Reduced graphene oxide-titania nanocomposite-modified photoanode for efficient dye-sensitized solar cells

We report the successful application of reduced graphene oxide–titania (rGO–TiO2) nanocomposite as an efficient photoanode for dye‐sensitized solar cell (DSSC). The DSSC assembled with the rGO–TiO2‐modified photoanode demonstrated an enhanced solar to electrical energy conversion efficiency of 4.74%...

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Main Authors: Lim, Su Pei, Pandikumar, Alagarsamy, Huang, Nay Ming, Lim, Hong Ngee
Format: Article
Language:English
Published: John Wiley & Sons 2015
Online Access:http://psasir.upm.edu.my/id/eprint/46103/1/Reduced%20graphene%20oxide-titania%20nanocomposite-modified%20photoanode%20for%20efficient%20dye-sensitized%20solar%20cells.pdf
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author Lim, Su Pei
Pandikumar, Alagarsamy
Huang, Nay Ming
Lim, Hong Ngee
author_facet Lim, Su Pei
Pandikumar, Alagarsamy
Huang, Nay Ming
Lim, Hong Ngee
author_sort Lim, Su Pei
collection UPM
description We report the successful application of reduced graphene oxide–titania (rGO–TiO2) nanocomposite as an efficient photoanode for dye‐sensitized solar cell (DSSC). The DSSC assembled with the rGO–TiO2‐modified photoanode demonstrated an enhanced solar to electrical energy conversion efficiency of 4.74% compared with the photoanode of DSSC composed with unmodified TiO2 (2.19%) under full sunlight illumination (100 mW/cm2, AM 1.5G) as a result of the better charge collection efficiency of rGO, which reduced the back electron transfer process. Influence of the rGO content on the overall efficiency was also investigated, and the optimal rGO content for TiO2 was 0.5 mg. Further, the modification of rGO–TiO2 on the compact layer TiO2 surface led to an increase in efficiency to 5.83%. The superior charge collection and enhanced solar energy conversion efficiency of the rGO–TiO2 nanocomposite makes it to be used as a promising alternative to conventional photoanode‐based DSSCs.
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spelling upm.eprints-461032018-05-07T07:34:57Z http://psasir.upm.edu.my/id/eprint/46103/ Reduced graphene oxide-titania nanocomposite-modified photoanode for efficient dye-sensitized solar cells Lim, Su Pei Pandikumar, Alagarsamy Huang, Nay Ming Lim, Hong Ngee We report the successful application of reduced graphene oxide–titania (rGO–TiO2) nanocomposite as an efficient photoanode for dye‐sensitized solar cell (DSSC). The DSSC assembled with the rGO–TiO2‐modified photoanode demonstrated an enhanced solar to electrical energy conversion efficiency of 4.74% compared with the photoanode of DSSC composed with unmodified TiO2 (2.19%) under full sunlight illumination (100 mW/cm2, AM 1.5G) as a result of the better charge collection efficiency of rGO, which reduced the back electron transfer process. Influence of the rGO content on the overall efficiency was also investigated, and the optimal rGO content for TiO2 was 0.5 mg. Further, the modification of rGO–TiO2 on the compact layer TiO2 surface led to an increase in efficiency to 5.83%. The superior charge collection and enhanced solar energy conversion efficiency of the rGO–TiO2 nanocomposite makes it to be used as a promising alternative to conventional photoanode‐based DSSCs. John Wiley & Sons 2015 Article PeerReviewed text en http://psasir.upm.edu.my/id/eprint/46103/1/Reduced%20graphene%20oxide-titania%20nanocomposite-modified%20photoanode%20for%20efficient%20dye-sensitized%20solar%20cells.pdf Lim, Su Pei and Pandikumar, Alagarsamy and Huang, Nay Ming and Lim, Hong Ngee (2015) Reduced graphene oxide-titania nanocomposite-modified photoanode for efficient dye-sensitized solar cells. International Journal of Energy Research, 39 (2). pp. 812-824. ISSN 0363-907X http://onlinelibrary.wiley.com/journal/10.1002/(ISSN)1099-114X 10.1002/er.3307
spellingShingle Lim, Su Pei
Pandikumar, Alagarsamy
Huang, Nay Ming
Lim, Hong Ngee
Reduced graphene oxide-titania nanocomposite-modified photoanode for efficient dye-sensitized solar cells
title Reduced graphene oxide-titania nanocomposite-modified photoanode for efficient dye-sensitized solar cells
title_full Reduced graphene oxide-titania nanocomposite-modified photoanode for efficient dye-sensitized solar cells
title_fullStr Reduced graphene oxide-titania nanocomposite-modified photoanode for efficient dye-sensitized solar cells
title_full_unstemmed Reduced graphene oxide-titania nanocomposite-modified photoanode for efficient dye-sensitized solar cells
title_short Reduced graphene oxide-titania nanocomposite-modified photoanode for efficient dye-sensitized solar cells
title_sort reduced graphene oxide titania nanocomposite modified photoanode for efficient dye sensitized solar cells
url http://psasir.upm.edu.my/id/eprint/46103/1/Reduced%20graphene%20oxide-titania%20nanocomposite-modified%20photoanode%20for%20efficient%20dye-sensitized%20solar%20cells.pdf
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AT pandikumaralagarsamy reducedgrapheneoxidetitaniananocompositemodifiedphotoanodeforefficientdyesensitizedsolarcells
AT huangnayming reducedgrapheneoxidetitaniananocompositemodifiedphotoanodeforefficientdyesensitizedsolarcells
AT limhongngee reducedgrapheneoxidetitaniananocompositemodifiedphotoanodeforefficientdyesensitizedsolarcells