Production of biodiesel from palm oil using modified Malaysian natural dolomites

Calcined dolomite (AD), produced by calcination of Malaysian dolomite (UD) promotes a potential natural catalyst for biodiesel production from palm oil with the conversion of 99.98%. The catalysts were characterized by using X-ray Diffractometer (XRD), Brunauer–Emmet–Teller (BET) surface area, Scann...

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Bibliographic Details
Main Authors: Zdainal Abidin, Shajaratun Nur, Yap, Taufiq Yun Hin, Md Fahmy, Rabiah Nizah, Teo, Siow Hwa, Osman, Nur Syazwani, Islam, Aminul
Format: Article
Language:English
Published: Elsevier 2014
Online Access:http://psasir.upm.edu.my/id/eprint/35076/1/Production%20of%20biodiesel%20from%20palm%20oil%20using%20modified%20Malaysian%20natural%20dolomites.pdf
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Summary:Calcined dolomite (AD), produced by calcination of Malaysian dolomite (UD) promotes a potential natural catalyst for biodiesel production from palm oil with the conversion of 99.98%. The catalysts were characterized by using X-ray Diffractometer (XRD), Brunauer–Emmet–Teller (BET) surface area, Scanning Electron Microscopy (SEM) and Temperature Programmed Desorption (TPD) of CO2. All catalysts were then employed for transesterification reaction under different conditions (time, methanol to oil molar ratio and amount of catalyst). SnO2 doped on activated dolomite (SD) shows an optimum conversion (99.98%) at conditions, i.e. 15:1 methanol to oil molar ratio in 4 h compared to ZnO doped on activated dolomite (ZD) and AD. The catalytic activities of these catalysts were found to be depending on the basicity as well as the surface area of the catalyst used.