Kinetic and Equilibrium Studies on the Exchange Process of n-Hexanol and Cetyl Trimethyl Ammonium Bromide (CTAB) Micelles
Kinetic studies using ultrasonic relaxation method in the mixed micellar solutions of n-hexanol dan cetyl trimethyl ammonium bromide have shown a well-defined single relaxation. This is associated with the exchange process involving the partitioning of alcohol with the mixed micelle. The equilibriu...
Main Authors: | , , , |
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Format: | Article |
Language: | English English |
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Universiti Putra Malaysia Press
1995
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Online Access: | http://psasir.upm.edu.my/id/eprint/3869/1/Kinetic_and_Equilibrium_Studies_on_the_Exchange.pdf |
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author | Wan Badhi, Wan Ahmad Suhaimi, Hamdan Ibrahim, Ramli Hassan, Senin |
author_facet | Wan Badhi, Wan Ahmad Suhaimi, Hamdan Ibrahim, Ramli Hassan, Senin |
author_sort | Wan Badhi, Wan Ahmad |
collection | UPM |
description | Kinetic studies using ultrasonic relaxation method in the mixed micellar solutions of n-hexanol dan cetyl trimethyl ammonium bromide have shown a well-defined single relaxation. This is associated with the exchange process
involving the partitioning of alcohol with the mixed micelle. The equilibrium measurement which monitors the monomer concentration of n-hexanol was measured using head space analysis involving gas chromatography. The combined
relaxation and equilibrium data were analysed using a phenomenological treatment in which the kinetics and thermodynamics parameters were evaluated for the exchange process. The main conclusion from this work is that the
association of n-hexanol to the the mixed micelles is almost a diffusion controlled process. |
first_indexed | 2024-03-06T07:02:23Z |
format | Article |
id | upm.eprints-3869 |
institution | Universiti Putra Malaysia |
language | English English |
last_indexed | 2024-03-06T07:02:23Z |
publishDate | 1995 |
publisher | Universiti Putra Malaysia Press |
record_format | dspace |
spelling | upm.eprints-38692013-05-27T07:11:54Z http://psasir.upm.edu.my/id/eprint/3869/ Kinetic and Equilibrium Studies on the Exchange Process of n-Hexanol and Cetyl Trimethyl Ammonium Bromide (CTAB) Micelles Wan Badhi, Wan Ahmad Suhaimi, Hamdan Ibrahim, Ramli Hassan, Senin Kinetic studies using ultrasonic relaxation method in the mixed micellar solutions of n-hexanol dan cetyl trimethyl ammonium bromide have shown a well-defined single relaxation. This is associated with the exchange process involving the partitioning of alcohol with the mixed micelle. The equilibrium measurement which monitors the monomer concentration of n-hexanol was measured using head space analysis involving gas chromatography. The combined relaxation and equilibrium data were analysed using a phenomenological treatment in which the kinetics and thermodynamics parameters were evaluated for the exchange process. The main conclusion from this work is that the association of n-hexanol to the the mixed micelles is almost a diffusion controlled process. Universiti Putra Malaysia Press 1995 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/3869/1/Kinetic_and_Equilibrium_Studies_on_the_Exchange.pdf Wan Badhi, Wan Ahmad and Suhaimi, Hamdan and Ibrahim, Ramli and Hassan, Senin (1995) Kinetic and Equilibrium Studies on the Exchange Process of n-Hexanol and Cetyl Trimethyl Ammonium Bromide (CTAB) Micelles. Pertanika Journal of Science & Technology, 3 (2). pp. 221-232. ISSN 0128-7680 English |
spellingShingle | Wan Badhi, Wan Ahmad Suhaimi, Hamdan Ibrahim, Ramli Hassan, Senin Kinetic and Equilibrium Studies on the Exchange Process of n-Hexanol and Cetyl Trimethyl Ammonium Bromide (CTAB) Micelles |
title | Kinetic and Equilibrium Studies on the Exchange Process of n-Hexanol and Cetyl Trimethyl Ammonium Bromide (CTAB) Micelles |
title_full | Kinetic and Equilibrium Studies on the Exchange Process of n-Hexanol and Cetyl Trimethyl Ammonium Bromide (CTAB) Micelles |
title_fullStr | Kinetic and Equilibrium Studies on the Exchange Process of n-Hexanol and Cetyl Trimethyl Ammonium Bromide (CTAB) Micelles |
title_full_unstemmed | Kinetic and Equilibrium Studies on the Exchange Process of n-Hexanol and Cetyl Trimethyl Ammonium Bromide (CTAB) Micelles |
title_short | Kinetic and Equilibrium Studies on the Exchange Process of n-Hexanol and Cetyl Trimethyl Ammonium Bromide (CTAB) Micelles |
title_sort | kinetic and equilibrium studies on the exchange process of n hexanol and cetyl trimethyl ammonium bromide ctab micelles |
url | http://psasir.upm.edu.my/id/eprint/3869/1/Kinetic_and_Equilibrium_Studies_on_the_Exchange.pdf |
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