New coumarin and dihydrocinnamic acid derivatives from two Malaysian populations of Micromelum minutum

Three novel compounds, two compounds and a dihydrocinnamic acid, have been isolated from two collections of Micromelum minutum and identified by means of NMR spectroscopy. A sample collected from Pahang gave the typical coumarin micromelin and a new dihydrocinnamic acid derivative of micromelin whic...

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Main Authors: Rahmani, Mawardi, Yap, Taufiq Yun Hin, Mohd Ismail, Hazar Bebe, Md. Sukari, Mohd Aspollah, Waterman, Peter G.
Format: Article
Language:English
Published: Elsevier Science 1994
Online Access:http://psasir.upm.edu.my/id/eprint/56240/1/New%20coumarin%20and%20dihydrocinnamic%20acid%20derivatives%20from%20two%20Malaysian%20populations%20of%20Micromelum%20minutum.pdf
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author Rahmani, Mawardi
Yap, Taufiq Yun Hin
Mohd Ismail, Hazar Bebe
Md. Sukari, Mohd Aspollah
Waterman, Peter G.
author_facet Rahmani, Mawardi
Yap, Taufiq Yun Hin
Mohd Ismail, Hazar Bebe
Md. Sukari, Mohd Aspollah
Waterman, Peter G.
author_sort Rahmani, Mawardi
collection UPM
description Three novel compounds, two compounds and a dihydrocinnamic acid, have been isolated from two collections of Micromelum minutum and identified by means of NMR spectroscopy. A sample collected from Pahang gave the typical coumarin micromelin and a new dihydrocinnamic acid derivative of micromelin which was identified as 1,2-seco-dihydromicromelin. The second sample, collected from Kelantan, gave two new tetracyclic coumarins, microminutinin and 6-methoxymicrominutinin, which possess a fused bifurano system that appears to be derived by cyclization of a 7-oxygenated-8-(1,2-dimethyl)propylcoumarin precursor. The structure of microminutinin is revised from that proposed in a previous paper.
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spelling upm.eprints-562402017-07-04T02:48:02Z http://psasir.upm.edu.my/id/eprint/56240/ New coumarin and dihydrocinnamic acid derivatives from two Malaysian populations of Micromelum minutum Rahmani, Mawardi Yap, Taufiq Yun Hin Mohd Ismail, Hazar Bebe Md. Sukari, Mohd Aspollah Waterman, Peter G. Three novel compounds, two compounds and a dihydrocinnamic acid, have been isolated from two collections of Micromelum minutum and identified by means of NMR spectroscopy. A sample collected from Pahang gave the typical coumarin micromelin and a new dihydrocinnamic acid derivative of micromelin which was identified as 1,2-seco-dihydromicromelin. The second sample, collected from Kelantan, gave two new tetracyclic coumarins, microminutinin and 6-methoxymicrominutinin, which possess a fused bifurano system that appears to be derived by cyclization of a 7-oxygenated-8-(1,2-dimethyl)propylcoumarin precursor. The structure of microminutinin is revised from that proposed in a previous paper. Elsevier Science 1994 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/56240/1/New%20coumarin%20and%20dihydrocinnamic%20acid%20derivatives%20from%20two%20Malaysian%20populations%20of%20Micromelum%20minutum.pdf Rahmani, Mawardi and Yap, Taufiq Yun Hin and Mohd Ismail, Hazar Bebe and Md. Sukari, Mohd Aspollah and Waterman, Peter G. (1994) New coumarin and dihydrocinnamic acid derivatives from two Malaysian populations of Micromelum minutum. Phytochemistry, 37 (2). pp. 561-564. ISSN 0031-9422; ESSN: 1873-3700 http://www.sciencedirect.com/science/article/pii/003194229485100X# 10.1016/0031-9422(94)85100-X
spellingShingle Rahmani, Mawardi
Yap, Taufiq Yun Hin
Mohd Ismail, Hazar Bebe
Md. Sukari, Mohd Aspollah
Waterman, Peter G.
New coumarin and dihydrocinnamic acid derivatives from two Malaysian populations of Micromelum minutum
title New coumarin and dihydrocinnamic acid derivatives from two Malaysian populations of Micromelum minutum
title_full New coumarin and dihydrocinnamic acid derivatives from two Malaysian populations of Micromelum minutum
title_fullStr New coumarin and dihydrocinnamic acid derivatives from two Malaysian populations of Micromelum minutum
title_full_unstemmed New coumarin and dihydrocinnamic acid derivatives from two Malaysian populations of Micromelum minutum
title_short New coumarin and dihydrocinnamic acid derivatives from two Malaysian populations of Micromelum minutum
title_sort new coumarin and dihydrocinnamic acid derivatives from two malaysian populations of micromelum minutum
url http://psasir.upm.edu.my/id/eprint/56240/1/New%20coumarin%20and%20dihydrocinnamic%20acid%20derivatives%20from%20two%20Malaysian%20populations%20of%20Micromelum%20minutum.pdf
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