Kinetic and thermodynamic study of nitrate adsorption from aqueous solution by lignocellulose-based anion resins

Nitrates are present in drinking water sources and pose serious health issues in many countries throughout the world. In this research, nitrate removal by palm kernel shell-based lignocellulose anion resins was studied under various nitrate concentrations, pH, and adsorbent dosages. The nitrate adso...

Full description

Bibliographic Details
Main Authors: Bashir, Muhammad Tariq, Ali, Salmiaton, Idris, Azni, Harun, Razif
Format: Article
Language:English
Published: Taylor & Francis 2017
Online Access:http://psasir.upm.edu.my/id/eprint/62266/1/Kinetic%20and%20thermodynamic%20study%20of%20nitrate%20adsorption%20from%20aqueous%20solution%20by%20lignocellulose-based%20anion%20resins.pdf
_version_ 1825932466056069120
author Bashir, Muhammad Tariq
Ali, Salmiaton
Idris, Azni
Harun, Razif
author_facet Bashir, Muhammad Tariq
Ali, Salmiaton
Idris, Azni
Harun, Razif
author_sort Bashir, Muhammad Tariq
collection UPM
description Nitrates are present in drinking water sources and pose serious health issues in many countries throughout the world. In this research, nitrate removal by palm kernel shell-based lignocellulose anion resins was studied under various nitrate concentrations, pH, and adsorbent dosages. The nitrate adsorption capacity demonstrated by the biomaterial-based resins was 53.18 mg/L. A pseudo-second order model and the Weber–Morris diffusion model were used to assess the adsorption process. The thermodynamic study predicted the exothermic nature of the process and the dominance of physical adsorption. Resins were characterized using elemental, proximate, and chemical analyses as well as by the pH at the point of zero charge. The lignocellulose-based adsorbent is a satisfactory material for nitrate removal from water and can be regenerated and reused.
first_indexed 2024-03-06T09:42:27Z
format Article
id upm.eprints-62266
institution Universiti Putra Malaysia
language English
last_indexed 2024-03-06T09:42:27Z
publishDate 2017
publisher Taylor & Francis
record_format dspace
spelling upm.eprints-622662019-05-23T05:31:26Z http://psasir.upm.edu.my/id/eprint/62266/ Kinetic and thermodynamic study of nitrate adsorption from aqueous solution by lignocellulose-based anion resins Bashir, Muhammad Tariq Ali, Salmiaton Idris, Azni Harun, Razif Nitrates are present in drinking water sources and pose serious health issues in many countries throughout the world. In this research, nitrate removal by palm kernel shell-based lignocellulose anion resins was studied under various nitrate concentrations, pH, and adsorbent dosages. The nitrate adsorption capacity demonstrated by the biomaterial-based resins was 53.18 mg/L. A pseudo-second order model and the Weber–Morris diffusion model were used to assess the adsorption process. The thermodynamic study predicted the exothermic nature of the process and the dominance of physical adsorption. Resins were characterized using elemental, proximate, and chemical analyses as well as by the pH at the point of zero charge. The lignocellulose-based adsorbent is a satisfactory material for nitrate removal from water and can be regenerated and reused. Taylor & Francis 2017-02 Article PeerReviewed text en http://psasir.upm.edu.my/id/eprint/62266/1/Kinetic%20and%20thermodynamic%20study%20of%20nitrate%20adsorption%20from%20aqueous%20solution%20by%20lignocellulose-based%20anion%20resins.pdf Bashir, Muhammad Tariq and Ali, Salmiaton and Idris, Azni and Harun, Razif (2017) Kinetic and thermodynamic study of nitrate adsorption from aqueous solution by lignocellulose-based anion resins. Desalination and Water Treatment, 62. 449 - 456. ISSN 1944-3994; ESSN: 1944-3986 http://www.deswater.com/DWT_abstracts/vol_62/62_2017_449.pdf 10.5004/dwt.2017.20136
spellingShingle Bashir, Muhammad Tariq
Ali, Salmiaton
Idris, Azni
Harun, Razif
Kinetic and thermodynamic study of nitrate adsorption from aqueous solution by lignocellulose-based anion resins
title Kinetic and thermodynamic study of nitrate adsorption from aqueous solution by lignocellulose-based anion resins
title_full Kinetic and thermodynamic study of nitrate adsorption from aqueous solution by lignocellulose-based anion resins
title_fullStr Kinetic and thermodynamic study of nitrate adsorption from aqueous solution by lignocellulose-based anion resins
title_full_unstemmed Kinetic and thermodynamic study of nitrate adsorption from aqueous solution by lignocellulose-based anion resins
title_short Kinetic and thermodynamic study of nitrate adsorption from aqueous solution by lignocellulose-based anion resins
title_sort kinetic and thermodynamic study of nitrate adsorption from aqueous solution by lignocellulose based anion resins
url http://psasir.upm.edu.my/id/eprint/62266/1/Kinetic%20and%20thermodynamic%20study%20of%20nitrate%20adsorption%20from%20aqueous%20solution%20by%20lignocellulose-based%20anion%20resins.pdf
work_keys_str_mv AT bashirmuhammadtariq kineticandthermodynamicstudyofnitrateadsorptionfromaqueoussolutionbylignocellulosebasedanionresins
AT alisalmiaton kineticandthermodynamicstudyofnitrateadsorptionfromaqueoussolutionbylignocellulosebasedanionresins
AT idrisazni kineticandthermodynamicstudyofnitrateadsorptionfromaqueoussolutionbylignocellulosebasedanionresins
AT harunrazif kineticandthermodynamicstudyofnitrateadsorptionfromaqueoussolutionbylignocellulosebasedanionresins