Facile synthesis of calcium borate nanoparticles and the annealing effect on their structure and size

Calcium borate nanoparticles have been synthesized by a thermal treatment method via facile co-precipitation. Differences of annealing temperature and annealing time and their effects on crystal structure, particle size, size distribution and thermal stability of nanoparticles were investigated. The...

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Main Authors: Haghiri, Maryam Erfani, Saion, Elias, Soltani, Nayereh, Hashim, Mansor, Wan Abdullah, Wan Saffiey, Navasery, Manizheh
Format: Article
Language:English
Published: MDPI AG 2012
Online Access:http://psasir.upm.edu.my/id/eprint/52280/1/52280.pdf
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author Haghiri, Maryam Erfani
Saion, Elias
Soltani, Nayereh
Hashim, Mansor
Wan Abdullah, Wan Saffiey
Navasery, Manizheh
author_facet Haghiri, Maryam Erfani
Saion, Elias
Soltani, Nayereh
Hashim, Mansor
Wan Abdullah, Wan Saffiey
Navasery, Manizheh
author_sort Haghiri, Maryam Erfani
collection UPM
description Calcium borate nanoparticles have been synthesized by a thermal treatment method via facile co-precipitation. Differences of annealing temperature and annealing time and their effects on crystal structure, particle size, size distribution and thermal stability of nanoparticles were investigated. The formation of calcium borate compound was characterized by X-ray diffraction (XRD) and Fourier Transform Infrared spectroscopy (FTIR), Transmission electron microscopy (TEM), and Thermogravimetry (TGA). The XRD patterns revealed that the co-precipitated samples annealed at 700 °C for 3 h annealing time formed an amorphous structure and the transformation into a crystalline structure only occurred after 5 h annealing time. It was found that the samples annealed at 900 °C are mostly metaborate (CaB2O4) nanoparticles and tetraborate (CaB4O7) nanoparticles only observed at 970 °C, which was confirmed by FTIR. The TEM images indicated that with increasing the annealing time and temperature, the average particle size increases. TGA analysis confirmed the thermal stability of the annealed samples at higher temperatures.
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spelling upm.eprints-522802017-06-05T05:33:21Z http://psasir.upm.edu.my/id/eprint/52280/ Facile synthesis of calcium borate nanoparticles and the annealing effect on their structure and size Haghiri, Maryam Erfani Saion, Elias Soltani, Nayereh Hashim, Mansor Wan Abdullah, Wan Saffiey Navasery, Manizheh Calcium borate nanoparticles have been synthesized by a thermal treatment method via facile co-precipitation. Differences of annealing temperature and annealing time and their effects on crystal structure, particle size, size distribution and thermal stability of nanoparticles were investigated. The formation of calcium borate compound was characterized by X-ray diffraction (XRD) and Fourier Transform Infrared spectroscopy (FTIR), Transmission electron microscopy (TEM), and Thermogravimetry (TGA). The XRD patterns revealed that the co-precipitated samples annealed at 700 °C for 3 h annealing time formed an amorphous structure and the transformation into a crystalline structure only occurred after 5 h annealing time. It was found that the samples annealed at 900 °C are mostly metaborate (CaB2O4) nanoparticles and tetraborate (CaB4O7) nanoparticles only observed at 970 °C, which was confirmed by FTIR. The TEM images indicated that with increasing the annealing time and temperature, the average particle size increases. TGA analysis confirmed the thermal stability of the annealed samples at higher temperatures. MDPI AG 2012 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/52280/1/52280.pdf Haghiri, Maryam Erfani and Saion, Elias and Soltani, Nayereh and Hashim, Mansor and Wan Abdullah, Wan Saffiey and Navasery, Manizheh (2012) Facile synthesis of calcium borate nanoparticles and the annealing effect on their structure and size. International Journal of Molecular Sciences, 13 (11). pp. 14434-14445. ISSN 1422-0067 http://www.mdpi.com/1422-0067/13/11/14434 10.3390/ijms131114434
spellingShingle Haghiri, Maryam Erfani
Saion, Elias
Soltani, Nayereh
Hashim, Mansor
Wan Abdullah, Wan Saffiey
Navasery, Manizheh
Facile synthesis of calcium borate nanoparticles and the annealing effect on their structure and size
title Facile synthesis of calcium borate nanoparticles and the annealing effect on their structure and size
title_full Facile synthesis of calcium borate nanoparticles and the annealing effect on their structure and size
title_fullStr Facile synthesis of calcium borate nanoparticles and the annealing effect on their structure and size
title_full_unstemmed Facile synthesis of calcium borate nanoparticles and the annealing effect on their structure and size
title_short Facile synthesis of calcium borate nanoparticles and the annealing effect on their structure and size
title_sort facile synthesis of calcium borate nanoparticles and the annealing effect on their structure and size
url http://psasir.upm.edu.my/id/eprint/52280/1/52280.pdf
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