Thermochemical measurement of the ligand field splitting energies for hexaaquocopper (II) and hexaamminecopper (II) ions
The vacuum dehydration of copper (II) sulphate pentahydrate has been shown to pass through the transitory tryhydrate state before proceeding to the monohydrate composition. Based on this, the heat of solution data for the high-energy modification hydrates have been reinterpreted and the low-energy c...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
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N R C Research Press
1979
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| Online Access: | http://psasir.upm.edu.my/id/eprint/33808/1/33808%20thermochemical.pdf |
| _version_ | 1825948333852590080 |
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| author | Muhammad Badri, Jamieson, James W. S. |
| author_facet | Muhammad Badri, Jamieson, James W. S. |
| author_sort | Muhammad Badri, |
| collection | UPM |
| description | The vacuum dehydration of copper (II) sulphate pentahydrate has been shown to pass through the transitory tryhydrate state before proceeding to the monohydrate composition. Based on this, the heat of solution data for the high-energy modification hydrates have been reinterpreted and the low-energy crystalline hydrates of various compositions have been prepared and their heats of solution measured. From the heat of solution data the maximum energy difference expressed in kcal/mol heptahydrate appears to be of the right order of magnitude to be regarded as the ligand field splitting energy for the hexaaquocopper (II) ion. Similar measurement for the ammine complexes of copper (II) sulphate has also been done and the maximum energy difference was found to agree well with the value of LFSE obtained by spectroscopic method. |
| first_indexed | 2024-03-06T08:27:13Z |
| format | Article |
| id | upm.eprints-33808 |
| institution | Universiti Putra Malaysia |
| language | English |
| last_indexed | 2024-03-06T08:27:13Z |
| publishDate | 1979 |
| publisher | N R C Research Press |
| record_format | dspace |
| spelling | upm.eprints-338082015-04-13T01:23:57Z http://psasir.upm.edu.my/id/eprint/33808/ Thermochemical measurement of the ligand field splitting energies for hexaaquocopper (II) and hexaamminecopper (II) ions Muhammad Badri, Jamieson, James W. S. The vacuum dehydration of copper (II) sulphate pentahydrate has been shown to pass through the transitory tryhydrate state before proceeding to the monohydrate composition. Based on this, the heat of solution data for the high-energy modification hydrates have been reinterpreted and the low-energy crystalline hydrates of various compositions have been prepared and their heats of solution measured. From the heat of solution data the maximum energy difference expressed in kcal/mol heptahydrate appears to be of the right order of magnitude to be regarded as the ligand field splitting energy for the hexaaquocopper (II) ion. Similar measurement for the ammine complexes of copper (II) sulphate has also been done and the maximum energy difference was found to agree well with the value of LFSE obtained by spectroscopic method. N R C Research Press 1979 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/33808/1/33808%20thermochemical.pdf Muhammad Badri, and Jamieson, James W. S. (1979) Thermochemical measurement of the ligand field splitting energies for hexaaquocopper (II) and hexaamminecopper (II) ions. Canadian Journal of Chemistry, 57 (15). pp. 1926-1931. ISSN 0008-4042; ESSN: 1480-3291 http://www.nrcresearchpress.com/doi/abs/10.1139/v79-309 10.1139/v79-309 |
| spellingShingle | Muhammad Badri, Jamieson, James W. S. Thermochemical measurement of the ligand field splitting energies for hexaaquocopper (II) and hexaamminecopper (II) ions |
| title | Thermochemical measurement of the ligand field splitting energies for hexaaquocopper (II) and hexaamminecopper (II) ions |
| title_full | Thermochemical measurement of the ligand field splitting energies for hexaaquocopper (II) and hexaamminecopper (II) ions |
| title_fullStr | Thermochemical measurement of the ligand field splitting energies for hexaaquocopper (II) and hexaamminecopper (II) ions |
| title_full_unstemmed | Thermochemical measurement of the ligand field splitting energies for hexaaquocopper (II) and hexaamminecopper (II) ions |
| title_short | Thermochemical measurement of the ligand field splitting energies for hexaaquocopper (II) and hexaamminecopper (II) ions |
| title_sort | thermochemical measurement of the ligand field splitting energies for hexaaquocopper ii and hexaamminecopper ii ions |
| url | http://psasir.upm.edu.my/id/eprint/33808/1/33808%20thermochemical.pdf |
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