(E)-4-(Benzyloxy)Benzaldehyde Thiosemicarbazone
In the title compound, C15H15N3OS, the thiosemicarbazone group adopts an E configuration with respect to the C N bond. The benzaldehyde thiosemicarbazone fragment is almost planar [maximum deviation = 0.012 (1) A ° ], while the dihedral angle between the benzyloxy and phenyl rings is 72.48 (5)....
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English English |
| Published: |
International Union of Crystallography
2008
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| Online Access: | http://psasir.upm.edu.my/id/eprint/6157/1/63.pdf |
| Summary: | In the title compound, C15H15N3OS, the thiosemicarbazone
group adopts an E configuration with respect to the C N
bond. The benzaldehyde thiosemicarbazone fragment is
almost planar [maximum deviation = 0.012 (1) A ° ], while the dihedral angle between the benzyloxy and phenyl rings is
72.48 (5). In the crystal structure, molecules are interconnected by N—H N and N—H S hydrogen bonds,
forming a two-dimensional network parallel to the bc plane
and are further stacked along the a axis by – interactions
[centroid–centroid separation 3.9043 (7) A ° ]. The crystal structure is also stabilized by C—H interactions |
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