Graft copolymerization of methyl acrylate onto sago starch using ceric ammonium nitrate as an initiator
The graft copolymerization of methyl acrylate onto sago starch was carried out by a free radical initiating process. The free radicals were produced by the chemical initiation method in which ceric ammonium nitrate was used as an initiator. It was found that the percentages of grafting, grafting eff...
| Main Authors: | , , , , , |
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| Format: | Article |
| Language: | English English |
| Published: |
Wiley
2000
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| Online Access: | http://psasir.upm.edu.my/id/eprint/40117/1/Graft%20copolymerization%20of%20methyl%20acrylate%20onto%20sago%20starch%20using%20ceric%20ammonium%20nitrate%20as%20an%20initiator.pdf http://psasir.upm.edu.my/id/eprint/40117/7/J%20of%20Applied%20Polymer%20Sci%20-%202000%20-%20Rahman%20-%20Graft%20copolymerization%20of%20methyl%20acrylate%20onto%20sago%20starch%20using%20ceric%20ammonium.pdf |
| _version_ | 1825949540047388672 |
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| author | Rahman, Lutfor Silong, Sidik Wan Yunus, Wan Md Zin Ab. Rahman, Mohamad Zaki Ahmad @ Ayob, Mansor Haron, Md. Jelas |
| author_facet | Rahman, Lutfor Silong, Sidik Wan Yunus, Wan Md Zin Ab. Rahman, Mohamad Zaki Ahmad @ Ayob, Mansor Haron, Md. Jelas |
| author_sort | Rahman, Lutfor |
| collection | UPM |
| description | The graft copolymerization of methyl acrylate onto sago starch was carried out by a free radical initiating process. The free radicals were produced by the chemical initiation method in which ceric ammonium nitrate was used as an initiator. It was found that the percentages of grafting, grafting efficiency, and rate of grafting were all dependent on the concentration of ceric ammonium nitrate (CAN), methyl acrylate (MA), sago starch (AGU), mineral acid (H2SO4), and reaction temperature and period. The variables affecting the graft copolymerization were thoroughly examined. The optimum yield of grafting was obtained when the concentration of CAN, MA, AGU, and H2SO4 were used at 8.77 × 10−3, 0.803, 0.135, and 0.175 mol L−1, respectively. The optimum reaction temperature and period were 50°C and 60 min, respectively. The rate of graft polymerization was explored on the basis of experimental results and reaction mechanism. The evidence of grafted copolymers was investigated by using FTIR spectroscopy, TG, and DSC analysis. |
| first_indexed | 2024-03-06T08:46:08Z |
| format | Article |
| id | upm.eprints-40117 |
| institution | Universiti Putra Malaysia |
| language | English English |
| last_indexed | 2024-09-25T03:34:15Z |
| publishDate | 2000 |
| publisher | Wiley |
| record_format | dspace |
| spelling | upm.eprints-401172024-07-24T06:39:33Z http://psasir.upm.edu.my/id/eprint/40117/ Graft copolymerization of methyl acrylate onto sago starch using ceric ammonium nitrate as an initiator Rahman, Lutfor Silong, Sidik Wan Yunus, Wan Md Zin Ab. Rahman, Mohamad Zaki Ahmad @ Ayob, Mansor Haron, Md. Jelas The graft copolymerization of methyl acrylate onto sago starch was carried out by a free radical initiating process. The free radicals were produced by the chemical initiation method in which ceric ammonium nitrate was used as an initiator. It was found that the percentages of grafting, grafting efficiency, and rate of grafting were all dependent on the concentration of ceric ammonium nitrate (CAN), methyl acrylate (MA), sago starch (AGU), mineral acid (H2SO4), and reaction temperature and period. The variables affecting the graft copolymerization were thoroughly examined. The optimum yield of grafting was obtained when the concentration of CAN, MA, AGU, and H2SO4 were used at 8.77 × 10−3, 0.803, 0.135, and 0.175 mol L−1, respectively. The optimum reaction temperature and period were 50°C and 60 min, respectively. The rate of graft polymerization was explored on the basis of experimental results and reaction mechanism. The evidence of grafted copolymers was investigated by using FTIR spectroscopy, TG, and DSC analysis. Wiley 2000-04 Article PeerReviewed text en http://psasir.upm.edu.my/id/eprint/40117/1/Graft%20copolymerization%20of%20methyl%20acrylate%20onto%20sago%20starch%20using%20ceric%20ammonium%20nitrate%20as%20an%20initiator.pdf text en http://psasir.upm.edu.my/id/eprint/40117/7/J%20of%20Applied%20Polymer%20Sci%20-%202000%20-%20Rahman%20-%20Graft%20copolymerization%20of%20methyl%20acrylate%20onto%20sago%20starch%20using%20ceric%20ammonium.pdf Rahman, Lutfor and Silong, Sidik and Wan Yunus, Wan Md Zin and Ab. Rahman, Mohamad Zaki and Ahmad @ Ayob, Mansor and Haron, Md. Jelas (2000) Graft copolymerization of methyl acrylate onto sago starch using ceric ammonium nitrate as an initiator. Journal of Applied Polymer Science, 76 (4). pp. 516-523. ISSN 0021-8995; ESSN: 1097-4628 http://onlinelibrary.wiley.com/doi/10.1002/%28SICI%291097-4628%2820000425%2976:4%3C516::AID-APP9%3E3.0.CO;2-7/abstract 10.1002/(SICI)1097-4628(20000425)76:4<516::AID-APP9>3.0.CO;2-7 |
| spellingShingle | Rahman, Lutfor Silong, Sidik Wan Yunus, Wan Md Zin Ab. Rahman, Mohamad Zaki Ahmad @ Ayob, Mansor Haron, Md. Jelas Graft copolymerization of methyl acrylate onto sago starch using ceric ammonium nitrate as an initiator |
| title | Graft copolymerization of methyl acrylate onto sago starch using ceric ammonium nitrate as an initiator |
| title_full | Graft copolymerization of methyl acrylate onto sago starch using ceric ammonium nitrate as an initiator |
| title_fullStr | Graft copolymerization of methyl acrylate onto sago starch using ceric ammonium nitrate as an initiator |
| title_full_unstemmed | Graft copolymerization of methyl acrylate onto sago starch using ceric ammonium nitrate as an initiator |
| title_short | Graft copolymerization of methyl acrylate onto sago starch using ceric ammonium nitrate as an initiator |
| title_sort | graft copolymerization of methyl acrylate onto sago starch using ceric ammonium nitrate as an initiator |
| url | http://psasir.upm.edu.my/id/eprint/40117/1/Graft%20copolymerization%20of%20methyl%20acrylate%20onto%20sago%20starch%20using%20ceric%20ammonium%20nitrate%20as%20an%20initiator.pdf http://psasir.upm.edu.my/id/eprint/40117/7/J%20of%20Applied%20Polymer%20Sci%20-%202000%20-%20Rahman%20-%20Graft%20copolymerization%20of%20methyl%20acrylate%20onto%20sago%20starch%20using%20ceric%20ammonium.pdf |
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