Prospective application of palm oil mill boiler ash as a biosorbent: effect of microwave irradiation and palm oil mill effluent decolorization by adsorption

Common conventional biological treatment methods fail to decolorize palm oil mill effluent (POME). The present study focused on using the abundant palm oil mill boiler (POMB) ashes for POME decolorization. The POMB ashes were subjected to microwave irradiation and chemical treatment using H2SO4. The...

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Main Authors: Hamzah, Muhammad Hazwan, Ahmad Asri, Muhammad Fitri, Che Man, Hasfalina, Mohammed, Abdulsalam
Format: Article
Language:English
Published: MDPI 2019
Online Access:http://psasir.upm.edu.my/id/eprint/38253/1/38253.pdf
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author Hamzah, Muhammad Hazwan
Ahmad Asri, Muhammad Fitri
Che Man, Hasfalina
Mohammed, Abdulsalam
author_facet Hamzah, Muhammad Hazwan
Ahmad Asri, Muhammad Fitri
Che Man, Hasfalina
Mohammed, Abdulsalam
author_sort Hamzah, Muhammad Hazwan
collection UPM
description Common conventional biological treatment methods fail to decolorize palm oil mill effluent (POME). The present study focused on using the abundant palm oil mill boiler (POMB) ashes for POME decolorization. The POMB ashes were subjected to microwave irradiation and chemical treatment using H2SO4. The resultant adsorbents were characterized using scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDX), and Brunauer–Emmett–Teller (BET) analyses. The adsorption efficiency was evaluated at various pH levels (2–8.5), adsorption dosages (3–15 g) in 200 mL, and contact times (1–5 h). The microwave-irradiated POMB-retained ash recorded the highest color removal of 92.31%, for which the best conditions were pH 2, 15 g adsorbent dosage in 200 mL, and 5 h of contact time. At these best treatment conditions, the color concentration of the treated effluent was analyzed using the method proposed by the American Dye Manufacturers Institute (ADMI). The color concentration was 19.20 ADMI, which complies with the Malaysia discharge standard class A. The Freundlich isotherm model better fit the experimental data and had a high R2 of 0.9740. Based on these results, it can be deduced that microwave-irradiated POMB-retained ash has potential applications for POME decolorization via a biosorption process.
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spelling upm.eprints-382532020-05-04T16:08:01Z http://psasir.upm.edu.my/id/eprint/38253/ Prospective application of palm oil mill boiler ash as a biosorbent: effect of microwave irradiation and palm oil mill effluent decolorization by adsorption Hamzah, Muhammad Hazwan Ahmad Asri, Muhammad Fitri Che Man, Hasfalina Mohammed, Abdulsalam Common conventional biological treatment methods fail to decolorize palm oil mill effluent (POME). The present study focused on using the abundant palm oil mill boiler (POMB) ashes for POME decolorization. The POMB ashes were subjected to microwave irradiation and chemical treatment using H2SO4. The resultant adsorbents were characterized using scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDX), and Brunauer–Emmett–Teller (BET) analyses. The adsorption efficiency was evaluated at various pH levels (2–8.5), adsorption dosages (3–15 g) in 200 mL, and contact times (1–5 h). The microwave-irradiated POMB-retained ash recorded the highest color removal of 92.31%, for which the best conditions were pH 2, 15 g adsorbent dosage in 200 mL, and 5 h of contact time. At these best treatment conditions, the color concentration of the treated effluent was analyzed using the method proposed by the American Dye Manufacturers Institute (ADMI). The color concentration was 19.20 ADMI, which complies with the Malaysia discharge standard class A. The Freundlich isotherm model better fit the experimental data and had a high R2 of 0.9740. Based on these results, it can be deduced that microwave-irradiated POMB-retained ash has potential applications for POME decolorization via a biosorption process. MDPI 2019 Article PeerReviewed text en http://psasir.upm.edu.my/id/eprint/38253/1/38253.pdf Hamzah, Muhammad Hazwan and Ahmad Asri, Muhammad Fitri and Che Man, Hasfalina and Mohammed, Abdulsalam (2019) Prospective application of palm oil mill boiler ash as a biosorbent: effect of microwave irradiation and palm oil mill effluent decolorization by adsorption. International Journal of Environmental Research and Public Health, 16 (18). art. no. 3453. pp. 1-18. ISSN 1661-7827; ESSN: 1660-4601 https://www.mdpi.com/1660-4601/16/18/3453 10.3390/ijerph16183453
spellingShingle Hamzah, Muhammad Hazwan
Ahmad Asri, Muhammad Fitri
Che Man, Hasfalina
Mohammed, Abdulsalam
Prospective application of palm oil mill boiler ash as a biosorbent: effect of microwave irradiation and palm oil mill effluent decolorization by adsorption
title Prospective application of palm oil mill boiler ash as a biosorbent: effect of microwave irradiation and palm oil mill effluent decolorization by adsorption
title_full Prospective application of palm oil mill boiler ash as a biosorbent: effect of microwave irradiation and palm oil mill effluent decolorization by adsorption
title_fullStr Prospective application of palm oil mill boiler ash as a biosorbent: effect of microwave irradiation and palm oil mill effluent decolorization by adsorption
title_full_unstemmed Prospective application of palm oil mill boiler ash as a biosorbent: effect of microwave irradiation and palm oil mill effluent decolorization by adsorption
title_short Prospective application of palm oil mill boiler ash as a biosorbent: effect of microwave irradiation and palm oil mill effluent decolorization by adsorption
title_sort prospective application of palm oil mill boiler ash as a biosorbent effect of microwave irradiation and palm oil mill effluent decolorization by adsorption
url http://psasir.upm.edu.my/id/eprint/38253/1/38253.pdf
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