Thermochemical measurement of the ligand field splitting energies for hexaammine complexes of Mn(II), Fe(II), and Zn(II)
Various lower ammines and high-energy modifications of lower ammines of the sulphates of Mn(II), Fe(II), and Zn(II) have been prepared and their heats of solution have been measured. For each of these ammine systems, the maximum difference in heat of solution, expressed in kcal/mol of heptaammine, h...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
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NRC Research Press
1977
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| Online Access: | http://psasir.upm.edu.my/id/eprint/38483/1/0001.pdf |
| _version_ | 1796973354498916352 |
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| author | Badri, M. Jamieson, J. W. S. |
| author_facet | Badri, M. Jamieson, J. W. S. |
| author_sort | Badri, M. |
| collection | UPM |
| description | Various lower ammines and high-energy modifications of lower ammines of the sulphates of Mn(II), Fe(II), and Zn(II) have been prepared and their heats of solution have been measured. For each of these ammine systems, the maximum difference in heat of solution, expressed in kcal/mol of heptaammine, has been found to be of the right order of magnitude to be regarded as the ligand field splitting energy for the hexaammine complex of the metal ion |
| first_indexed | 2024-03-06T08:41:25Z |
| format | Article |
| id | upm.eprints-38483 |
| institution | Universiti Putra Malaysia |
| language | English |
| last_indexed | 2024-03-06T08:41:25Z |
| publishDate | 1977 |
| publisher | NRC Research Press |
| record_format | dspace |
| spelling | upm.eprints-384832015-05-28T07:03:55Z http://psasir.upm.edu.my/id/eprint/38483/ Thermochemical measurement of the ligand field splitting energies for hexaammine complexes of Mn(II), Fe(II), and Zn(II) Badri, M. Jamieson, J. W. S. Various lower ammines and high-energy modifications of lower ammines of the sulphates of Mn(II), Fe(II), and Zn(II) have been prepared and their heats of solution have been measured. For each of these ammine systems, the maximum difference in heat of solution, expressed in kcal/mol of heptaammine, has been found to be of the right order of magnitude to be regarded as the ligand field splitting energy for the hexaammine complex of the metal ion NRC Research Press 1977 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/38483/1/0001.pdf Badri, M. and Jamieson, J. W. S. (1977) Thermochemical measurement of the ligand field splitting energies for hexaammine complexes of Mn(II), Fe(II), and Zn(II). Canadian Journal of Chemistry, 55 (20). pp. 3530-3535. ISSN 0008-4042; ESSN: 1480-3291 |
| spellingShingle | Badri, M. Jamieson, J. W. S. Thermochemical measurement of the ligand field splitting energies for hexaammine complexes of Mn(II), Fe(II), and Zn(II) |
| title | Thermochemical measurement of the ligand field splitting energies for hexaammine complexes of Mn(II), Fe(II), and Zn(II) |
| title_full | Thermochemical measurement of the ligand field splitting energies for hexaammine complexes of Mn(II), Fe(II), and Zn(II) |
| title_fullStr | Thermochemical measurement of the ligand field splitting energies for hexaammine complexes of Mn(II), Fe(II), and Zn(II) |
| title_full_unstemmed | Thermochemical measurement of the ligand field splitting energies for hexaammine complexes of Mn(II), Fe(II), and Zn(II) |
| title_short | Thermochemical measurement of the ligand field splitting energies for hexaammine complexes of Mn(II), Fe(II), and Zn(II) |
| title_sort | thermochemical measurement of the ligand field splitting energies for hexaammine complexes of mn ii fe ii and zn ii |
| url | http://psasir.upm.edu.my/id/eprint/38483/1/0001.pdf |
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