Synthesis and optical characterization of zinc borotellurite glass doped with lanthanum nanoparticles

A glass series with chemical composition of {[(TeO2)0.7(B2O3)0.3]0.7(ZnO)0.3}1-x (La NPs)x where x = 0.01, 0.02, 0.03, 0.04 and 0.05 molar fraction was synthesized through conventional melt-quenching method. The fabricated glasses were characterized by using UV-Vis and FTIR technique in the range of...

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Main Authors: Faznny, M. F., Halimah, Mohamed Kamari, Latif, Amirah Abdul, Iskandar, Shahrim Mustafa
Format: Article
Language:English
Published: Trans Tech Publications 2017
Online Access:http://psasir.upm.edu.my/id/eprint/63360/1/Synthesis%20and%20optical%20characterization%20of%20zinc%20borotellurite%20glass%20doped%20with%20lanthanum%20nanoparticles.pdf
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author Faznny, M. F.
Halimah, Mohamed Kamari
Latif, Amirah Abdul
Iskandar, Shahrim Mustafa
author_facet Faznny, M. F.
Halimah, Mohamed Kamari
Latif, Amirah Abdul
Iskandar, Shahrim Mustafa
author_sort Faznny, M. F.
collection UPM
description A glass series with chemical composition of {[(TeO2)0.7(B2O3)0.3]0.7(ZnO)0.3}1-x (La NPs)x where x = 0.01, 0.02, 0.03, 0.04 and 0.05 molar fraction was synthesized through conventional melt-quenching method. The fabricated glasses were characterized by using UV-Vis and FTIR technique in the range of 220 to 800 nm and 280 to 2000 cm-1 respectively. Various absorption bands that were recorded in FTIR spectra indicates the presence of TeO4, BO3 and BO4 unit. In this research, indirect energy band gap showed an increasing trend while refractive index values decreases as amount of La NPs increases due to the decrement of high polarizability nonbridging oxygen number in the glass system. Other optical parameter that also take part in governing the value of refractive index such as electronic polarizability was also determined.
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spelling upm.eprints-633602018-10-16T00:31:20Z http://psasir.upm.edu.my/id/eprint/63360/ Synthesis and optical characterization of zinc borotellurite glass doped with lanthanum nanoparticles Faznny, M. F. Halimah, Mohamed Kamari Latif, Amirah Abdul Iskandar, Shahrim Mustafa A glass series with chemical composition of {[(TeO2)0.7(B2O3)0.3]0.7(ZnO)0.3}1-x (La NPs)x where x = 0.01, 0.02, 0.03, 0.04 and 0.05 molar fraction was synthesized through conventional melt-quenching method. The fabricated glasses were characterized by using UV-Vis and FTIR technique in the range of 220 to 800 nm and 280 to 2000 cm-1 respectively. Various absorption bands that were recorded in FTIR spectra indicates the presence of TeO4, BO3 and BO4 unit. In this research, indirect energy band gap showed an increasing trend while refractive index values decreases as amount of La NPs increases due to the decrement of high polarizability nonbridging oxygen number in the glass system. Other optical parameter that also take part in governing the value of refractive index such as electronic polarizability was also determined. Trans Tech Publications 2017 Article PeerReviewed text en http://psasir.upm.edu.my/id/eprint/63360/1/Synthesis%20and%20optical%20characterization%20of%20zinc%20borotellurite%20glass%20doped%20with%20lanthanum%20nanoparticles.pdf Faznny, M. F. and Halimah, Mohamed Kamari and Latif, Amirah Abdul and Iskandar, Shahrim Mustafa (2017) Synthesis and optical characterization of zinc borotellurite glass doped with lanthanum nanoparticles. Solid State Phenomena, 268. 23 - 27. ISSN 1012-0394; ESSN: 1662-9779 10.4028/www.scientific.net/SSP.268.23
spellingShingle Faznny, M. F.
Halimah, Mohamed Kamari
Latif, Amirah Abdul
Iskandar, Shahrim Mustafa
Synthesis and optical characterization of zinc borotellurite glass doped with lanthanum nanoparticles
title Synthesis and optical characterization of zinc borotellurite glass doped with lanthanum nanoparticles
title_full Synthesis and optical characterization of zinc borotellurite glass doped with lanthanum nanoparticles
title_fullStr Synthesis and optical characterization of zinc borotellurite glass doped with lanthanum nanoparticles
title_full_unstemmed Synthesis and optical characterization of zinc borotellurite glass doped with lanthanum nanoparticles
title_short Synthesis and optical characterization of zinc borotellurite glass doped with lanthanum nanoparticles
title_sort synthesis and optical characterization of zinc borotellurite glass doped with lanthanum nanoparticles
url http://psasir.upm.edu.my/id/eprint/63360/1/Synthesis%20and%20optical%20characterization%20of%20zinc%20borotellurite%20glass%20doped%20with%20lanthanum%20nanoparticles.pdf
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