Decolorisation of crude palm oil by acid-activated spent bleaching earth

Regeneration of spent bleaching earth by acid activation and heat treatment has been investigated. Spent bleaching earth was activated by H2SO4 of various concentrations (1–40%) and heat treated at 120°C–350°C. The experimental results indicate that treatment of spent bleaching earth with 10% H2SO4...

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Main Authors: Low, Kun She, Lee, Chnoong Kheng, Kong, Lee Yong
Format: Article
Language:English
Published: Society of Chemical Industry 1998
Online Access:http://psasir.upm.edu.my/id/eprint/51716/1/51716.pdf
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author Low, Kun She
Lee, Chnoong Kheng
Kong, Lee Yong
author_facet Low, Kun She
Lee, Chnoong Kheng
Kong, Lee Yong
author_sort Low, Kun She
collection UPM
description Regeneration of spent bleaching earth by acid activation and heat treatment has been investigated. Spent bleaching earth was activated by H2SO4 of various concentrations (1–40%) and heat treated at 120°C–350°C. The experimental results indicate that treatment of spent bleaching earth with 10% H2SO4 at 350°C produced a material which was most effective in removing coloured pigments from crude palm oil. Subsequent experiments were conducted using this particular acid-treated spent bleaching earth. Various parameters which affect the sorption process were studied. They include initial crude palm oil concentration, sorbent dosage and temperature. Applicability of both the Freundlich and Langmuir isotherms to the acid-treated spent bleaching earth–palm oil hexane miscella system indicates that both physiosorption and chemisorption were involved in the sorption process. Measurements of various quality parameters of bleached and crude palm oils were carried out. They include Lovibond Colour index, carotene content, peroxide value, free fatty acid, fatty acid composition and iodine value. The results show that the bleached palm oil retained good oil quality after the decolorisation process using 10% acid-treated spent bleaching earth with a Lovibond Colour of 6·4.
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spelling upm.eprints-517162017-09-05T09:07:29Z http://psasir.upm.edu.my/id/eprint/51716/ Decolorisation of crude palm oil by acid-activated spent bleaching earth Low, Kun She Lee, Chnoong Kheng Kong, Lee Yong Regeneration of spent bleaching earth by acid activation and heat treatment has been investigated. Spent bleaching earth was activated by H2SO4 of various concentrations (1–40%) and heat treated at 120°C–350°C. The experimental results indicate that treatment of spent bleaching earth with 10% H2SO4 at 350°C produced a material which was most effective in removing coloured pigments from crude palm oil. Subsequent experiments were conducted using this particular acid-treated spent bleaching earth. Various parameters which affect the sorption process were studied. They include initial crude palm oil concentration, sorbent dosage and temperature. Applicability of both the Freundlich and Langmuir isotherms to the acid-treated spent bleaching earth–palm oil hexane miscella system indicates that both physiosorption and chemisorption were involved in the sorption process. Measurements of various quality parameters of bleached and crude palm oils were carried out. They include Lovibond Colour index, carotene content, peroxide value, free fatty acid, fatty acid composition and iodine value. The results show that the bleached palm oil retained good oil quality after the decolorisation process using 10% acid-treated spent bleaching earth with a Lovibond Colour of 6·4. Society of Chemical Industry 1998 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/51716/1/51716.pdf Low, Kun She and Lee, Chnoong Kheng and Kong, Lee Yong (1998) Decolorisation of crude palm oil by acid-activated spent bleaching earth. Journal of Chemical Technology and Biotechnology, 72 (1). pp. 67-73. ISSN 0268-2575; ESSN: 1097-4660 http://onlinelibrary.wiley.com/doi/10.1002/(SICI)1097-4660(199805)72:1%3C67::AID-JCTB881%3E3.0.CO;2-N/abstract 10.1002/(SICI)1097-4660(199805)72:1<67::AID-JCTB881>3.0.CO;2-N
spellingShingle Low, Kun She
Lee, Chnoong Kheng
Kong, Lee Yong
Decolorisation of crude palm oil by acid-activated spent bleaching earth
title Decolorisation of crude palm oil by acid-activated spent bleaching earth
title_full Decolorisation of crude palm oil by acid-activated spent bleaching earth
title_fullStr Decolorisation of crude palm oil by acid-activated spent bleaching earth
title_full_unstemmed Decolorisation of crude palm oil by acid-activated spent bleaching earth
title_short Decolorisation of crude palm oil by acid-activated spent bleaching earth
title_sort decolorisation of crude palm oil by acid activated spent bleaching earth
url http://psasir.upm.edu.my/id/eprint/51716/1/51716.pdf
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