Infrared absorption spectra of a series of 2, 6-diamino and 2-amino-6hydroxy-8-choroalkyl purines

8-haloalky purines were synthesized and infrared analysis (IR) carried out on them. The syntheses as well as the ill analyses are reported. The purines synthesized and studied include (i) 2,6-diamin-8-Chloromethyl purines, (ii) 2, 6-diamin-8-chlorethyl purine, (iii) 2, 6-diamino-8-chlor$'opyl...

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Main Author: I. M., Ejimadu
Format: Article
Language:English
Published: Universiti Putra Malaysia Press 2003
Online Access:http://psasir.upm.edu.my/id/eprint/3445/1/Infrared_Absorption_Spectra_of_a_Series_of_2%2C_6-diamino.pdf
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author I. M., Ejimadu
author_facet I. M., Ejimadu
author_sort I. M., Ejimadu
collection UPM
description 8-haloalky purines were synthesized and infrared analysis (IR) carried out on them. The syntheses as well as the ill analyses are reported. The purines synthesized and studied include (i) 2,6-diamin-8-Chloromethyl purines, (ii) 2, 6-diamin-8-chlorethyl purine, (iii) 2, 6-diamino-8-chlor$'opyl purine, (iv) 2-amin~6-hydroxyl-8-chloroethyl purine, (v) 2-amin-6-hydroxyl 8-(3-chlor$'opyl) purine. The ultra violet UV lmax absorption oj these purines were taken at /11 and results are presented. The melting points and their elemental analyses are also presented. The IR (infrared in KBr) spectra of C-8 substituted 2, 6-diamino; 2. or 2-amino -6hydroxy purines, 6 are compared to the IR spectra of pteridines 2; E.; benzimidazole, 2; Pyrroles, 10; indole, 11 (Tables I, II, III and figures 1, 2, 3, 5 and 6). Figure 4 is presented to relate these novel purines to (i) natural liver L. casei Jactor (A) (ii) synthetic liver L. cacei factor (Racemic pteroylgutamic acid (C) (v) Synthetic racemic liver L. casei factor, racemic pteraylglutamic acid (D) (iv) Natural racemic liver L. casei factor pteroic acid (E).
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spelling upm.eprints-34452015-09-11T01:14:08Z http://psasir.upm.edu.my/id/eprint/3445/ Infrared absorption spectra of a series of 2, 6-diamino and 2-amino-6hydroxy-8-choroalkyl purines I. M., Ejimadu 8-haloalky purines were synthesized and infrared analysis (IR) carried out on them. The syntheses as well as the ill analyses are reported. The purines synthesized and studied include (i) 2,6-diamin-8-Chloromethyl purines, (ii) 2, 6-diamin-8-chlorethyl purine, (iii) 2, 6-diamino-8-chlor$'opyl purine, (iv) 2-amin~6-hydroxyl-8-chloroethyl purine, (v) 2-amin-6-hydroxyl 8-(3-chlor$'opyl) purine. The ultra violet UV lmax absorption oj these purines were taken at /11 and results are presented. The melting points and their elemental analyses are also presented. The IR (infrared in KBr) spectra of C-8 substituted 2, 6-diamino; 2. or 2-amino -6hydroxy purines, 6 are compared to the IR spectra of pteridines 2; E.; benzimidazole, 2; Pyrroles, 10; indole, 11 (Tables I, II, III and figures 1, 2, 3, 5 and 6). Figure 4 is presented to relate these novel purines to (i) natural liver L. casei Jactor (A) (ii) synthetic liver L. cacei factor (Racemic pteroylgutamic acid (C) (v) Synthetic racemic liver L. casei factor, racemic pteraylglutamic acid (D) (iv) Natural racemic liver L. casei factor pteroic acid (E). Universiti Putra Malaysia Press 2003 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/3445/1/Infrared_Absorption_Spectra_of_a_Series_of_2%2C_6-diamino.pdf I. M., Ejimadu (2003) Infrared absorption spectra of a series of 2, 6-diamino and 2-amino-6hydroxy-8-choroalkyl purines. Pertanika Journal of Tropical Agricultural Science, 26 (2). pp. 131-138. ISSN 1511-3701 http://www.pertanika.upm.edu.my/Pertanika%20PAPERS/JTAS%20Vol.%2026%20(2)%20Sep.%202003/09%20JTAS%20Vol.26%20(2)%202003%20(Pg%20131-138).pdf
spellingShingle I. M., Ejimadu
Infrared absorption spectra of a series of 2, 6-diamino and 2-amino-6hydroxy-8-choroalkyl purines
title Infrared absorption spectra of a series of 2, 6-diamino and 2-amino-6hydroxy-8-choroalkyl purines
title_full Infrared absorption spectra of a series of 2, 6-diamino and 2-amino-6hydroxy-8-choroalkyl purines
title_fullStr Infrared absorption spectra of a series of 2, 6-diamino and 2-amino-6hydroxy-8-choroalkyl purines
title_full_unstemmed Infrared absorption spectra of a series of 2, 6-diamino and 2-amino-6hydroxy-8-choroalkyl purines
title_short Infrared absorption spectra of a series of 2, 6-diamino and 2-amino-6hydroxy-8-choroalkyl purines
title_sort infrared absorption spectra of a series of 2 6 diamino and 2 amino 6hydroxy 8 choroalkyl purines
url http://psasir.upm.edu.my/id/eprint/3445/1/Infrared_Absorption_Spectra_of_a_Series_of_2%2C_6-diamino.pdf
work_keys_str_mv AT imejimadu infraredabsorptionspectraofaseriesof26diaminoand2amino6hydroxy8choroalkylpurines