Facile electrodeposition of poly(3,4-ethylenedioxythiophene) on poly(vinyl alcohol) nanofibers as the positive electrode for high-performance asymmetric supercapacitor

Poly(vinyl alcohol)/poly(3,4-ethylenedioxythiophene) (PVA/PEDOT) nanofibers were synthesized as a positive electrode for high-performance asymmetric supercapacitor (ASC). PVA/PEDOT nanofibers were prepared through electrospinning and electrodeposition meanwhile reduced graphene oxide (rGO) was obtai...

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Main Authors: Dasdevan, Nivekthiren, Mohd Abdah, Muhammad Amirul Aizat, Sulaiman, Yusran
Format: Article
Language:English
Published: MDPI 2019
Online Access:http://psasir.upm.edu.my/id/eprint/38271/1/38271.pdf
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author Dasdevan, Nivekthiren
Mohd Abdah, Muhammad Amirul Aizat
Sulaiman, Yusran
author_facet Dasdevan, Nivekthiren
Mohd Abdah, Muhammad Amirul Aizat
Sulaiman, Yusran
author_sort Dasdevan, Nivekthiren
collection UPM
description Poly(vinyl alcohol)/poly(3,4-ethylenedioxythiophene) (PVA/PEDOT) nanofibers were synthesized as a positive electrode for high-performance asymmetric supercapacitor (ASC). PVA/PEDOT nanofibers were prepared through electrospinning and electrodeposition meanwhile reduced graphene oxide (rGO) was obtained by electrochemical reduction. The PVA/PEDOT nanofibers demonstrated cauliflower-like morphology showing that PEDOT was uniformly coated on the smooth cross-linking structure of PVA nanofibers. In addition, the ASC showed a remarkable energy output efficiency by delivering specific energy of 21.45 Wh·kg−1 at a specific power of 335.50 W·kg−1 with good cyclability performance (83% capacitance retained) after 5000 CV cycles. The outstanding supercapacitive performance is contributed from the synergistic effects of both PVA/PEDOT//rGO, which gives promising materials for designing high-performance supercapacitor applications.
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spelling upm.eprints-382712020-05-04T16:10:35Z http://psasir.upm.edu.my/id/eprint/38271/ Facile electrodeposition of poly(3,4-ethylenedioxythiophene) on poly(vinyl alcohol) nanofibers as the positive electrode for high-performance asymmetric supercapacitor Dasdevan, Nivekthiren Mohd Abdah, Muhammad Amirul Aizat Sulaiman, Yusran Poly(vinyl alcohol)/poly(3,4-ethylenedioxythiophene) (PVA/PEDOT) nanofibers were synthesized as a positive electrode for high-performance asymmetric supercapacitor (ASC). PVA/PEDOT nanofibers were prepared through electrospinning and electrodeposition meanwhile reduced graphene oxide (rGO) was obtained by electrochemical reduction. The PVA/PEDOT nanofibers demonstrated cauliflower-like morphology showing that PEDOT was uniformly coated on the smooth cross-linking structure of PVA nanofibers. In addition, the ASC showed a remarkable energy output efficiency by delivering specific energy of 21.45 Wh·kg−1 at a specific power of 335.50 W·kg−1 with good cyclability performance (83% capacitance retained) after 5000 CV cycles. The outstanding supercapacitive performance is contributed from the synergistic effects of both PVA/PEDOT//rGO, which gives promising materials for designing high-performance supercapacitor applications. MDPI 2019 Article PeerReviewed text en http://psasir.upm.edu.my/id/eprint/38271/1/38271.pdf Dasdevan, Nivekthiren and Mohd Abdah, Muhammad Amirul Aizat and Sulaiman, Yusran (2019) Facile electrodeposition of poly(3,4-ethylenedioxythiophene) on poly(vinyl alcohol) nanofibers as the positive electrode for high-performance asymmetric supercapacitor. Energies, 12 (17). art. no. 3382. pp. 1-13. ISSN 1996-1073 https://www.mdpi.com/1996-1073/12/17/3382 10.3390/en12173382
spellingShingle Dasdevan, Nivekthiren
Mohd Abdah, Muhammad Amirul Aizat
Sulaiman, Yusran
Facile electrodeposition of poly(3,4-ethylenedioxythiophene) on poly(vinyl alcohol) nanofibers as the positive electrode for high-performance asymmetric supercapacitor
title Facile electrodeposition of poly(3,4-ethylenedioxythiophene) on poly(vinyl alcohol) nanofibers as the positive electrode for high-performance asymmetric supercapacitor
title_full Facile electrodeposition of poly(3,4-ethylenedioxythiophene) on poly(vinyl alcohol) nanofibers as the positive electrode for high-performance asymmetric supercapacitor
title_fullStr Facile electrodeposition of poly(3,4-ethylenedioxythiophene) on poly(vinyl alcohol) nanofibers as the positive electrode for high-performance asymmetric supercapacitor
title_full_unstemmed Facile electrodeposition of poly(3,4-ethylenedioxythiophene) on poly(vinyl alcohol) nanofibers as the positive electrode for high-performance asymmetric supercapacitor
title_short Facile electrodeposition of poly(3,4-ethylenedioxythiophene) on poly(vinyl alcohol) nanofibers as the positive electrode for high-performance asymmetric supercapacitor
title_sort facile electrodeposition of poly 3 4 ethylenedioxythiophene on poly vinyl alcohol nanofibers as the positive electrode for high performance asymmetric supercapacitor
url http://psasir.upm.edu.my/id/eprint/38271/1/38271.pdf
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AT mohdabdahmuhammadamirulaizat facileelectrodepositionofpoly34ethylenedioxythiopheneonpolyvinylalcoholnanofibersasthepositiveelectrodeforhighperformanceasymmetricsupercapacitor
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