Assessing the kinetic model of hydro-distillation and chemical composition of Aquilaria malaccensis leaves essential oil

This study aimed to model the kinetic of hydro-distillation of Aquilaria malaccensis leaves oil in order to understand and optimize the extraction process. In addition, this study, for the first time, aimed to identify the chemical compositions of the A. malaccensis leave-oil. By assessing both firs...

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Main Authors: Samadi, Mahtab, Zainal Abidin, Zurina, Yunus, Robiah, Awang Biak, Dayang Radiah, Yoshida, Hiroyuki, Eng, Hai Lok
Format: Article
Language:English
Published: The Chemical Industry and Engineering Society of China, and Chemical Industry Press 2017
Online Access:http://psasir.upm.edu.my/id/eprint/60937/1/Assessing%20the%20kinetic%20model%20of%20hydro-distillation%20and%20chemical%20composition%20of%20Aquilaria%20malaccensis%20leaves%20essential%20oil.pdf
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author Samadi, Mahtab
Zainal Abidin, Zurina
Yunus, Robiah
Awang Biak, Dayang Radiah
Yoshida, Hiroyuki
Eng, Hai Lok
author_facet Samadi, Mahtab
Zainal Abidin, Zurina
Yunus, Robiah
Awang Biak, Dayang Radiah
Yoshida, Hiroyuki
Eng, Hai Lok
author_sort Samadi, Mahtab
collection UPM
description This study aimed to model the kinetic of hydro-distillation of Aquilaria malaccensis leaves oil in order to understand and optimize the extraction process. In addition, this study, for the first time, aimed to identify the chemical compositions of the A. malaccensis leave-oil. By assessing both first-order kinetic model and the model of simultaneous washing and diffusion, the result indicated that the model of simultaneous washing and diffusion better describes the hydro-distillation mechanism of the essential oil from A. malaccensis leaves. The optimum time, solid to liquid ratio, and the heating power for extracting the highest amount of essential oil were found to be around 3 h, 1:10 (g·ml− 1), and 300 W respectively. Yellow essential oil with a strong smell and a yield of 0.05 v/w was extracted by hydro-distillation Clevenger apparatus. Chemical compounds of the essential oil were analyzed using gas chromatography–mass spectroscopy (GC/MS), which resulted in identification of 42 compounds that constitute 93% of essential oil. Among the identified components, Pentadecanal (32.082%), 9-Octadecenal, (Z) (15.894%), and Tetradecanal (6.927%) were the major compounds. Considering the fact that all the identified major components possess pesticidal properties, A. malaccensis leaves can be regarded as a promising natural source for producing pesticides.
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spelling upm.eprints-609372019-03-22T01:42:51Z http://psasir.upm.edu.my/id/eprint/60937/ Assessing the kinetic model of hydro-distillation and chemical composition of Aquilaria malaccensis leaves essential oil Samadi, Mahtab Zainal Abidin, Zurina Yunus, Robiah Awang Biak, Dayang Radiah Yoshida, Hiroyuki Eng, Hai Lok This study aimed to model the kinetic of hydro-distillation of Aquilaria malaccensis leaves oil in order to understand and optimize the extraction process. In addition, this study, for the first time, aimed to identify the chemical compositions of the A. malaccensis leave-oil. By assessing both first-order kinetic model and the model of simultaneous washing and diffusion, the result indicated that the model of simultaneous washing and diffusion better describes the hydro-distillation mechanism of the essential oil from A. malaccensis leaves. The optimum time, solid to liquid ratio, and the heating power for extracting the highest amount of essential oil were found to be around 3 h, 1:10 (g·ml− 1), and 300 W respectively. Yellow essential oil with a strong smell and a yield of 0.05 v/w was extracted by hydro-distillation Clevenger apparatus. Chemical compounds of the essential oil were analyzed using gas chromatography–mass spectroscopy (GC/MS), which resulted in identification of 42 compounds that constitute 93% of essential oil. Among the identified components, Pentadecanal (32.082%), 9-Octadecenal, (Z) (15.894%), and Tetradecanal (6.927%) were the major compounds. Considering the fact that all the identified major components possess pesticidal properties, A. malaccensis leaves can be regarded as a promising natural source for producing pesticides. The Chemical Industry and Engineering Society of China, and Chemical Industry Press 2017 Article PeerReviewed text en http://psasir.upm.edu.my/id/eprint/60937/1/Assessing%20the%20kinetic%20model%20of%20hydro-distillation%20and%20chemical%20composition%20of%20Aquilaria%20malaccensis%20leaves%20essential%20oil.pdf Samadi, Mahtab and Zainal Abidin, Zurina and Yunus, Robiah and Awang Biak, Dayang Radiah and Yoshida, Hiroyuki and Eng, Hai Lok (2017) Assessing the kinetic model of hydro-distillation and chemical composition of Aquilaria malaccensis leaves essential oil. Chinese Journal of Chemical Engineering, 25. 216 - 222. ISSN 1004-9541; ESSN: 2210-321X https://pdf.sciencedirectassets.com/273518/1-s2.0-S1004954117X00037/1-s2.0-S1004954116302208/main.pdf?x-amz-security-token=AgoJb3JpZ2luX2VjENn%2F%2F%2F%2F%2F%2F%2F%2F%2F%2FwEaCXVzLWVhc3QtMSJIMEYCIQDYetxYAUSKXGIkj1uYcyGQr8rFnXVnQDqSbDQm8xoPBgIhAOlfovbwJ0RT 10.1016/j.cjche.2016.09.006
spellingShingle Samadi, Mahtab
Zainal Abidin, Zurina
Yunus, Robiah
Awang Biak, Dayang Radiah
Yoshida, Hiroyuki
Eng, Hai Lok
Assessing the kinetic model of hydro-distillation and chemical composition of Aquilaria malaccensis leaves essential oil
title Assessing the kinetic model of hydro-distillation and chemical composition of Aquilaria malaccensis leaves essential oil
title_full Assessing the kinetic model of hydro-distillation and chemical composition of Aquilaria malaccensis leaves essential oil
title_fullStr Assessing the kinetic model of hydro-distillation and chemical composition of Aquilaria malaccensis leaves essential oil
title_full_unstemmed Assessing the kinetic model of hydro-distillation and chemical composition of Aquilaria malaccensis leaves essential oil
title_short Assessing the kinetic model of hydro-distillation and chemical composition of Aquilaria malaccensis leaves essential oil
title_sort assessing the kinetic model of hydro distillation and chemical composition of aquilaria malaccensis leaves essential oil
url http://psasir.upm.edu.my/id/eprint/60937/1/Assessing%20the%20kinetic%20model%20of%20hydro-distillation%20and%20chemical%20composition%20of%20Aquilaria%20malaccensis%20leaves%20essential%20oil.pdf
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