Sorption removal of arsenic by cerium-exchanged zeolite P

Modification of zeolite P was performed by exchanged of its sodium with cerium(III). The resulting cerium-exchanged zeolite P, (CeZP) did not change in its crystallinity compared to original zeolite. The CeZP was subsequently used to sorb As(V) from aqueous solution. Maximum sorption of As(V) by CeZ...

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Main Authors: Haron, Md. Jelas, Ab Rahim, Farha, Abdullah, Abdul Halim, Hussein, Mohd Zobir, Kassim, Anuar
Format: Article
Language:English
Published: Elsevier 2008
Online Access:http://psasir.upm.edu.my/id/eprint/5812/1/Sorption%20removal%20of%20arsenic%20by%20cerium-exchanged%20zeolite%20P.pdf
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author Haron, Md. Jelas
Ab Rahim, Farha
Abdullah, Abdul Halim
Hussein, Mohd Zobir
Kassim, Anuar
author_facet Haron, Md. Jelas
Ab Rahim, Farha
Abdullah, Abdul Halim
Hussein, Mohd Zobir
Kassim, Anuar
author_sort Haron, Md. Jelas
collection UPM
description Modification of zeolite P was performed by exchanged of its sodium with cerium(III). The resulting cerium-exchanged zeolite P, (CeZP) did not change in its crystallinity compared to original zeolite. The CeZP was subsequently used to sorb As(V) from aqueous solution. Maximum sorption of As(V) by CeZP occurred at pH range 3–10. In addition, the sorption capacity increased with increasing initial As(V) concentrations. The sorption follows Langmuir model with maximum sorption capacity of 8.72 mg g−1 at 25°C and increased to 23.42 mg g−1 at 90°C, indicating an endothermic process. The arsenic sorption by CeZP was not affected by the present of nitrate, chloride, sulphate, carbonate and bromide but was reduced significantly in the presence of phosphate. This study shows that the as prepared CeZP was found effective for the removal of arsenic from wastewater sample of wood treatment industry.
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spelling upm.eprints-58122015-12-02T03:18:58Z http://psasir.upm.edu.my/id/eprint/5812/ Sorption removal of arsenic by cerium-exchanged zeolite P Haron, Md. Jelas Ab Rahim, Farha Abdullah, Abdul Halim Hussein, Mohd Zobir Kassim, Anuar Modification of zeolite P was performed by exchanged of its sodium with cerium(III). The resulting cerium-exchanged zeolite P, (CeZP) did not change in its crystallinity compared to original zeolite. The CeZP was subsequently used to sorb As(V) from aqueous solution. Maximum sorption of As(V) by CeZP occurred at pH range 3–10. In addition, the sorption capacity increased with increasing initial As(V) concentrations. The sorption follows Langmuir model with maximum sorption capacity of 8.72 mg g−1 at 25°C and increased to 23.42 mg g−1 at 90°C, indicating an endothermic process. The arsenic sorption by CeZP was not affected by the present of nitrate, chloride, sulphate, carbonate and bromide but was reduced significantly in the presence of phosphate. This study shows that the as prepared CeZP was found effective for the removal of arsenic from wastewater sample of wood treatment industry. Elsevier 2008-03 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/5812/1/Sorption%20removal%20of%20arsenic%20by%20cerium-exchanged%20zeolite%20P.pdf Haron, Md. Jelas and Ab Rahim, Farha and Abdullah, Abdul Halim and Hussein, Mohd Zobir and Kassim, Anuar (2008) Sorption removal of arsenic by cerium-exchanged zeolite P. Materials Science and Engineering: B, 149 (2). pp. 204-208. ISSN 0921-5107 10.1016/j.mseb.2007.11.028
spellingShingle Haron, Md. Jelas
Ab Rahim, Farha
Abdullah, Abdul Halim
Hussein, Mohd Zobir
Kassim, Anuar
Sorption removal of arsenic by cerium-exchanged zeolite P
title Sorption removal of arsenic by cerium-exchanged zeolite P
title_full Sorption removal of arsenic by cerium-exchanged zeolite P
title_fullStr Sorption removal of arsenic by cerium-exchanged zeolite P
title_full_unstemmed Sorption removal of arsenic by cerium-exchanged zeolite P
title_short Sorption removal of arsenic by cerium-exchanged zeolite P
title_sort sorption removal of arsenic by cerium exchanged zeolite p
url http://psasir.upm.edu.my/id/eprint/5812/1/Sorption%20removal%20of%20arsenic%20by%20cerium-exchanged%20zeolite%20P.pdf
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