Kinetic and Equilibrium Studies on the Exchange Process of n-Hexanol and Cetyl Trimethyl Ammonium Bromide (CTAB) Micelles

Kinetic studies using ultrasonic relaxation method in the mixed micellar solutions of n-hexanol dan cetyl trimethyl ammonium bromide have shown a well-defined single relaxation. This is associated with the exchange process involving the partitioning of alcohol with the mixed micelle. The equilibriu...

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Main Authors: Wan Badhi, Wan Ahmad, Suhaimi, Hamdan, Ibrahim, Ramli, Hassan, Senin
Format: Article
Language:English
English
Published: Universiti Putra Malaysia Press 1995
Online Access:http://psasir.upm.edu.my/id/eprint/3869/1/Kinetic_and_Equilibrium_Studies_on_the_Exchange.pdf
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author Wan Badhi, Wan Ahmad
Suhaimi, Hamdan
Ibrahim, Ramli
Hassan, Senin
author_facet Wan Badhi, Wan Ahmad
Suhaimi, Hamdan
Ibrahim, Ramli
Hassan, Senin
author_sort Wan Badhi, Wan Ahmad
collection UPM
description Kinetic studies using ultrasonic relaxation method in the mixed micellar solutions of n-hexanol dan cetyl trimethyl ammonium bromide have shown a well-defined single relaxation. This is associated with the exchange process involving the partitioning of alcohol with the mixed micelle. The equilibrium measurement which monitors the monomer concentration of n-hexanol was measured using head space analysis involving gas chromatography. The combined relaxation and equilibrium data were analysed using a phenomenological treatment in which the kinetics and thermodynamics parameters were evaluated for the exchange process. The main conclusion from this work is that the association of n-hexanol to the the mixed micelles is almost a diffusion controlled process.
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spelling upm.eprints-38692013-05-27T07:11:54Z http://psasir.upm.edu.my/id/eprint/3869/ Kinetic and Equilibrium Studies on the Exchange Process of n-Hexanol and Cetyl Trimethyl Ammonium Bromide (CTAB) Micelles Wan Badhi, Wan Ahmad Suhaimi, Hamdan Ibrahim, Ramli Hassan, Senin Kinetic studies using ultrasonic relaxation method in the mixed micellar solutions of n-hexanol dan cetyl trimethyl ammonium bromide have shown a well-defined single relaxation. This is associated with the exchange process involving the partitioning of alcohol with the mixed micelle. The equilibrium measurement which monitors the monomer concentration of n-hexanol was measured using head space analysis involving gas chromatography. The combined relaxation and equilibrium data were analysed using a phenomenological treatment in which the kinetics and thermodynamics parameters were evaluated for the exchange process. The main conclusion from this work is that the association of n-hexanol to the the mixed micelles is almost a diffusion controlled process. Universiti Putra Malaysia Press 1995 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/3869/1/Kinetic_and_Equilibrium_Studies_on_the_Exchange.pdf Wan Badhi, Wan Ahmad and Suhaimi, Hamdan and Ibrahim, Ramli and Hassan, Senin (1995) Kinetic and Equilibrium Studies on the Exchange Process of n-Hexanol and Cetyl Trimethyl Ammonium Bromide (CTAB) Micelles. Pertanika Journal of Science & Technology, 3 (2). pp. 221-232. ISSN 0128-7680 English
spellingShingle Wan Badhi, Wan Ahmad
Suhaimi, Hamdan
Ibrahim, Ramli
Hassan, Senin
Kinetic and Equilibrium Studies on the Exchange Process of n-Hexanol and Cetyl Trimethyl Ammonium Bromide (CTAB) Micelles
title Kinetic and Equilibrium Studies on the Exchange Process of n-Hexanol and Cetyl Trimethyl Ammonium Bromide (CTAB) Micelles
title_full Kinetic and Equilibrium Studies on the Exchange Process of n-Hexanol and Cetyl Trimethyl Ammonium Bromide (CTAB) Micelles
title_fullStr Kinetic and Equilibrium Studies on the Exchange Process of n-Hexanol and Cetyl Trimethyl Ammonium Bromide (CTAB) Micelles
title_full_unstemmed Kinetic and Equilibrium Studies on the Exchange Process of n-Hexanol and Cetyl Trimethyl Ammonium Bromide (CTAB) Micelles
title_short Kinetic and Equilibrium Studies on the Exchange Process of n-Hexanol and Cetyl Trimethyl Ammonium Bromide (CTAB) Micelles
title_sort kinetic and equilibrium studies on the exchange process of n hexanol and cetyl trimethyl ammonium bromide ctab micelles
url http://psasir.upm.edu.my/id/eprint/3869/1/Kinetic_and_Equilibrium_Studies_on_the_Exchange.pdf
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