Pr0.67Ba0.33MnO3 in bulk and thin film ceramic

Bulk polycrystalline of Pr0.67Ba0.33MnO3 (PBMO) ceramic prepared via solid‐state reaction and converted into thin films on corning glass, fused silica and MgO (100) by pulsed laser deposition (PLD) technique. As compared to bulk PBMO, the unit cell in thin film PBMO experienced positive misfit due t...

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Main Authors: Wong, Jen Kuen, Lim, Kean Pah, Shaari, Abdul Halim, Chen, Soo Kien, Ng, Siau Wei, Gan, Albert Han Ming
Format: Conference or Workshop Item
Language:English
Published: American Institute of Physics 2010
Online Access:http://psasir.upm.edu.my/id/eprint/57369/1/Pr0.67Ba0.33MnO3%20in%20bulk%20and%20thin%20film%20ceramic.pdf
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author Wong, Jen Kuen
Lim, Kean Pah
Shaari, Abdul Halim
Chen, Soo Kien
Ng, Siau Wei
Gan, Albert Han Ming
author_facet Wong, Jen Kuen
Lim, Kean Pah
Shaari, Abdul Halim
Chen, Soo Kien
Ng, Siau Wei
Gan, Albert Han Ming
author_sort Wong, Jen Kuen
collection UPM
description Bulk polycrystalline of Pr0.67Ba0.33MnO3 (PBMO) ceramic prepared via solid‐state reaction and converted into thin films on corning glass, fused silica and MgO (100) by pulsed laser deposition (PLD) technique. As compared to bulk PBMO, the unit cell in thin film PBMO experienced positive misfit due to lattice strain induced by substrate used resulting MnO6 to deform (change in Mn‐O‐Mn bond angle and Mn‐O bond length). Bulk PBMO had large grains (∼1.5μm) as compared to thin film which are nano‐sized (<100 nm). Two metal‐insulator transition temperatures, TP (156 K and 190 K) were observed in bulk due to core‐shell effect as proposed by Zhang et al.. In summary, variation of electrical behaviour was observed between bulk and thin film samples which believed to be due to the difference of ordering in core (body) and grain surface.
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spelling upm.eprints-573692017-09-27T02:44:05Z http://psasir.upm.edu.my/id/eprint/57369/ Pr0.67Ba0.33MnO3 in bulk and thin film ceramic Wong, Jen Kuen Lim, Kean Pah Shaari, Abdul Halim Chen, Soo Kien Ng, Siau Wei Gan, Albert Han Ming Bulk polycrystalline of Pr0.67Ba0.33MnO3 (PBMO) ceramic prepared via solid‐state reaction and converted into thin films on corning glass, fused silica and MgO (100) by pulsed laser deposition (PLD) technique. As compared to bulk PBMO, the unit cell in thin film PBMO experienced positive misfit due to lattice strain induced by substrate used resulting MnO6 to deform (change in Mn‐O‐Mn bond angle and Mn‐O bond length). Bulk PBMO had large grains (∼1.5μm) as compared to thin film which are nano‐sized (<100 nm). Two metal‐insulator transition temperatures, TP (156 K and 190 K) were observed in bulk due to core‐shell effect as proposed by Zhang et al.. In summary, variation of electrical behaviour was observed between bulk and thin film samples which believed to be due to the difference of ordering in core (body) and grain surface. American Institute of Physics 2010 Conference or Workshop Item PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/57369/1/Pr0.67Ba0.33MnO3%20in%20bulk%20and%20thin%20film%20ceramic.pdf Wong, Jen Kuen and Lim, Kean Pah and Shaari, Abdul Halim and Chen, Soo Kien and Ng, Siau Wei and Gan, Albert Han Ming (2010) Pr0.67Ba0.33MnO3 in bulk and thin film ceramic. In: Malaysia Annual Physics Conference 2010 (PERFIK‐2010), 27-30 Oct. 2010, Damai Laut, Perak, Malaysia. (pp. 251-253). 10.1063/1.3573745
spellingShingle Wong, Jen Kuen
Lim, Kean Pah
Shaari, Abdul Halim
Chen, Soo Kien
Ng, Siau Wei
Gan, Albert Han Ming
Pr0.67Ba0.33MnO3 in bulk and thin film ceramic
title Pr0.67Ba0.33MnO3 in bulk and thin film ceramic
title_full Pr0.67Ba0.33MnO3 in bulk and thin film ceramic
title_fullStr Pr0.67Ba0.33MnO3 in bulk and thin film ceramic
title_full_unstemmed Pr0.67Ba0.33MnO3 in bulk and thin film ceramic
title_short Pr0.67Ba0.33MnO3 in bulk and thin film ceramic
title_sort pr0 67ba0 33mno3 in bulk and thin film ceramic
url http://psasir.upm.edu.my/id/eprint/57369/1/Pr0.67Ba0.33MnO3%20in%20bulk%20and%20thin%20film%20ceramic.pdf
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