Sawdust-derived Biochar: characterization and Co2 adsorption/desorption study

Sawdust-derived Biochars (SDB) was prepared in a stainless steel fixed bed pyrolyser of 43 mm height and 60 mm internal diameter at four different operating temperatures ranging from 450 to 850°C. SDB physico-chemical characterization such as surface area, functional groups and surface morphology we...

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Main Authors: Wan Ab. Karim Ghani, Wan Azlina, Da Silva, Gabriel
Format: Article
Published: Asian Network for Scientific Information 2014
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author Wan Ab. Karim Ghani, Wan Azlina
Da Silva, Gabriel
author_facet Wan Ab. Karim Ghani, Wan Azlina
Da Silva, Gabriel
author_sort Wan Ab. Karim Ghani, Wan Azlina
collection UPM
description Sawdust-derived Biochars (SDB) was prepared in a stainless steel fixed bed pyrolyser of 43 mm height and 60 mm internal diameter at four different operating temperatures ranging from 450 to 850°C. SDB physico-chemical characterization such as surface area, functional groups and surface morphology were analyzed by N2 physisorption, Fourier Transform Infrared Spectroscopy (FT-IR) and Scanning Electron Microscopy (SEM), respectively. SDBs to have a surface area between 10 to 200 m2g-1 and FTIR revealed an aromatic functional group about 866 cm-1 in most biochar samples. The experimental data shows that the biochars can absorb around 5% water by mass (hydrophilic) at lower temperatures (<550°C) and FTIR results indicated that lignin is not converted into a hydrophobic polycyclic aromatic hydrocarbon (PAH) matrix. While, at higher temperature (>650°C), biochars is thermally stable and became hydrophobic due to the presence of aromatic compounds. The SDB is used for the adsorption of carbon dioxide (CO2) and its can be apply for the removal of CO2 from environment.
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spelling upm.eprints-353152015-12-31T06:07:37Z http://psasir.upm.edu.my/id/eprint/35315/ Sawdust-derived Biochar: characterization and Co2 adsorption/desorption study Wan Ab. Karim Ghani, Wan Azlina Da Silva, Gabriel Sawdust-derived Biochars (SDB) was prepared in a stainless steel fixed bed pyrolyser of 43 mm height and 60 mm internal diameter at four different operating temperatures ranging from 450 to 850°C. SDB physico-chemical characterization such as surface area, functional groups and surface morphology were analyzed by N2 physisorption, Fourier Transform Infrared Spectroscopy (FT-IR) and Scanning Electron Microscopy (SEM), respectively. SDBs to have a surface area between 10 to 200 m2g-1 and FTIR revealed an aromatic functional group about 866 cm-1 in most biochar samples. The experimental data shows that the biochars can absorb around 5% water by mass (hydrophilic) at lower temperatures (<550°C) and FTIR results indicated that lignin is not converted into a hydrophobic polycyclic aromatic hydrocarbon (PAH) matrix. While, at higher temperature (>650°C), biochars is thermally stable and became hydrophobic due to the presence of aromatic compounds. The SDB is used for the adsorption of carbon dioxide (CO2) and its can be apply for the removal of CO2 from environment. Asian Network for Scientific Information 2014 Article NonPeerReviewed Wan Ab. Karim Ghani, Wan Azlina and Da Silva, Gabriel (2014) Sawdust-derived Biochar: characterization and Co2 adsorption/desorption study. Journal of Applied Sciences, 14 (13). pp. 1450-1454. ISSN 1812-5654; ESSN: 1812-5662 http://scialert.net/abstract/?doi=jas.2014.1450.1454 10.3923/jas.2014.1450.1454
spellingShingle Wan Ab. Karim Ghani, Wan Azlina
Da Silva, Gabriel
Sawdust-derived Biochar: characterization and Co2 adsorption/desorption study
title Sawdust-derived Biochar: characterization and Co2 adsorption/desorption study
title_full Sawdust-derived Biochar: characterization and Co2 adsorption/desorption study
title_fullStr Sawdust-derived Biochar: characterization and Co2 adsorption/desorption study
title_full_unstemmed Sawdust-derived Biochar: characterization and Co2 adsorption/desorption study
title_short Sawdust-derived Biochar: characterization and Co2 adsorption/desorption study
title_sort sawdust derived biochar characterization and co2 adsorption desorption study
work_keys_str_mv AT wanabkarimghaniwanazlina sawdustderivedbiocharcharacterizationandco2adsorptiondesorptionstudy
AT dasilvagabriel sawdustderivedbiocharcharacterizationandco2adsorptiondesorptionstudy