Structural, optical and sensing properties of ionophore doped graphene based bionanocomposite thin film

In this study, the ionophore doped graphene-based bionanocomposite solution has been prepared using valinomycin, graphene oxide and chitosan in acetic acid under mild condition. After the reaction, the ionophore doped graphene-based bionanocomposite thin film was fabricated using spin coating techni...

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Main Authors: Zainudin, Afiq Azri, Yap, Wing Fen, Yusof, Nor Azah, Omar, Nur Alia Sheh
Format: Article
Language:English
Published: Elsevier 2017
Online Access:http://psasir.upm.edu.my/id/eprint/63310/1/Structural%2C%20optical%20and%20sensing%20properties%20of%20ionophore%20doped%20graphene%20based%20bionanocomposite%20thin%20film.pdf
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author Zainudin, Afiq Azri
Yap, Wing Fen
Yusof, Nor Azah
Omar, Nur Alia Sheh
author_facet Zainudin, Afiq Azri
Yap, Wing Fen
Yusof, Nor Azah
Omar, Nur Alia Sheh
author_sort Zainudin, Afiq Azri
collection UPM
description In this study, the ionophore doped graphene-based bionanocomposite solution has been prepared using valinomycin, graphene oxide and chitosan in acetic acid under mild condition. After the reaction, the ionophore doped graphene-based bionanocomposite thin film was fabricated using spin coating technique. The structural and optical properties of the bionanocomposite thin film was characterized by Fourier transform infrared spectroscopy (FTIR), atomic force microscopy (AFM) and ultraviolet-visible near infra-red (UV–vis-NIR). The functional group of the thin film has been confirmed by FTIR and surface morphology by AFM indicated that the bionanocomposite thin film is relatively smooth and homogeneous. The UV–vis-NIR analysis showed that absorption of the thin film is high with optical band gap of 3.987 eV. Also, this derivative bionanocomposite thin film has been studied as a sensor element by using surface plasmon resonance (SPR) spectroscopy. The SPR results suggested that potassium ion can be detected by integrating the thin film in the SPR system. This ionophore doped graphene-based bionanocomposite thin film has high potential as novel optical material for metal ion sensing application.
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spelling upm.eprints-633102018-10-15T02:58:15Z http://psasir.upm.edu.my/id/eprint/63310/ Structural, optical and sensing properties of ionophore doped graphene based bionanocomposite thin film Zainudin, Afiq Azri Yap, Wing Fen Yusof, Nor Azah Omar, Nur Alia Sheh In this study, the ionophore doped graphene-based bionanocomposite solution has been prepared using valinomycin, graphene oxide and chitosan in acetic acid under mild condition. After the reaction, the ionophore doped graphene-based bionanocomposite thin film was fabricated using spin coating technique. The structural and optical properties of the bionanocomposite thin film was characterized by Fourier transform infrared spectroscopy (FTIR), atomic force microscopy (AFM) and ultraviolet-visible near infra-red (UV–vis-NIR). The functional group of the thin film has been confirmed by FTIR and surface morphology by AFM indicated that the bionanocomposite thin film is relatively smooth and homogeneous. The UV–vis-NIR analysis showed that absorption of the thin film is high with optical band gap of 3.987 eV. Also, this derivative bionanocomposite thin film has been studied as a sensor element by using surface plasmon resonance (SPR) spectroscopy. The SPR results suggested that potassium ion can be detected by integrating the thin film in the SPR system. This ionophore doped graphene-based bionanocomposite thin film has high potential as novel optical material for metal ion sensing application. Elsevier 2017 Article PeerReviewed text en http://psasir.upm.edu.my/id/eprint/63310/1/Structural%2C%20optical%20and%20sensing%20properties%20of%20ionophore%20doped%20graphene%20based%20bionanocomposite%20thin%20film.pdf Zainudin, Afiq Azri and Yap, Wing Fen and Yusof, Nor Azah and Omar, Nur Alia Sheh (2017) Structural, optical and sensing properties of ionophore doped graphene based bionanocomposite thin film. Optik, 144. 308 - 315. ISSN 0030-4026; ESSN: 1618-1336 https://www.sciencedirect.com/science/article/pii/S0030402617308100 10.1016/j.ijleo.2017.07.001
spellingShingle Zainudin, Afiq Azri
Yap, Wing Fen
Yusof, Nor Azah
Omar, Nur Alia Sheh
Structural, optical and sensing properties of ionophore doped graphene based bionanocomposite thin film
title Structural, optical and sensing properties of ionophore doped graphene based bionanocomposite thin film
title_full Structural, optical and sensing properties of ionophore doped graphene based bionanocomposite thin film
title_fullStr Structural, optical and sensing properties of ionophore doped graphene based bionanocomposite thin film
title_full_unstemmed Structural, optical and sensing properties of ionophore doped graphene based bionanocomposite thin film
title_short Structural, optical and sensing properties of ionophore doped graphene based bionanocomposite thin film
title_sort structural optical and sensing properties of ionophore doped graphene based bionanocomposite thin film
url http://psasir.upm.edu.my/id/eprint/63310/1/Structural%2C%20optical%20and%20sensing%20properties%20of%20ionophore%20doped%20graphene%20based%20bionanocomposite%20thin%20film.pdf
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