Equilibrium, kinetics and thermodynamic adsorption studies of acid dyes on adsorbent developed from kenaf core fiber
Quaternized kenaf core fiber (QKCF) was used as an adsorbent for adsorption of anionic Acid Blue-25 (AB) and anionic Acid Green-25 (AG) dyes. Chemical treatment with (3-chloro-2-hydroxypropyl) trimethylammonium chloride under basic condition was applied in order to alter the surface properties of th...
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| Format: | Article |
| Language: | English |
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SAGE Publications
2018
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| Online Access: | http://psasir.upm.edu.my/id/eprint/72602/1/Equilibrium.pdf |
| _version_ | 1796979488155762688 |
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| author | Tharwani, Intidhar Jabir Idan Abdullah, Luqman Chuah Choong, Thomas Shean Yaw Md. Jamil, Siti Nurul Ain |
| author_facet | Tharwani, Intidhar Jabir Idan Abdullah, Luqman Chuah Choong, Thomas Shean Yaw Md. Jamil, Siti Nurul Ain |
| author_sort | Tharwani, Intidhar Jabir Idan |
| collection | UPM |
| description | Quaternized kenaf core fiber (QKCF) was used as an adsorbent for adsorption of anionic Acid Blue-25 (AB) and anionic Acid Green-25 (AG) dyes. Chemical treatment with (3-chloro-2-hydroxypropyl) trimethylammonium chloride under basic condition was applied in order to alter the surface properties of the raw kenaf core fiber. Adsorption studies were carried out to delineate the effect of initial dye concentration, temperature and pH on removal of dyes. The results show that the percentage removal of Acid Blue-25 and Acid Green-25 dyes were increased by increasing the concentrations of dyes. In addition, the maximum percentage removal was 99.8% and 99.65% for Acid Blue-25 and Acid Green-25, respectively. Langmuir, Freundlich and Temkin isotherm models were applied to analyze the data for dye adsorption at 15℃, 25℃, 35℃, and 45℃. The experimental data were best represented by the Langmuir model with maximum adsorption capacity of 303.03 mg/g and 344.83 mg/g for Acid Blue-25 and Acid Green-25 dyes, respectively, at 15℃, and the kinetic data for both dyes were best represented by the pseudo-second-order kinetic model. Thermodynamic studies indicated that the reactions of Acid Blue-25 and Acid Green-25 dyes were endothermic. It was concluded that QKCF adsorbent can be utilized as an efficient low-cost adsorbent for removal of anionic dyes. |
| first_indexed | 2024-03-06T10:09:39Z |
| format | Article |
| id | upm.eprints-72602 |
| institution | Universiti Putra Malaysia |
| language | English |
| last_indexed | 2024-03-06T10:09:39Z |
| publishDate | 2018 |
| publisher | SAGE Publications |
| record_format | dspace |
| spelling | upm.eprints-726022020-11-09T12:52:46Z http://psasir.upm.edu.my/id/eprint/72602/ Equilibrium, kinetics and thermodynamic adsorption studies of acid dyes on adsorbent developed from kenaf core fiber Tharwani, Intidhar Jabir Idan Abdullah, Luqman Chuah Choong, Thomas Shean Yaw Md. Jamil, Siti Nurul Ain Quaternized kenaf core fiber (QKCF) was used as an adsorbent for adsorption of anionic Acid Blue-25 (AB) and anionic Acid Green-25 (AG) dyes. Chemical treatment with (3-chloro-2-hydroxypropyl) trimethylammonium chloride under basic condition was applied in order to alter the surface properties of the raw kenaf core fiber. Adsorption studies were carried out to delineate the effect of initial dye concentration, temperature and pH on removal of dyes. The results show that the percentage removal of Acid Blue-25 and Acid Green-25 dyes were increased by increasing the concentrations of dyes. In addition, the maximum percentage removal was 99.8% and 99.65% for Acid Blue-25 and Acid Green-25, respectively. Langmuir, Freundlich and Temkin isotherm models were applied to analyze the data for dye adsorption at 15℃, 25℃, 35℃, and 45℃. The experimental data were best represented by the Langmuir model with maximum adsorption capacity of 303.03 mg/g and 344.83 mg/g for Acid Blue-25 and Acid Green-25 dyes, respectively, at 15℃, and the kinetic data for both dyes were best represented by the pseudo-second-order kinetic model. Thermodynamic studies indicated that the reactions of Acid Blue-25 and Acid Green-25 dyes were endothermic. It was concluded that QKCF adsorbent can be utilized as an efficient low-cost adsorbent for removal of anionic dyes. SAGE Publications 2018 Article PeerReviewed text en http://psasir.upm.edu.my/id/eprint/72602/1/Equilibrium.pdf Tharwani, Intidhar Jabir Idan and Abdullah, Luqman Chuah and Choong, Thomas Shean Yaw and Md. Jamil, Siti Nurul Ain (2018) Equilibrium, kinetics and thermodynamic adsorption studies of acid dyes on adsorbent developed from kenaf core fiber. Adsorption Science and Technology, 36 (1-2). 694 - 712. ISSN 0263-6174; ESSN: 2048-4038 https://journals.sagepub.com/doi/full/10.1177/0263617417715532 10.1177/0263617417715532 |
| spellingShingle | Tharwani, Intidhar Jabir Idan Abdullah, Luqman Chuah Choong, Thomas Shean Yaw Md. Jamil, Siti Nurul Ain Equilibrium, kinetics and thermodynamic adsorption studies of acid dyes on adsorbent developed from kenaf core fiber |
| title | Equilibrium, kinetics and thermodynamic adsorption studies of acid dyes on adsorbent developed from kenaf core fiber |
| title_full | Equilibrium, kinetics and thermodynamic adsorption studies of acid dyes on adsorbent developed from kenaf core fiber |
| title_fullStr | Equilibrium, kinetics and thermodynamic adsorption studies of acid dyes on adsorbent developed from kenaf core fiber |
| title_full_unstemmed | Equilibrium, kinetics and thermodynamic adsorption studies of acid dyes on adsorbent developed from kenaf core fiber |
| title_short | Equilibrium, kinetics and thermodynamic adsorption studies of acid dyes on adsorbent developed from kenaf core fiber |
| title_sort | equilibrium kinetics and thermodynamic adsorption studies of acid dyes on adsorbent developed from kenaf core fiber |
| url | http://psasir.upm.edu.my/id/eprint/72602/1/Equilibrium.pdf |
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