Polarizability and optical basicity of Er3+ ions doped tellurite based glasses

The refractive indices (n) and densities (ρ) of {[ (TeO2)0.70 (B2O3)0.30]1-x (ZnO)x}1-y (Er3O2)y glasses with y = 0.00, y = 0.005, y = 0.01, y = 0.02, y = 0.03, y = 0.04, y = 0.05 were measured at room temperature. The theoretical value of average electronic polarizabilty and oxide ion polarizabilit...

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Main Authors: Abd Azis, Muhammad Noorazlan, Mohamed Kamari, Halimah, Zulkefly, Siti Shafinas, Wan Yusoff, Wan Mohamad Daud
Format: Article
Language:English
Published: National Institute of Materials Physics, National Institute of Optoelectronics 2014
Online Access:http://psasir.upm.edu.my/id/eprint/34949/1/Polarizability%20and%20optical%20basicity%20of%20Er3%2B%20ions%20doped%20tellurite%20based%20glasses.pdf
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author Abd Azis, Muhammad Noorazlan
Mohamed Kamari, Halimah
Zulkefly, Siti Shafinas
Wan Yusoff, Wan Mohamad Daud
author_facet Abd Azis, Muhammad Noorazlan
Mohamed Kamari, Halimah
Zulkefly, Siti Shafinas
Wan Yusoff, Wan Mohamad Daud
author_sort Abd Azis, Muhammad Noorazlan
collection UPM
description The refractive indices (n) and densities (ρ) of {[ (TeO2)0.70 (B2O3)0.30]1-x (ZnO)x}1-y (Er3O2)y glasses with y = 0.00, y = 0.005, y = 0.01, y = 0.02, y = 0.03, y = 0.04, y = 0.05 were measured at room temperature. The theoretical value of average electronic polarizabilty and oxide ion polarizability were calculated by using Lorentz-Lorenz equation on the basis of refractive index and band gap energy. The value of electronic polarizability and oxide ion polarizability is found to be increased with increasing refractive index and decreasing band gap energy. The optical basicity was measured on the basis of oxide ion polarizability and calculated from refractive index and band gap energy. The value of optical basicity was found to be increased with increasing refractive index and band gap energy. The metallization criterion has been calculated on the basis of refractive index and band gap. It was found to be decreased with increasing refractive index and decreasing band gap. The large value of metallization criterion indicates that the glass materials are an insulators.
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spelling upm.eprints-349492017-04-26T08:07:34Z http://psasir.upm.edu.my/id/eprint/34949/ Polarizability and optical basicity of Er3+ ions doped tellurite based glasses Abd Azis, Muhammad Noorazlan Mohamed Kamari, Halimah Zulkefly, Siti Shafinas Wan Yusoff, Wan Mohamad Daud The refractive indices (n) and densities (ρ) of {[ (TeO2)0.70 (B2O3)0.30]1-x (ZnO)x}1-y (Er3O2)y glasses with y = 0.00, y = 0.005, y = 0.01, y = 0.02, y = 0.03, y = 0.04, y = 0.05 were measured at room temperature. The theoretical value of average electronic polarizabilty and oxide ion polarizability were calculated by using Lorentz-Lorenz equation on the basis of refractive index and band gap energy. The value of electronic polarizability and oxide ion polarizability is found to be increased with increasing refractive index and decreasing band gap energy. The optical basicity was measured on the basis of oxide ion polarizability and calculated from refractive index and band gap energy. The value of optical basicity was found to be increased with increasing refractive index and band gap energy. The metallization criterion has been calculated on the basis of refractive index and band gap. It was found to be decreased with increasing refractive index and decreasing band gap. The large value of metallization criterion indicates that the glass materials are an insulators. National Institute of Materials Physics, National Institute of Optoelectronics 2014-07 Article NonPeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/34949/1/Polarizability%20and%20optical%20basicity%20of%20Er3%2B%20ions%20doped%20tellurite%20based%20glasses.pdf Abd Azis, Muhammad Noorazlan and Mohamed Kamari, Halimah and Zulkefly, Siti Shafinas and Wan Yusoff, Wan Mohamad Daud (2014) Polarizability and optical basicity of Er3+ ions doped tellurite based glasses. Chalcogenide Letters, 11 (7). pp. 319-335. ISSN 1584-8663 http://www.chalcogen.ro/index.php/journals/chalcogenide-letters/11-cl/79-volume-11-number-7-july-2014
spellingShingle Abd Azis, Muhammad Noorazlan
Mohamed Kamari, Halimah
Zulkefly, Siti Shafinas
Wan Yusoff, Wan Mohamad Daud
Polarizability and optical basicity of Er3+ ions doped tellurite based glasses
title Polarizability and optical basicity of Er3+ ions doped tellurite based glasses
title_full Polarizability and optical basicity of Er3+ ions doped tellurite based glasses
title_fullStr Polarizability and optical basicity of Er3+ ions doped tellurite based glasses
title_full_unstemmed Polarizability and optical basicity of Er3+ ions doped tellurite based glasses
title_short Polarizability and optical basicity of Er3+ ions doped tellurite based glasses
title_sort polarizability and optical basicity of er3 ions doped tellurite based glasses
url http://psasir.upm.edu.my/id/eprint/34949/1/Polarizability%20and%20optical%20basicity%20of%20Er3%2B%20ions%20doped%20tellurite%20based%20glasses.pdf
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