Well-dispersed cellulose nanofiber in low density polyethylene nanocomposite by liquid-assisted extrusion

Two different liquid assisted processing methods: internal melt-blending (IMB) and twin-screw extrusion (TWS) were performed to fabricate polyethylene (PE)/cellulose nanofiber (CNF) nanocomposites. The nanocomposites consisted maleic anhydride-grafted PE (PEgMA) as a compatibilizer, with PE/PEgMA/CN...

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Main Authors: Tengku Yasim Anuar, Tengku Arisyah, Ariffin, Hidayah, Norrrahim, Mohd Nor Faiz, Hassan, Mohd Ali, Andou, Yoshito, Tsukegi, Takayuki, Nishida, Haruo
Format: Article
Language:English
Published: MDPI 2020
Online Access:http://psasir.upm.edu.my/id/eprint/38392/1/38392.pdf
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author Tengku Yasim Anuar, Tengku Arisyah
Ariffin, Hidayah
Norrrahim, Mohd Nor Faiz
Hassan, Mohd Ali
Andou, Yoshito
Tsukegi, Takayuki
Nishida, Haruo
author_facet Tengku Yasim Anuar, Tengku Arisyah
Ariffin, Hidayah
Norrrahim, Mohd Nor Faiz
Hassan, Mohd Ali
Andou, Yoshito
Tsukegi, Takayuki
Nishida, Haruo
author_sort Tengku Yasim Anuar, Tengku Arisyah
collection UPM
description Two different liquid assisted processing methods: internal melt-blending (IMB) and twin-screw extrusion (TWS) were performed to fabricate polyethylene (PE)/cellulose nanofiber (CNF) nanocomposites. The nanocomposites consisted maleic anhydride-grafted PE (PEgMA) as a compatibilizer, with PE/PEgMA/CNF ratio of 97/3/0.5–5 (wt./wt./wt.), respectively. Morphological analysis exhibited that CNF was well-dispersed in nanocomposites prepared by liquid-assisted TWS. Meanwhile, a randomly oriented and agglomerated CNF was observed in the nanocomposites prepared by liquid-assisted IMB. The nanocomposites obtained from liquid-assisted TWS exhibited the best mechanical properties at 3 wt.% CNF addition with an increment in flexural strength by almost 139%, higher than that of liquid-assisted IMB. Results from this study indicated that liquid feeding of CNF assisted the homogenous dispersion of CNF in PE matrix, and the mechanical properties of the nanocomposites were affected by compounding method due to the CNF dispersion and alignment.
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spelling upm.eprints-383922020-05-04T16:27:14Z http://psasir.upm.edu.my/id/eprint/38392/ Well-dispersed cellulose nanofiber in low density polyethylene nanocomposite by liquid-assisted extrusion Tengku Yasim Anuar, Tengku Arisyah Ariffin, Hidayah Norrrahim, Mohd Nor Faiz Hassan, Mohd Ali Andou, Yoshito Tsukegi, Takayuki Nishida, Haruo Two different liquid assisted processing methods: internal melt-blending (IMB) and twin-screw extrusion (TWS) were performed to fabricate polyethylene (PE)/cellulose nanofiber (CNF) nanocomposites. The nanocomposites consisted maleic anhydride-grafted PE (PEgMA) as a compatibilizer, with PE/PEgMA/CNF ratio of 97/3/0.5–5 (wt./wt./wt.), respectively. Morphological analysis exhibited that CNF was well-dispersed in nanocomposites prepared by liquid-assisted TWS. Meanwhile, a randomly oriented and agglomerated CNF was observed in the nanocomposites prepared by liquid-assisted IMB. The nanocomposites obtained from liquid-assisted TWS exhibited the best mechanical properties at 3 wt.% CNF addition with an increment in flexural strength by almost 139%, higher than that of liquid-assisted IMB. Results from this study indicated that liquid feeding of CNF assisted the homogenous dispersion of CNF in PE matrix, and the mechanical properties of the nanocomposites were affected by compounding method due to the CNF dispersion and alignment. MDPI 2020 Article PeerReviewed text en http://psasir.upm.edu.my/id/eprint/38392/1/38392.pdf Tengku Yasim Anuar, Tengku Arisyah and Ariffin, Hidayah and Norrrahim, Mohd Nor Faiz and Hassan, Mohd Ali and Andou, Yoshito and Tsukegi, Takayuki and Nishida, Haruo (2020) Well-dispersed cellulose nanofiber in low density polyethylene nanocomposite by liquid-assisted extrusion. Polymers, 12 (4). art. no. 927. pp. 1-17. ISSN 2073-4360 https://www.mdpi.com/2073-4360/12/4/927 10.3390/polym12040927
spellingShingle Tengku Yasim Anuar, Tengku Arisyah
Ariffin, Hidayah
Norrrahim, Mohd Nor Faiz
Hassan, Mohd Ali
Andou, Yoshito
Tsukegi, Takayuki
Nishida, Haruo
Well-dispersed cellulose nanofiber in low density polyethylene nanocomposite by liquid-assisted extrusion
title Well-dispersed cellulose nanofiber in low density polyethylene nanocomposite by liquid-assisted extrusion
title_full Well-dispersed cellulose nanofiber in low density polyethylene nanocomposite by liquid-assisted extrusion
title_fullStr Well-dispersed cellulose nanofiber in low density polyethylene nanocomposite by liquid-assisted extrusion
title_full_unstemmed Well-dispersed cellulose nanofiber in low density polyethylene nanocomposite by liquid-assisted extrusion
title_short Well-dispersed cellulose nanofiber in low density polyethylene nanocomposite by liquid-assisted extrusion
title_sort well dispersed cellulose nanofiber in low density polyethylene nanocomposite by liquid assisted extrusion
url http://psasir.upm.edu.my/id/eprint/38392/1/38392.pdf
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