Structural,optical and thermal properties of PVA/CdS nanocomposites synthesized by radiolytic method

Monodispersed spherical CdS nanoparticles stabilized in PVA solution were synthesized by the gamma radiolytic method and found the average particle size increased from 12 to 13 nm with the increment of dose from 10 to 40 kGy. The XRD results show that it has crystalline planes of cubic structure wit...

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Main Authors: Kharazmi, Alireza, Saion, Elias, Faraji, Nastaran, Mat Hussin, Roslina, Mat Yunus, Wan Mahmood
Format: Article
Published: Elsevier 2014
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author Kharazmi, Alireza
Saion, Elias
Faraji, Nastaran
Mat Hussin, Roslina
Mat Yunus, Wan Mahmood
author_facet Kharazmi, Alireza
Saion, Elias
Faraji, Nastaran
Mat Hussin, Roslina
Mat Yunus, Wan Mahmood
author_sort Kharazmi, Alireza
collection UPM
description Monodispersed spherical CdS nanoparticles stabilized in PVA solution were synthesized by the gamma radiolytic method and found the average particle size increased from 12 to 13 nm with the increment of dose from 10 to 40 kGy. The XRD results show that it has crystalline planes of cubic structure with crystal lattice parameter of 5.832 Å. The optical reflectance revealed a band-edge of CdS nanoparticles at about 475 nm and the reflectance wavelength red shifted with increasing dose due to increasing particle size. The thermal conductivity of CdS/PVA nanocomposites measured by the transient hot wire method that revealed a decrement of the thermal conductivity with an increase of dose caused by effect of radiation on crystallinity of the polymer structure.
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spelling upm.eprints-355012016-01-11T03:20:54Z http://psasir.upm.edu.my/id/eprint/35501/ Structural,optical and thermal properties of PVA/CdS nanocomposites synthesized by radiolytic method Kharazmi, Alireza Saion, Elias Faraji, Nastaran Mat Hussin, Roslina Mat Yunus, Wan Mahmood Monodispersed spherical CdS nanoparticles stabilized in PVA solution were synthesized by the gamma radiolytic method and found the average particle size increased from 12 to 13 nm with the increment of dose from 10 to 40 kGy. The XRD results show that it has crystalline planes of cubic structure with crystal lattice parameter of 5.832 Å. The optical reflectance revealed a band-edge of CdS nanoparticles at about 475 nm and the reflectance wavelength red shifted with increasing dose due to increasing particle size. The thermal conductivity of CdS/PVA nanocomposites measured by the transient hot wire method that revealed a decrement of the thermal conductivity with an increase of dose caused by effect of radiation on crystallinity of the polymer structure. Elsevier 2014-04 Article PeerReviewed Kharazmi, Alireza and Saion, Elias and Faraji, Nastaran and Mat Hussin, Roslina and Mat Yunus, Wan Mahmood (2014) Structural,optical and thermal properties of PVA/CdS nanocomposites synthesized by radiolytic method. Radiation Physics and Chemistry, 97. pp. 212-216. ISSN 0969-806X; ESSN: 1879-0895 http://www.sciencedirect.com/science/article/pii/S0969806X13006506 10.1016/j.radphyschem.2013.12.003
spellingShingle Kharazmi, Alireza
Saion, Elias
Faraji, Nastaran
Mat Hussin, Roslina
Mat Yunus, Wan Mahmood
Structural,optical and thermal properties of PVA/CdS nanocomposites synthesized by radiolytic method
title Structural,optical and thermal properties of PVA/CdS nanocomposites synthesized by radiolytic method
title_full Structural,optical and thermal properties of PVA/CdS nanocomposites synthesized by radiolytic method
title_fullStr Structural,optical and thermal properties of PVA/CdS nanocomposites synthesized by radiolytic method
title_full_unstemmed Structural,optical and thermal properties of PVA/CdS nanocomposites synthesized by radiolytic method
title_short Structural,optical and thermal properties of PVA/CdS nanocomposites synthesized by radiolytic method
title_sort structural optical and thermal properties of pva cds nanocomposites synthesized by radiolytic method
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AT saionelias structuralopticalandthermalpropertiesofpvacdsnanocompositessynthesizedbyradiolyticmethod
AT farajinastaran structuralopticalandthermalpropertiesofpvacdsnanocompositessynthesizedbyradiolyticmethod
AT mathussinroslina structuralopticalandthermalpropertiesofpvacdsnanocompositessynthesizedbyradiolyticmethod
AT matyunuswanmahmood structuralopticalandthermalpropertiesofpvacdsnanocompositessynthesizedbyradiolyticmethod