Synthesis and thermophysical properties of Ti3C2TX -based vanadium bromide redox flow for green energy storage

Vanadium bromide redox flow batteries (V-Br RFB) have been created with new promising technologies for stationary renewable energy storage. Compared to previous redox flow battery systems, this technology is very efficient, inexpensive, and long-lasting. However, the low thermal conductivity, low di...

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Main Authors: Hossain, Md Hasnat, Mohd Radzi, Mohd Amran, Zaed, Md Abu, Rahman, Saidur, Shafie, Suhaidi, Hossain, Md Showkot
Format: Conference or Workshop Item
Published: IEEE 2022
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author Hossain, Md Hasnat
Mohd Radzi, Mohd Amran
Zaed, Md Abu
Rahman, Saidur
Shafie, Suhaidi
Hossain, Md Showkot
author_facet Hossain, Md Hasnat
Mohd Radzi, Mohd Amran
Zaed, Md Abu
Rahman, Saidur
Shafie, Suhaidi
Hossain, Md Showkot
author_sort Hossain, Md Hasnat
collection UPM
description Vanadium bromide redox flow batteries (V-Br RFB) have been created with new promising technologies for stationary renewable energy storage. Compared to previous redox flow battery systems, this technology is very efficient, inexpensive, and long-lasting. However, the low thermal conductivity, low diffusivity, high resistivity, high liquid density, and low energy efficiency of V-Br RFB need to be overcome. V-Br3 electrolytes containing MXene are being investigated in this work to increase thermal conductivity, decrease resistivity, and enhance diffusivity. The nanofluid based on V-Br3 electrolyte is tested with a varied MXene (Ti3C2Tx) content (0.25% wt, 0.50% wt, 0.75 % wt) at different temperatures. Thermal and electrochemical characterizations, such as FTIR, UV-Vis, SEM, and EDX are done. MXene's light transmission capacity is improved, the 2D layer structure was smooth, and electrolyte solutions were stable, according to FTIR, UV-Vis, SEM, and EDX. The highest value of thermal conductivity for an MXene-based electrolyte is raised versus a base solution by 53.6%, 70.3%, and 82.1% while the resistivity is lowered by 65.1%, 81.2%, and 81.9%. At 450C, 0.75% wt MXene provides the highest thermal conductivity enhancement of 82.1%. The study's improved physical, thermal, and electrochemical characterizations may aid future research into green energy storage technology, and it will help to meet the Sustainable Development Goals (SDGs).
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spelling upm.eprints-442202023-12-24T15:58:30Z http://psasir.upm.edu.my/id/eprint/44220/ Synthesis and thermophysical properties of Ti3C2TX -based vanadium bromide redox flow for green energy storage Hossain, Md Hasnat Mohd Radzi, Mohd Amran Zaed, Md Abu Rahman, Saidur Shafie, Suhaidi Hossain, Md Showkot Vanadium bromide redox flow batteries (V-Br RFB) have been created with new promising technologies for stationary renewable energy storage. Compared to previous redox flow battery systems, this technology is very efficient, inexpensive, and long-lasting. However, the low thermal conductivity, low diffusivity, high resistivity, high liquid density, and low energy efficiency of V-Br RFB need to be overcome. V-Br3 electrolytes containing MXene are being investigated in this work to increase thermal conductivity, decrease resistivity, and enhance diffusivity. The nanofluid based on V-Br3 electrolyte is tested with a varied MXene (Ti3C2Tx) content (0.25% wt, 0.50% wt, 0.75 % wt) at different temperatures. Thermal and electrochemical characterizations, such as FTIR, UV-Vis, SEM, and EDX are done. MXene's light transmission capacity is improved, the 2D layer structure was smooth, and electrolyte solutions were stable, according to FTIR, UV-Vis, SEM, and EDX. The highest value of thermal conductivity for an MXene-based electrolyte is raised versus a base solution by 53.6%, 70.3%, and 82.1% while the resistivity is lowered by 65.1%, 81.2%, and 81.9%. At 450C, 0.75% wt MXene provides the highest thermal conductivity enhancement of 82.1%. The study's improved physical, thermal, and electrochemical characterizations may aid future research into green energy storage technology, and it will help to meet the Sustainable Development Goals (SDGs). IEEE 2022 Conference or Workshop Item PeerReviewed Hossain, Md Hasnat and Mohd Radzi, Mohd Amran and Zaed, Md Abu and Rahman, Saidur and Shafie, Suhaidi and Hossain, Md Showkot (2022) Synthesis and thermophysical properties of Ti3C2TX -based vanadium bromide redox flow for green energy storage. In: 2022 IEEE International Conference on Power and Energy (PECon2022), 5-6 Dec. 2022, Langkawi, Kedah, Malaysia. (pp. 132-137). https://ieeexplore.ieee.org/document/9988956 10.1109/PECon54459.2022.9988956
spellingShingle Hossain, Md Hasnat
Mohd Radzi, Mohd Amran
Zaed, Md Abu
Rahman, Saidur
Shafie, Suhaidi
Hossain, Md Showkot
Synthesis and thermophysical properties of Ti3C2TX -based vanadium bromide redox flow for green energy storage
title Synthesis and thermophysical properties of Ti3C2TX -based vanadium bromide redox flow for green energy storage
title_full Synthesis and thermophysical properties of Ti3C2TX -based vanadium bromide redox flow for green energy storage
title_fullStr Synthesis and thermophysical properties of Ti3C2TX -based vanadium bromide redox flow for green energy storage
title_full_unstemmed Synthesis and thermophysical properties of Ti3C2TX -based vanadium bromide redox flow for green energy storage
title_short Synthesis and thermophysical properties of Ti3C2TX -based vanadium bromide redox flow for green energy storage
title_sort synthesis and thermophysical properties of ti3c2tx based vanadium bromide redox flow for green energy storage
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