Fabrication of poly(vinyl alcohol)-graphene quantum dots coated with poly(3, 4-ethylenedioxythiophene) for supercapacitor
Conducting nanofiber composed of poly(vinyl alcohol) (PVA), graphene quantum dots (GQDs) and poly(3,4‐ethylenedioxythiophene) (PEDOT) was prepared for symmetrical supercapacitor through electrospinning and electropolymerization techniques. The formation of PVA nanofibers with the addition of GQDs wa...
| Main Authors: | , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
John Wiley and Sons
2018
|
| Online Access: | http://psasir.upm.edu.my/id/eprint/72700/1/Fabrication%20of%20poly.pdf |
| _version_ | 1825950130075860992 |
|---|---|
| author | Syed Zainol Abidin, Shariffah Nur Jannah Mamat, Shuhazlly Abdul Rashid, Suraya Zainal, Zulkarnain Sulaiman, Yusran |
| author_facet | Syed Zainol Abidin, Shariffah Nur Jannah Mamat, Shuhazlly Abdul Rashid, Suraya Zainal, Zulkarnain Sulaiman, Yusran |
| author_sort | Syed Zainol Abidin, Shariffah Nur Jannah |
| collection | UPM |
| description | Conducting nanofiber composed of poly(vinyl alcohol) (PVA), graphene quantum dots (GQDs) and poly(3,4‐ethylenedioxythiophene) (PEDOT) was prepared for symmetrical supercapacitor through electrospinning and electropolymerization techniques. The formation of PVA nanofibers with the addition of GQDs was excellently prepared with the average diameter of 55.66 ± 27 nm. Field emission scanning electron microscopy images revealed that cauliflower‐like structure of PEDOT was successfully coated on PVA‐GQD electrospun nanofibers. PVA‐GQD/PEDOT nanocomposite exhibited the highest specific capacitance of 291.86 F/g compared with PVA/PEDOT (220.73 F/g) and PEDOT (161.48 F/g). PVA‐GQD/PEDOT also demonstrated a high specific energy and specific power of 16.95 and 984.48 W/kg, respectively, at 2.0 A/g current density. PVA‐GQD/PEDOT exhibited the lowest resistance of charge transfer (Rct) and equivalent series resistance compared with PEDOT and PVA/PEDOT, indicating that the fast ion diffusion between the electrode and electrolyte interface. PVA‐GQD/PEDOT nanocomposite also showed an excellent stability with retention of 98% after 1000 cycles. |
| first_indexed | 2024-03-06T10:09:54Z |
| format | Article |
| id | upm.eprints-72700 |
| institution | Universiti Putra Malaysia |
| language | English |
| last_indexed | 2024-03-06T10:09:54Z |
| publishDate | 2018 |
| publisher | John Wiley and Sons |
| record_format | dspace |
| spelling | upm.eprints-727002021-01-06T09:20:30Z http://psasir.upm.edu.my/id/eprint/72700/ Fabrication of poly(vinyl alcohol)-graphene quantum dots coated with poly(3, 4-ethylenedioxythiophene) for supercapacitor Syed Zainol Abidin, Shariffah Nur Jannah Mamat, Shuhazlly Abdul Rashid, Suraya Zainal, Zulkarnain Sulaiman, Yusran Conducting nanofiber composed of poly(vinyl alcohol) (PVA), graphene quantum dots (GQDs) and poly(3,4‐ethylenedioxythiophene) (PEDOT) was prepared for symmetrical supercapacitor through electrospinning and electropolymerization techniques. The formation of PVA nanofibers with the addition of GQDs was excellently prepared with the average diameter of 55.66 ± 27 nm. Field emission scanning electron microscopy images revealed that cauliflower‐like structure of PEDOT was successfully coated on PVA‐GQD electrospun nanofibers. PVA‐GQD/PEDOT nanocomposite exhibited the highest specific capacitance of 291.86 F/g compared with PVA/PEDOT (220.73 F/g) and PEDOT (161.48 F/g). PVA‐GQD/PEDOT also demonstrated a high specific energy and specific power of 16.95 and 984.48 W/kg, respectively, at 2.0 A/g current density. PVA‐GQD/PEDOT exhibited the lowest resistance of charge transfer (Rct) and equivalent series resistance compared with PEDOT and PVA/PEDOT, indicating that the fast ion diffusion between the electrode and electrolyte interface. PVA‐GQD/PEDOT nanocomposite also showed an excellent stability with retention of 98% after 1000 cycles. John Wiley and Sons 2018-01 Article PeerReviewed text en http://psasir.upm.edu.my/id/eprint/72700/1/Fabrication%20of%20poly.pdf Syed Zainol Abidin, Shariffah Nur Jannah and Mamat, Shuhazlly and Abdul Rashid, Suraya and Zainal, Zulkarnain and Sulaiman, Yusran (2018) Fabrication of poly(vinyl alcohol)-graphene quantum dots coated with poly(3, 4-ethylenedioxythiophene) for supercapacitor. Journal of Polymer Science Part A: Polymer Chemistry, 56 (1). 50 - 58. ISSN 1099-0518; ESSN: 0887-624X https://onlinelibrary.wiley.com/doi/abs/10.1002/pola.28859 10.1002/pola.28859 |
| spellingShingle | Syed Zainol Abidin, Shariffah Nur Jannah Mamat, Shuhazlly Abdul Rashid, Suraya Zainal, Zulkarnain Sulaiman, Yusran Fabrication of poly(vinyl alcohol)-graphene quantum dots coated with poly(3, 4-ethylenedioxythiophene) for supercapacitor |
| title | Fabrication of poly(vinyl alcohol)-graphene quantum dots coated with poly(3, 4-ethylenedioxythiophene) for supercapacitor |
| title_full | Fabrication of poly(vinyl alcohol)-graphene quantum dots coated with poly(3, 4-ethylenedioxythiophene) for supercapacitor |
| title_fullStr | Fabrication of poly(vinyl alcohol)-graphene quantum dots coated with poly(3, 4-ethylenedioxythiophene) for supercapacitor |
| title_full_unstemmed | Fabrication of poly(vinyl alcohol)-graphene quantum dots coated with poly(3, 4-ethylenedioxythiophene) for supercapacitor |
| title_short | Fabrication of poly(vinyl alcohol)-graphene quantum dots coated with poly(3, 4-ethylenedioxythiophene) for supercapacitor |
| title_sort | fabrication of poly vinyl alcohol graphene quantum dots coated with poly 3 4 ethylenedioxythiophene for supercapacitor |
| url | http://psasir.upm.edu.my/id/eprint/72700/1/Fabrication%20of%20poly.pdf |
| work_keys_str_mv | AT syedzainolabidinshariffahnurjannah fabricationofpolyvinylalcoholgraphenequantumdotscoatedwithpoly34ethylenedioxythiopheneforsupercapacitor AT mamatshuhazlly fabricationofpolyvinylalcoholgraphenequantumdotscoatedwithpoly34ethylenedioxythiopheneforsupercapacitor AT abdulrashidsuraya fabricationofpolyvinylalcoholgraphenequantumdotscoatedwithpoly34ethylenedioxythiopheneforsupercapacitor AT zainalzulkarnain fabricationofpolyvinylalcoholgraphenequantumdotscoatedwithpoly34ethylenedioxythiopheneforsupercapacitor AT sulaimanyusran fabricationofpolyvinylalcoholgraphenequantumdotscoatedwithpoly34ethylenedioxythiopheneforsupercapacitor |