Selectivity of Candida rugosa Lipase immobilized onto layered double hydroxides as catalyst in synthesis of fatty acid esters

The enzymatic selectivity of Lipase from Candida rugosa immobilized onto a calcined layered double hydroxide (CLDHs-CRL) towards the chain-length of fatty acids and alcohols in the synthesis of fatty acid esters was investigated. The results showed that CMAN-CRL catalyzed the esterification process...

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Main Authors: Abdul Rahman, Mohd Basyaruddin, Othman, Siti Salhah, Md Yunus, Noor Mona
Format: Article
Language:English
Published: Universiti Teknologi Malaysia Press 2016
Online Access:http://psasir.upm.edu.my/id/eprint/53790/1/Selectivity%20of%20Candida%20rugosa%20Lipase%20immobilized%20onto%20layered%20double%20hydroxides%20as%20catalyst%20in%20synthesis%20of%20fatty%20acid%20esters.pdf
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author Abdul Rahman, Mohd Basyaruddin
Othman, Siti Salhah
Md Yunus, Noor Mona
author_facet Abdul Rahman, Mohd Basyaruddin
Othman, Siti Salhah
Md Yunus, Noor Mona
author_sort Abdul Rahman, Mohd Basyaruddin
collection UPM
description The enzymatic selectivity of Lipase from Candida rugosa immobilized onto a calcined layered double hydroxide (CLDHs-CRL) towards the chain-length of fatty acids and alcohols in the synthesis of fatty acid esters was investigated. The results showed that CMAN-CRL catalyzed the esterification process with fatty acids of medium chain lengths (C10-C14) effectively while, CNAN-CRL and CZAN-CRL exhibited high percentage conversion in fatty acids with carbon chain lengths of C8-C12 and C10-C18, respectively. In the alcohol selectivity study, CMAN-CRL showed high selectivity toward alcohols with carbon chain lengths of C4, C6 and C10. On the other hand, both CNAN-CRL and CZAN-CRL exhibited rather low selectivity towards longer carbon chain length of alcohols.
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spelling upm.eprints-537902018-02-01T08:59:37Z http://psasir.upm.edu.my/id/eprint/53790/ Selectivity of Candida rugosa Lipase immobilized onto layered double hydroxides as catalyst in synthesis of fatty acid esters Abdul Rahman, Mohd Basyaruddin Othman, Siti Salhah Md Yunus, Noor Mona The enzymatic selectivity of Lipase from Candida rugosa immobilized onto a calcined layered double hydroxide (CLDHs-CRL) towards the chain-length of fatty acids and alcohols in the synthesis of fatty acid esters was investigated. The results showed that CMAN-CRL catalyzed the esterification process with fatty acids of medium chain lengths (C10-C14) effectively while, CNAN-CRL and CZAN-CRL exhibited high percentage conversion in fatty acids with carbon chain lengths of C8-C12 and C10-C18, respectively. In the alcohol selectivity study, CMAN-CRL showed high selectivity toward alcohols with carbon chain lengths of C4, C6 and C10. On the other hand, both CNAN-CRL and CZAN-CRL exhibited rather low selectivity towards longer carbon chain length of alcohols. Universiti Teknologi Malaysia Press 2016-05 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/53790/1/Selectivity%20of%20Candida%20rugosa%20Lipase%20immobilized%20onto%20layered%20double%20hydroxides%20as%20catalyst%20in%20synthesis%20of%20fatty%20acid%20esters.pdf Abdul Rahman, Mohd Basyaruddin and Othman, Siti Salhah and Md Yunus, Noor Mona (2016) Selectivity of Candida rugosa Lipase immobilized onto layered double hydroxides as catalyst in synthesis of fatty acid esters. Jurnal Teknologi, 78 (5-6). pp. 111-115. ISSN 0127–9696; ESSN: 2180–3722 http://www.myjurnal.my/public/article-view.php?id=95126
spellingShingle Abdul Rahman, Mohd Basyaruddin
Othman, Siti Salhah
Md Yunus, Noor Mona
Selectivity of Candida rugosa Lipase immobilized onto layered double hydroxides as catalyst in synthesis of fatty acid esters
title Selectivity of Candida rugosa Lipase immobilized onto layered double hydroxides as catalyst in synthesis of fatty acid esters
title_full Selectivity of Candida rugosa Lipase immobilized onto layered double hydroxides as catalyst in synthesis of fatty acid esters
title_fullStr Selectivity of Candida rugosa Lipase immobilized onto layered double hydroxides as catalyst in synthesis of fatty acid esters
title_full_unstemmed Selectivity of Candida rugosa Lipase immobilized onto layered double hydroxides as catalyst in synthesis of fatty acid esters
title_short Selectivity of Candida rugosa Lipase immobilized onto layered double hydroxides as catalyst in synthesis of fatty acid esters
title_sort selectivity of candida rugosa lipase immobilized onto layered double hydroxides as catalyst in synthesis of fatty acid esters
url http://psasir.upm.edu.my/id/eprint/53790/1/Selectivity%20of%20Candida%20rugosa%20Lipase%20immobilized%20onto%20layered%20double%20hydroxides%20as%20catalyst%20in%20synthesis%20of%20fatty%20acid%20esters.pdf
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AT mdyunusnoormona selectivityofcandidarugosalipaseimmobilizedontolayereddoublehydroxidesascatalystinsynthesisoffattyacidesters