Synthesis of 1,3-dichloropropanol from glycerol using muriatic acid as chlorinating agent
Today, one of the problems associated with biodiesel production is the availability of high amount of glycerol byproduct. Among the various possibilities, technology to convert glycerol to dichloropropanol has diverted our attention. Dichloropropanol an important raw material for epichlorohydrin pro...
| Main Authors: | , , , , |
|---|---|
| Format: | Article |
| Published: |
Chemic Publishing Company
2014
|
| _version_ | 1796972737188593664 |
|---|---|
| author | Rahman, Herliati Yunus, Robiah Rashid, Umer Zainal Abidin, Zurina Ahamad, Intan Salwani |
| author_facet | Rahman, Herliati Yunus, Robiah Rashid, Umer Zainal Abidin, Zurina Ahamad, Intan Salwani |
| author_sort | Rahman, Herliati |
| collection | UPM |
| description | Today, one of the problems associated with biodiesel production is the availability of high amount of glycerol byproduct. Among the various possibilities, technology to convert glycerol to dichloropropanol has diverted our attention. Dichloropropanol an important raw material for epichlorohydrin production was successfully synthesized via hydrochlorination reaction of glycerol with aqueous hydrogen chloride to produce 1,3-dichloropropanol. Experimental study was carried out under temperatures ranged; 80 to 120 °C, reactant molar ratio; 1:16 to 1:32 and various carboxylic acid catalysts. The optimal reaction conditions were: temperature, 110 °C; reactant molar ratio glycerol to HCl, 1:24; catalyst, malonic acid; and time duration, 3 h. |
| first_indexed | 2024-03-06T08:32:44Z |
| format | Article |
| id | upm.eprints-35575 |
| institution | Universiti Putra Malaysia |
| last_indexed | 2024-03-06T08:32:44Z |
| publishDate | 2014 |
| publisher | Chemic Publishing Company |
| record_format | dspace |
| spelling | upm.eprints-355752016-01-18T01:05:54Z http://psasir.upm.edu.my/id/eprint/35575/ Synthesis of 1,3-dichloropropanol from glycerol using muriatic acid as chlorinating agent Rahman, Herliati Yunus, Robiah Rashid, Umer Zainal Abidin, Zurina Ahamad, Intan Salwani Today, one of the problems associated with biodiesel production is the availability of high amount of glycerol byproduct. Among the various possibilities, technology to convert glycerol to dichloropropanol has diverted our attention. Dichloropropanol an important raw material for epichlorohydrin production was successfully synthesized via hydrochlorination reaction of glycerol with aqueous hydrogen chloride to produce 1,3-dichloropropanol. Experimental study was carried out under temperatures ranged; 80 to 120 °C, reactant molar ratio; 1:16 to 1:32 and various carboxylic acid catalysts. The optimal reaction conditions were: temperature, 110 °C; reactant molar ratio glycerol to HCl, 1:24; catalyst, malonic acid; and time duration, 3 h. Chemic Publishing Company 2014 Article PeerReviewed Rahman, Herliati and Yunus, Robiah and Rashid, Umer and Zainal Abidin, Zurina and Ahamad, Intan Salwani (2014) Synthesis of 1,3-dichloropropanol from glycerol using muriatic acid as chlorinating agent. Asian Journal of Chemistry, 26 (10). pp. 2907-2912. ISSN 0970-7077; ESSN: 0975-427X http://www.asianjournalofchemistry.co.in/user/journal/viewarticle.aspx?ArticleID=26_11_22 |
| spellingShingle | Rahman, Herliati Yunus, Robiah Rashid, Umer Zainal Abidin, Zurina Ahamad, Intan Salwani Synthesis of 1,3-dichloropropanol from glycerol using muriatic acid as chlorinating agent |
| title | Synthesis of 1,3-dichloropropanol from glycerol using muriatic acid as chlorinating agent |
| title_full | Synthesis of 1,3-dichloropropanol from glycerol using muriatic acid as chlorinating agent |
| title_fullStr | Synthesis of 1,3-dichloropropanol from glycerol using muriatic acid as chlorinating agent |
| title_full_unstemmed | Synthesis of 1,3-dichloropropanol from glycerol using muriatic acid as chlorinating agent |
| title_short | Synthesis of 1,3-dichloropropanol from glycerol using muriatic acid as chlorinating agent |
| title_sort | synthesis of 1 3 dichloropropanol from glycerol using muriatic acid as chlorinating agent |
| work_keys_str_mv | AT rahmanherliati synthesisof13dichloropropanolfromglycerolusingmuriaticacidaschlorinatingagent AT yunusrobiah synthesisof13dichloropropanolfromglycerolusingmuriaticacidaschlorinatingagent AT rashidumer synthesisof13dichloropropanolfromglycerolusingmuriaticacidaschlorinatingagent AT zainalabidinzurina synthesisof13dichloropropanolfromglycerolusingmuriaticacidaschlorinatingagent AT ahamadintansalwani synthesisof13dichloropropanolfromglycerolusingmuriaticacidaschlorinatingagent |