Core/shell structure of Ni/NiO encapsulated in carbon nanosphere coated with few- and multi-layered graphene: synthesis, mechanism and application

This paper focuses on the synthesis and mechanism of carbon nanospheres (CNS) coated with few- and multi-layered graphene (FLG, MLG). The graphitic carbon encapsulates the core/shell structure of the Ni/NiO nanoparticles via the chemical vapor deposition (CVD) method. The application of the resultin...

Full description

Bibliographic Details
Main Authors: Ghaemi, Ferial, Abdullah, Luqman Chuah, Tahir, Paridah
Format: Article
Language:English
Published: MDPI 2016
Online Access:http://psasir.upm.edu.my/id/eprint/55384/1/CoreShell%20Structure%20of%20NiNiO%20Encapsulated%20in.pdf
_version_ 1825931208097267712
author Ghaemi, Ferial
Abdullah, Luqman Chuah
Tahir, Paridah
author_facet Ghaemi, Ferial
Abdullah, Luqman Chuah
Tahir, Paridah
author_sort Ghaemi, Ferial
collection UPM
description This paper focuses on the synthesis and mechanism of carbon nanospheres (CNS) coated with few- and multi-layered graphene (FLG, MLG). The graphitic carbon encapsulates the core/shell structure of the Ni/NiO nanoparticles via the chemical vapor deposition (CVD) method. The application of the resulting CNS and hybrids of CNS-FLG and CNS-MLG as reinforcement nanofillers in a polypropylene (PP) matrix were studied from the aspects of mechanical and thermal characteristics. In this research, to synthesize carbon nanostructures, nickel nitrate hexahydrate (Ni(NO3)2·6H2O) and acetylene (C2H2) were used as the catalyst source and carbon source, respectively. Besides, the morphology, structure and graphitization of the resulting carbon nanostructures were investigated. On the other hand, the mechanisms of CNS growth and the synthesis of graphene sheets on the CNS surface were studied. Finally, the mechanical and thermal properties of the CNS/PP, CNS-FLG/PP, and CNS-MLG/PP composites were analyzed by applying tensile test and thermogravimetric analysis (TGA), respectively.
first_indexed 2024-03-06T09:23:15Z
format Article
id upm.eprints-55384
institution Universiti Putra Malaysia
language English
last_indexed 2024-03-06T09:23:15Z
publishDate 2016
publisher MDPI
record_format dspace
spelling upm.eprints-553842017-11-03T06:35:50Z http://psasir.upm.edu.my/id/eprint/55384/ Core/shell structure of Ni/NiO encapsulated in carbon nanosphere coated with few- and multi-layered graphene: synthesis, mechanism and application Ghaemi, Ferial Abdullah, Luqman Chuah Tahir, Paridah This paper focuses on the synthesis and mechanism of carbon nanospheres (CNS) coated with few- and multi-layered graphene (FLG, MLG). The graphitic carbon encapsulates the core/shell structure of the Ni/NiO nanoparticles via the chemical vapor deposition (CVD) method. The application of the resulting CNS and hybrids of CNS-FLG and CNS-MLG as reinforcement nanofillers in a polypropylene (PP) matrix were studied from the aspects of mechanical and thermal characteristics. In this research, to synthesize carbon nanostructures, nickel nitrate hexahydrate (Ni(NO3)2·6H2O) and acetylene (C2H2) were used as the catalyst source and carbon source, respectively. Besides, the morphology, structure and graphitization of the resulting carbon nanostructures were investigated. On the other hand, the mechanisms of CNS growth and the synthesis of graphene sheets on the CNS surface were studied. Finally, the mechanical and thermal properties of the CNS/PP, CNS-FLG/PP, and CNS-MLG/PP composites were analyzed by applying tensile test and thermogravimetric analysis (TGA), respectively. MDPI 2016 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/55384/1/CoreShell%20Structure%20of%20NiNiO%20Encapsulated%20in.pdf Ghaemi, Ferial and Abdullah, Luqman Chuah and Tahir, Paridah (2016) Core/shell structure of Ni/NiO encapsulated in carbon nanosphere coated with few- and multi-layered graphene: synthesis, mechanism and application. Polymers, 8 (381). pp. 1-12. ISSN 2073-4360 http://www.mdpi.com/2073-4360/8/11/381 10.3390/polym8110381
spellingShingle Ghaemi, Ferial
Abdullah, Luqman Chuah
Tahir, Paridah
Core/shell structure of Ni/NiO encapsulated in carbon nanosphere coated with few- and multi-layered graphene: synthesis, mechanism and application
title Core/shell structure of Ni/NiO encapsulated in carbon nanosphere coated with few- and multi-layered graphene: synthesis, mechanism and application
title_full Core/shell structure of Ni/NiO encapsulated in carbon nanosphere coated with few- and multi-layered graphene: synthesis, mechanism and application
title_fullStr Core/shell structure of Ni/NiO encapsulated in carbon nanosphere coated with few- and multi-layered graphene: synthesis, mechanism and application
title_full_unstemmed Core/shell structure of Ni/NiO encapsulated in carbon nanosphere coated with few- and multi-layered graphene: synthesis, mechanism and application
title_short Core/shell structure of Ni/NiO encapsulated in carbon nanosphere coated with few- and multi-layered graphene: synthesis, mechanism and application
title_sort core shell structure of ni nio encapsulated in carbon nanosphere coated with few and multi layered graphene synthesis mechanism and application
url http://psasir.upm.edu.my/id/eprint/55384/1/CoreShell%20Structure%20of%20NiNiO%20Encapsulated%20in.pdf
work_keys_str_mv AT ghaemiferial coreshellstructureofninioencapsulatedincarbonnanospherecoatedwithfewandmultilayeredgraphenesynthesismechanismandapplication
AT abdullahluqmanchuah coreshellstructureofninioencapsulatedincarbonnanospherecoatedwithfewandmultilayeredgraphenesynthesismechanismandapplication
AT tahirparidah coreshellstructureofninioencapsulatedincarbonnanospherecoatedwithfewandmultilayeredgraphenesynthesismechanismandapplication