0 respectively. The applicability of Langmuir isotherm suggested the formation of monolayer coverage of Cd (II) ions at the outer surface of the adsorbent. Therefore, this study demonstrated that POFA could be used successfully for adsorption of Cd (II) ions from aqueous solution. Faculty of Engineering, Universiti Putra Malaysia 2012 Conference or Workshop Item NonPeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/31954/1/31954.pdf Abdul Aziz, Abdul Shukor and Abd Manaf, Latifah and Che Man, Hasfalina and Hamdan, Mas Ernawati (2012) Adsorption of cadmium (II) ions from aqueous solution using palm oil fly ash (POFA). In: International Conference on Agricultural and Food Engineering for Life (Cafei2012), 26-28 Nov. 2012, Palm Garden Hotel, Putrajaya. (pp. 295-303). http://cafei.upm.edu.my/download.php?filename=/TechnicalPapers/CAFEi2012_99.pdf
spellingShingle Abdul Aziz, Abdul Shukor
Abd Manaf, Latifah
Che Man, Hasfalina
Hamdan, Mas Ernawati
Adsorption of cadmium (II) ions from aqueous solution using palm oil fly ash (POFA)
title Adsorption of cadmium (II) ions from aqueous solution using palm oil fly ash (POFA)
title_full Adsorption of cadmium (II) ions from aqueous solution using palm oil fly ash (POFA)
title_fullStr Adsorption of cadmium (II) ions from aqueous solution using palm oil fly ash (POFA)
title_full_unstemmed Adsorption of cadmium (II) ions from aqueous solution using palm oil fly ash (POFA)
title_short Adsorption of cadmium (II) ions from aqueous solution using palm oil fly ash (POFA)
title_sort adsorption of cadmium ii ions from aqueous solution using palm oil fly ash pofa
url http://psasir.upm.edu.my/id/eprint/31954/1/31954.pdf
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