Waste ostrich- and chicken-eggshells as heterogeneous base catalyst for biodiesel production from used cooking oil: catalyst characterization and biodiesel yield performance
The primary goal of this paper is to investigate the catalyst characterization and biodiesel yield of a bio- diesel converted from a used cooking oil source via heterogeneous catalysts derived from very rare type of eggshell: ostrich-eggshell (ostrich-eggshell derived CaO). It also aims to compare...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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Pergamon Press
2015
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| Online Access: | http://psasir.upm.edu.my/id/eprint/46877/1/Waste%20ostrich-%20and%20chicken-eggshells%20as%20heterogeneous%20base%20catalyst%20for%20biodiesel%20production%20from%20used%20cooking%20oil%20catalyst%20characterization%20and%20biodiesel%20yield%20performance.pdf |
| _version_ | 1825929758662197248 |
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| author | Yie, Hua Tan Abdullah, Mohammad Omar Hipolito, Cirilo Nolasco Yap, Taufiq Yun Hin |
| author_facet | Yie, Hua Tan Abdullah, Mohammad Omar Hipolito, Cirilo Nolasco Yap, Taufiq Yun Hin |
| author_sort | Yie, Hua Tan |
| collection | UPM |
| description | The primary goal of this paper is to investigate the catalyst characterization and biodiesel yield of a bio-
diesel converted from a used cooking oil source via heterogeneous catalysts derived from very rare type
of eggshell: ostrich-eggshell (ostrich-eggshell derived CaO). It also aims to compare the performance of CaO catalyst derived from both waste ostrich-eggshell and the conventional chicken-eggshell, and to find the optimum conditions for biodiesel production. The prepared catalysts were then characterized by using XRD, FT-IR, BET, SEM, TGA and CO2-TPD. The parametric effects on the biodiesel production, such as catalyst concentration, molar ratio of methanol to oil, reaction temperature, reaction time, speed and reusability of the catalyst were investigated. The experimental result showed that 1.5 wt.% catalyst,12:1 M ratio of methanol to oil, 65°C reaction temperature, 2 h reaction time with speed of 250 rpm gave the best results. It was found that the ostrich-eggshell derived CaO catalyst shows higher surface area,higher basicity and smaller particle size. The maximum biodiesel yield is 96% and 94% for calcined ostrich-eggshell and chicken-eggshell, respectively. The CaO catalyst derived from waste calcined ostrich and chicken-eggshell maintained a good catalytic activity even after being repeatedly used for 5 cycles
with yield around 70%, which implies potential saving and affordable biodiesel production possibilities. |
| first_indexed | 2024-03-06T09:01:24Z |
| format | Article |
| id | upm.eprints-46877 |
| institution | Universiti Putra Malaysia |
| language | English |
| last_indexed | 2024-03-06T09:01:24Z |
| publishDate | 2015 |
| publisher | Pergamon Press |
| record_format | dspace |
| spelling | upm.eprints-468772018-01-30T07:07:52Z http://psasir.upm.edu.my/id/eprint/46877/ Waste ostrich- and chicken-eggshells as heterogeneous base catalyst for biodiesel production from used cooking oil: catalyst characterization and biodiesel yield performance Yie, Hua Tan Abdullah, Mohammad Omar Hipolito, Cirilo Nolasco Yap, Taufiq Yun Hin The primary goal of this paper is to investigate the catalyst characterization and biodiesel yield of a bio- diesel converted from a used cooking oil source via heterogeneous catalysts derived from very rare type of eggshell: ostrich-eggshell (ostrich-eggshell derived CaO). It also aims to compare the performance of CaO catalyst derived from both waste ostrich-eggshell and the conventional chicken-eggshell, and to find the optimum conditions for biodiesel production. The prepared catalysts were then characterized by using XRD, FT-IR, BET, SEM, TGA and CO2-TPD. The parametric effects on the biodiesel production, such as catalyst concentration, molar ratio of methanol to oil, reaction temperature, reaction time, speed and reusability of the catalyst were investigated. The experimental result showed that 1.5 wt.% catalyst,12:1 M ratio of methanol to oil, 65°C reaction temperature, 2 h reaction time with speed of 250 rpm gave the best results. It was found that the ostrich-eggshell derived CaO catalyst shows higher surface area,higher basicity and smaller particle size. The maximum biodiesel yield is 96% and 94% for calcined ostrich-eggshell and chicken-eggshell, respectively. The CaO catalyst derived from waste calcined ostrich and chicken-eggshell maintained a good catalytic activity even after being repeatedly used for 5 cycles with yield around 70%, which implies potential saving and affordable biodiesel production possibilities. Pergamon Press 2015-12-15 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/46877/1/Waste%20ostrich-%20and%20chicken-eggshells%20as%20heterogeneous%20base%20catalyst%20for%20biodiesel%20production%20from%20used%20cooking%20oil%20catalyst%20characterization%20and%20biodiesel%20yield%20performance.pdf Yie, Hua Tan and Abdullah, Mohammad Omar and Hipolito, Cirilo Nolasco and Yap, Taufiq Yun Hin (2015) Waste ostrich- and chicken-eggshells as heterogeneous base catalyst for biodiesel production from used cooking oil: catalyst characterization and biodiesel yield performance. Applied Energy, 160. pp. 58-70. ISSN 0306-2619; ESSN: 1872-9118 http://www.elsevier.com/locate/issn/03062619 10.1016/j.apenergy.2015.09.023 |
| spellingShingle | Yie, Hua Tan Abdullah, Mohammad Omar Hipolito, Cirilo Nolasco Yap, Taufiq Yun Hin Waste ostrich- and chicken-eggshells as heterogeneous base catalyst for biodiesel production from used cooking oil: catalyst characterization and biodiesel yield performance |
| title | Waste ostrich- and chicken-eggshells as heterogeneous base catalyst for biodiesel production from used cooking oil: catalyst characterization and biodiesel yield performance |
| title_full | Waste ostrich- and chicken-eggshells as heterogeneous base catalyst for biodiesel production from used cooking oil: catalyst characterization and biodiesel yield performance |
| title_fullStr | Waste ostrich- and chicken-eggshells as heterogeneous base catalyst for biodiesel production from used cooking oil: catalyst characterization and biodiesel yield performance |
| title_full_unstemmed | Waste ostrich- and chicken-eggshells as heterogeneous base catalyst for biodiesel production from used cooking oil: catalyst characterization and biodiesel yield performance |
| title_short | Waste ostrich- and chicken-eggshells as heterogeneous base catalyst for biodiesel production from used cooking oil: catalyst characterization and biodiesel yield performance |
| title_sort | waste ostrich and chicken eggshells as heterogeneous base catalyst for biodiesel production from used cooking oil catalyst characterization and biodiesel yield performance |
| url | http://psasir.upm.edu.my/id/eprint/46877/1/Waste%20ostrich-%20and%20chicken-eggshells%20as%20heterogeneous%20base%20catalyst%20for%20biodiesel%20production%20from%20used%20cooking%20oil%20catalyst%20characterization%20and%20biodiesel%20yield%20performance.pdf |
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