Perovskite solar cells using polymer electrolytes
This study deals with the characterization of methylammonium lead iodide (MAPbI3) material and the fabrication of perovskite solar cells using gel polymer electrolyte as the charge transport medium. The crystalline lead–based perovskite has been verified by x-ray diffraction (XRD). The [100], [200],...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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Taylor and Francis
2017
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| Online Access: | http://psasir.upm.edu.my/id/eprint/62712/1/GEL.pdf |
| _version_ | 1825932506309853184 |
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| author | Shamsuddin, L. Mohd Noor, Ikhwan Syafiq Albinsson, I. Mellander, B. E. Mohd Arof, Abdul Kariem |
| author_facet | Shamsuddin, L. Mohd Noor, Ikhwan Syafiq Albinsson, I. Mellander, B. E. Mohd Arof, Abdul Kariem |
| author_sort | Shamsuddin, L. |
| collection | UPM |
| description | This study deals with the characterization of methylammonium lead iodide (MAPbI3) material and the fabrication of perovskite solar cells using gel polymer electrolyte as the charge transport medium. The crystalline lead–based perovskite has been verified by x-ray diffraction (XRD). The [100], [200], [210], [211], [220], [300] and [222] reflection planes can be observed at 2θ angles of 14.10°, 28.35°, 31.90°, 34.95°, 40.40°, 43.15° and 50.20°, indicating a cubic crystal symmetry for CH3NH3PbI3. EDX spectrum showed a Pb:I ratio of approximately 1:3 as in CH3NH3PbI3. The band gap for lead-based perovskite is 1.45 eV estimated from UV-Vis absorption spectroscopy. The nanocrystalline MAPbI3 have been observed using field emission scanning electron microscopy (FESEM), where the average cuboid size of perovskite nanocrystals is 380 nm. The cell have been fabricated using gel polymer electrolyte with composition 17.02 wt.% PVA–13.93 wt.% TBAI–0.96 wt.% I2– 68.09 wt.% DMF. The cell exhibits a power conversion efficiency (PCE) of 1.28% with open circuit voltage (Voc) 0.58 mV, short circuit current density (Jsc) 3.74 mA cm−2 and fill factor (FF) 59.18%. |
| first_indexed | 2024-03-06T09:43:04Z |
| format | Article |
| id | upm.eprints-62712 |
| institution | Universiti Putra Malaysia |
| language | English |
| last_indexed | 2024-03-06T09:43:04Z |
| publishDate | 2017 |
| publisher | Taylor and Francis |
| record_format | dspace |
| spelling | upm.eprints-627122020-12-02T22:26:10Z http://psasir.upm.edu.my/id/eprint/62712/ Perovskite solar cells using polymer electrolytes Shamsuddin, L. Mohd Noor, Ikhwan Syafiq Albinsson, I. Mellander, B. E. Mohd Arof, Abdul Kariem This study deals with the characterization of methylammonium lead iodide (MAPbI3) material and the fabrication of perovskite solar cells using gel polymer electrolyte as the charge transport medium. The crystalline lead–based perovskite has been verified by x-ray diffraction (XRD). The [100], [200], [210], [211], [220], [300] and [222] reflection planes can be observed at 2θ angles of 14.10°, 28.35°, 31.90°, 34.95°, 40.40°, 43.15° and 50.20°, indicating a cubic crystal symmetry for CH3NH3PbI3. EDX spectrum showed a Pb:I ratio of approximately 1:3 as in CH3NH3PbI3. The band gap for lead-based perovskite is 1.45 eV estimated from UV-Vis absorption spectroscopy. The nanocrystalline MAPbI3 have been observed using field emission scanning electron microscopy (FESEM), where the average cuboid size of perovskite nanocrystals is 380 nm. The cell have been fabricated using gel polymer electrolyte with composition 17.02 wt.% PVA–13.93 wt.% TBAI–0.96 wt.% I2– 68.09 wt.% DMF. The cell exhibits a power conversion efficiency (PCE) of 1.28% with open circuit voltage (Voc) 0.58 mV, short circuit current density (Jsc) 3.74 mA cm−2 and fill factor (FF) 59.18%. Taylor and Francis 2017 Article PeerReviewed text en http://psasir.upm.edu.my/id/eprint/62712/1/GEL.pdf Shamsuddin, L. and Mohd Noor, Ikhwan Syafiq and Albinsson, I. and Mellander, B. E. and Mohd Arof, Abdul Kariem (2017) Perovskite solar cells using polymer electrolytes. Molecular Crystals and Liquid Crystals, 655 (1). 181 - 194. ISSN 1542-1406; ESSN: 1563-5287 https://www.tandfonline.com/doi/abs/10.1080/15421406.2017.1362889?journalCode=gmcl20 10.1080/15421406.2017.1362889 |
| spellingShingle | Shamsuddin, L. Mohd Noor, Ikhwan Syafiq Albinsson, I. Mellander, B. E. Mohd Arof, Abdul Kariem Perovskite solar cells using polymer electrolytes |
| title | Perovskite solar cells using polymer electrolytes |
| title_full | Perovskite solar cells using polymer electrolytes |
| title_fullStr | Perovskite solar cells using polymer electrolytes |
| title_full_unstemmed | Perovskite solar cells using polymer electrolytes |
| title_short | Perovskite solar cells using polymer electrolytes |
| title_sort | perovskite solar cells using polymer electrolytes |
| url | http://psasir.upm.edu.my/id/eprint/62712/1/GEL.pdf |
| work_keys_str_mv | AT shamsuddinl perovskitesolarcellsusingpolymerelectrolytes AT mohdnoorikhwansyafiq perovskitesolarcellsusingpolymerelectrolytes AT albinssoni perovskitesolarcellsusingpolymerelectrolytes AT mellanderbe perovskitesolarcellsusingpolymerelectrolytes AT mohdarofabdulkariem perovskitesolarcellsusingpolymerelectrolytes |