Ultrasound-assisted surfactant enhanced emulsification microextraction method coupled with gas chromatography-mass spectrometry for the determination of selected polycyclic aromatic hydrocarbons in aqueous samples
A simple and rapid microextraction method termed as ultrasound-assisted surfactant enhanced emulsification microextraction (UASEME) was developed for the determination of fluoranthene (FLU) and phenanthrene (PHE) in aqueous samples followed by gas chromatography-mass spectrometry (GC-MS). Six import...
| Main Authors: | , , , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Malaysian Analytical Sciences Society
2017
|
| Online Access: | http://psasir.upm.edu.my/id/eprint/63623/1/Ultrasound-assisted%20surfactant%20enhanced%20emulsification%20microextraction%20method%20coupled%20with%20gas%20.pdf |
| _version_ | 1796977775048916992 |
|---|---|
| author | Shater, Siti Farahiyah Ahmad Yahaya, Noorfatimah Zain, Nur Nadhirah Mohamad Mohamad, Sharlina Hassan, Farah Wahidah Mohd Kamaruzaman, Sazlinda Hanapi, Nor Suhaila Mohamad Miskam, Mazidatulakmam |
| author_facet | Shater, Siti Farahiyah Ahmad Yahaya, Noorfatimah Zain, Nur Nadhirah Mohamad Mohamad, Sharlina Hassan, Farah Wahidah Mohd Kamaruzaman, Sazlinda Hanapi, Nor Suhaila Mohamad Miskam, Mazidatulakmam |
| author_sort | Shater, Siti Farahiyah Ahmad |
| collection | UPM |
| description | A simple and rapid microextraction method termed as ultrasound-assisted surfactant enhanced emulsification microextraction (UASEME) was developed for the determination of fluoranthene (FLU) and phenanthrene (PHE) in aqueous samples followed by gas chromatography-mass spectrometry (GC-MS). Six important parameters, that affect the extraction efficiency of polycyclic aromatic hydrocarbons (PAHs) were evaluated and the results were as follows; extraction solvent (toluene), volume of extraction solvent (30 μL), surfactant (Tween 20), volume of surfactant (15 μL), extraction time (2 minutes) and with no salt addition. Under the optimum conditions, the method showed good linearity over the concentration range from 1 – 1000 μg L- 1 with correlation coefficients (R² ≥ 0.9932), acceptable limits of detection (0.3 μg L- 1) and limits of quantification (1.0 μg L- 1) for both analytes. Good relative recovery values, in the range of 91.75 – 104.1%, were obtained for tap water samples. The relative standard deviations (RSDs) were 1.62 – 10.32% (n = 3). The proposed method was applied for the determination of FLU and PHE in tap water and sugarcane juices. |
| first_indexed | 2024-03-06T09:45:00Z |
| format | Article |
| id | upm.eprints-63623 |
| institution | Universiti Putra Malaysia |
| language | English |
| last_indexed | 2024-03-06T09:45:00Z |
| publishDate | 2017 |
| publisher | Malaysian Analytical Sciences Society |
| record_format | dspace |
| spelling | upm.eprints-636232018-11-07T09:04:24Z http://psasir.upm.edu.my/id/eprint/63623/ Ultrasound-assisted surfactant enhanced emulsification microextraction method coupled with gas chromatography-mass spectrometry for the determination of selected polycyclic aromatic hydrocarbons in aqueous samples Shater, Siti Farahiyah Ahmad Yahaya, Noorfatimah Zain, Nur Nadhirah Mohamad Mohamad, Sharlina Hassan, Farah Wahidah Mohd Kamaruzaman, Sazlinda Hanapi, Nor Suhaila Mohamad Miskam, Mazidatulakmam A simple and rapid microextraction method termed as ultrasound-assisted surfactant enhanced emulsification microextraction (UASEME) was developed for the determination of fluoranthene (FLU) and phenanthrene (PHE) in aqueous samples followed by gas chromatography-mass spectrometry (GC-MS). Six important parameters, that affect the extraction efficiency of polycyclic aromatic hydrocarbons (PAHs) were evaluated and the results were as follows; extraction solvent (toluene), volume of extraction solvent (30 μL), surfactant (Tween 20), volume of surfactant (15 μL), extraction time (2 minutes) and with no salt addition. Under the optimum conditions, the method showed good linearity over the concentration range from 1 – 1000 μg L- 1 with correlation coefficients (R² ≥ 0.9932), acceptable limits of detection (0.3 μg L- 1) and limits of quantification (1.0 μg L- 1) for both analytes. Good relative recovery values, in the range of 91.75 – 104.1%, were obtained for tap water samples. The relative standard deviations (RSDs) were 1.62 – 10.32% (n = 3). The proposed method was applied for the determination of FLU and PHE in tap water and sugarcane juices. Malaysian Analytical Sciences Society 2017 Article PeerReviewed text en http://psasir.upm.edu.my/id/eprint/63623/1/Ultrasound-assisted%20surfactant%20enhanced%20emulsification%20microextraction%20method%20coupled%20with%20gas%20.pdf Shater, Siti Farahiyah Ahmad and Yahaya, Noorfatimah and Zain, Nur Nadhirah Mohamad and Mohamad, Sharlina and Hassan, Farah Wahidah Mohd and Kamaruzaman, Sazlinda and Hanapi, Nor Suhaila Mohamad and Miskam, Mazidatulakmam (2017) Ultrasound-assisted surfactant enhanced emulsification microextraction method coupled with gas chromatography-mass spectrometry for the determination of selected polycyclic aromatic hydrocarbons in aqueous samples. Malaysian Journal of Analytical Sciences, 21 (4). 810 - 819. ISSN 1394-2506 10.17576/mjas-2017-2104-07 |
| spellingShingle | Shater, Siti Farahiyah Ahmad Yahaya, Noorfatimah Zain, Nur Nadhirah Mohamad Mohamad, Sharlina Hassan, Farah Wahidah Mohd Kamaruzaman, Sazlinda Hanapi, Nor Suhaila Mohamad Miskam, Mazidatulakmam Ultrasound-assisted surfactant enhanced emulsification microextraction method coupled with gas chromatography-mass spectrometry for the determination of selected polycyclic aromatic hydrocarbons in aqueous samples |
| title | Ultrasound-assisted surfactant enhanced emulsification microextraction method coupled with gas chromatography-mass spectrometry for the determination of selected polycyclic aromatic hydrocarbons in aqueous samples |
| title_full | Ultrasound-assisted surfactant enhanced emulsification microextraction method coupled with gas chromatography-mass spectrometry for the determination of selected polycyclic aromatic hydrocarbons in aqueous samples |
| title_fullStr | Ultrasound-assisted surfactant enhanced emulsification microextraction method coupled with gas chromatography-mass spectrometry for the determination of selected polycyclic aromatic hydrocarbons in aqueous samples |
| title_full_unstemmed | Ultrasound-assisted surfactant enhanced emulsification microextraction method coupled with gas chromatography-mass spectrometry for the determination of selected polycyclic aromatic hydrocarbons in aqueous samples |
| title_short | Ultrasound-assisted surfactant enhanced emulsification microextraction method coupled with gas chromatography-mass spectrometry for the determination of selected polycyclic aromatic hydrocarbons in aqueous samples |
| title_sort | ultrasound assisted surfactant enhanced emulsification microextraction method coupled with gas chromatography mass spectrometry for the determination of selected polycyclic aromatic hydrocarbons in aqueous samples |
| url | http://psasir.upm.edu.my/id/eprint/63623/1/Ultrasound-assisted%20surfactant%20enhanced%20emulsification%20microextraction%20method%20coupled%20with%20gas%20.pdf |
| work_keys_str_mv | AT shatersitifarahiyahahmad ultrasoundassistedsurfactantenhancedemulsificationmicroextractionmethodcoupledwithgaschromatographymassspectrometryforthedeterminationofselectedpolycyclicaromatichydrocarbonsinaqueoussamples AT yahayanoorfatimah ultrasoundassistedsurfactantenhancedemulsificationmicroextractionmethodcoupledwithgaschromatographymassspectrometryforthedeterminationofselectedpolycyclicaromatichydrocarbonsinaqueoussamples AT zainnurnadhirahmohamad ultrasoundassistedsurfactantenhancedemulsificationmicroextractionmethodcoupledwithgaschromatographymassspectrometryforthedeterminationofselectedpolycyclicaromatichydrocarbonsinaqueoussamples AT mohamadsharlina ultrasoundassistedsurfactantenhancedemulsificationmicroextractionmethodcoupledwithgaschromatographymassspectrometryforthedeterminationofselectedpolycyclicaromatichydrocarbonsinaqueoussamples AT hassanfarahwahidahmohd ultrasoundassistedsurfactantenhancedemulsificationmicroextractionmethodcoupledwithgaschromatographymassspectrometryforthedeterminationofselectedpolycyclicaromatichydrocarbonsinaqueoussamples AT kamaruzamansazlinda ultrasoundassistedsurfactantenhancedemulsificationmicroextractionmethodcoupledwithgaschromatographymassspectrometryforthedeterminationofselectedpolycyclicaromatichydrocarbonsinaqueoussamples AT hanapinorsuhailamohamad ultrasoundassistedsurfactantenhancedemulsificationmicroextractionmethodcoupledwithgaschromatographymassspectrometryforthedeterminationofselectedpolycyclicaromatichydrocarbonsinaqueoussamples AT miskammazidatulakmam ultrasoundassistedsurfactantenhancedemulsificationmicroextractionmethodcoupledwithgaschromatographymassspectrometryforthedeterminationofselectedpolycyclicaromatichydrocarbonsinaqueoussamples |