Optical properties of zinc borotellurite glass doped with trivalent dysprosium ion
The zinc borotellurite doped with dysprosium oxide glass samples with chemical formula {[(TeO2)0.7(B2O3)0.3]0.7(ZnO)0.3}1−x(Dy2O3)x (where x=0.01, 0.02, 0.03, 0.04 and 0.05 M fraction) were prepared by using conventional melt quenching technique. The structural and optical properties of the proposed...
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| Format: | Article |
| Language: | English |
| Published: |
Elsevier
2017
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| Online Access: | http://psasir.upm.edu.my/id/eprint/54559/1/Optical%20properties%20of%20zinc%20borotellurite%20glass%20doped%20with%20trivalent%20dysprosium%20ion.pdf |
| _version_ | 1796976106570514432 |
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| author | Mohd Nor, Ami Hazlin Mohamed Kamari, Halimah Muhammad, Farah Diana Mohd Fudzi, Faznny |
| author_facet | Mohd Nor, Ami Hazlin Mohamed Kamari, Halimah Muhammad, Farah Diana Mohd Fudzi, Faznny |
| author_sort | Mohd Nor, Ami Hazlin |
| collection | UPM |
| description | The zinc borotellurite doped with dysprosium oxide glass samples with chemical formula {[(TeO2)0.7(B2O3)0.3]0.7(ZnO)0.3}1−x(Dy2O3)x (where x=0.01, 0.02, 0.03, 0.04 and 0.05 M fraction) were prepared by using conventional melt quenching technique. The structural and optical properties of the proposed glass systems were characterized by using X-ray diffraction (XRD) spectroscopy, Fourier Transform Infrared (FTIR) spectroscopy, and UV–VIS spectroscopy. The amorphous nature of the glass systems is confirmed by using XRD technique. The infrared spectra of the glass systems indicate three obvious absorption bands which are assigned to BO3 and TeO4 vibrational groups. Based on the absorption spectra obtained, the direct and indirect optical band gaps, as well as the Urbach energy were calculated. It is observed that both the direct and indirect optical band gaps increase with the concentration of Dy3+ ions. On the other hand, the Urbach energy is observed to decrease as the concentration of Dy3+ ions increases. |
| first_indexed | 2024-03-06T09:21:02Z |
| format | Article |
| id | upm.eprints-54559 |
| institution | Universiti Putra Malaysia |
| language | English |
| last_indexed | 2024-03-06T09:21:02Z |
| publishDate | 2017 |
| publisher | Elsevier |
| record_format | dspace |
| spelling | upm.eprints-545592020-03-10T01:24:26Z http://psasir.upm.edu.my/id/eprint/54559/ Optical properties of zinc borotellurite glass doped with trivalent dysprosium ion Mohd Nor, Ami Hazlin Mohamed Kamari, Halimah Muhammad, Farah Diana Mohd Fudzi, Faznny The zinc borotellurite doped with dysprosium oxide glass samples with chemical formula {[(TeO2)0.7(B2O3)0.3]0.7(ZnO)0.3}1−x(Dy2O3)x (where x=0.01, 0.02, 0.03, 0.04 and 0.05 M fraction) were prepared by using conventional melt quenching technique. The structural and optical properties of the proposed glass systems were characterized by using X-ray diffraction (XRD) spectroscopy, Fourier Transform Infrared (FTIR) spectroscopy, and UV–VIS spectroscopy. The amorphous nature of the glass systems is confirmed by using XRD technique. The infrared spectra of the glass systems indicate three obvious absorption bands which are assigned to BO3 and TeO4 vibrational groups. Based on the absorption spectra obtained, the direct and indirect optical band gaps, as well as the Urbach energy were calculated. It is observed that both the direct and indirect optical band gaps increase with the concentration of Dy3+ ions. On the other hand, the Urbach energy is observed to decrease as the concentration of Dy3+ ions increases. Elsevier 2017-04 Article PeerReviewed text en http://psasir.upm.edu.my/id/eprint/54559/1/Optical%20properties%20of%20zinc%20borotellurite%20glass%20doped%20with%20trivalent%20dysprosium%20ion.pdf Mohd Nor, Ami Hazlin and Mohamed Kamari, Halimah and Muhammad, Farah Diana and Mohd Fudzi, Faznny (2017) Optical properties of zinc borotellurite glass doped with trivalent dysprosium ion. Physica B: Condensed Matter, 510. pp. 38-42. ISSN 0921-4526; ESSN: 1873-2135 https://www.sciencedirect.com/science/article/pii/S0921452617300212#! 10.1016/j.physb.2017.01.012 |
| spellingShingle | Mohd Nor, Ami Hazlin Mohamed Kamari, Halimah Muhammad, Farah Diana Mohd Fudzi, Faznny Optical properties of zinc borotellurite glass doped with trivalent dysprosium ion |
| title | Optical properties of zinc borotellurite glass doped with trivalent dysprosium ion |
| title_full | Optical properties of zinc borotellurite glass doped with trivalent dysprosium ion |
| title_fullStr | Optical properties of zinc borotellurite glass doped with trivalent dysprosium ion |
| title_full_unstemmed | Optical properties of zinc borotellurite glass doped with trivalent dysprosium ion |
| title_short | Optical properties of zinc borotellurite glass doped with trivalent dysprosium ion |
| title_sort | optical properties of zinc borotellurite glass doped with trivalent dysprosium ion |
| url | http://psasir.upm.edu.my/id/eprint/54559/1/Optical%20properties%20of%20zinc%20borotellurite%20glass%20doped%20with%20trivalent%20dysprosium%20ion.pdf |
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