Green biofuel production via catalytic pyrolysis of Waste Cooking Oil using Malaysian Dolomite catalyst

Malaysian Dolomite has shown potential deoxygenation catalyst due to high capacity in removing oxygen compound and produce high quality of biofuel with desirable lighter hydrocarbon (C8-C24). The performance of this catalyst was compared with several commercial catalysts in catalytic pyrolysis of Wa...

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Автори: Raja Shahruzzaman, Raja Mohamad Hafriz, Ali, Salmiaton, Yunus, Robiah, Yap, Taufiq Yun Hin
Формат: Стаття
Мова:English
Опубліковано: Universitas Diponegoro 2018
Онлайн доступ:http://psasir.upm.edu.my/id/eprint/72863/1/Green%20biofuel%20production%20via%20catalytic%20pyrolysis%20of%20Waste%20Cooking%20Oil%20using%20Malaysian%20Dolomite%20catalyst.pdf
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author Raja Shahruzzaman, Raja Mohamad Hafriz
Ali, Salmiaton
Yunus, Robiah
Yap, Taufiq Yun Hin
author_facet Raja Shahruzzaman, Raja Mohamad Hafriz
Ali, Salmiaton
Yunus, Robiah
Yap, Taufiq Yun Hin
author_sort Raja Shahruzzaman, Raja Mohamad Hafriz
collection UPM
description Malaysian Dolomite has shown potential deoxygenation catalyst due to high capacity in removing oxygen compound and produce high quality of biofuel with desirable lighter hydrocarbon (C8-C24). The performance of this catalyst was compared with several commercial catalysts in catalytic pyrolysis of Waste Cooking Oil. Calcination at 900 °C in N2 produced catalyst with very high activity due to decomposition of CaMg(CO3)2 phase and formation of MgO-CaO phase. The liquid product showed similar chemical composition of biofuel in the range of gasoline, kerosene and diesel fuel. Furthermore, Malaysian Dolomite showed high reactivity with 76.51 % in total liquid hydrocarbon and the ability to convert the oxygenated compounds into CO2, CO, CH4, H2, hydrocarbon fuel gas, and H2O. Moreover, low acid value (33 mg KOH/g) and low aromatic hydrocarbon content were obtained in the biofuel. Thus, local calcined carbonated material has a potential to act as catalyst in converting waste cooking oil into biofuel.
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spelling upm.eprints-728632021-03-25T22:11:07Z http://psasir.upm.edu.my/id/eprint/72863/ Green biofuel production via catalytic pyrolysis of Waste Cooking Oil using Malaysian Dolomite catalyst Raja Shahruzzaman, Raja Mohamad Hafriz Ali, Salmiaton Yunus, Robiah Yap, Taufiq Yun Hin Malaysian Dolomite has shown potential deoxygenation catalyst due to high capacity in removing oxygen compound and produce high quality of biofuel with desirable lighter hydrocarbon (C8-C24). The performance of this catalyst was compared with several commercial catalysts in catalytic pyrolysis of Waste Cooking Oil. Calcination at 900 °C in N2 produced catalyst with very high activity due to decomposition of CaMg(CO3)2 phase and formation of MgO-CaO phase. The liquid product showed similar chemical composition of biofuel in the range of gasoline, kerosene and diesel fuel. Furthermore, Malaysian Dolomite showed high reactivity with 76.51 % in total liquid hydrocarbon and the ability to convert the oxygenated compounds into CO2, CO, CH4, H2, hydrocarbon fuel gas, and H2O. Moreover, low acid value (33 mg KOH/g) and low aromatic hydrocarbon content were obtained in the biofuel. Thus, local calcined carbonated material has a potential to act as catalyst in converting waste cooking oil into biofuel. Universitas Diponegoro 2018-12 Article PeerReviewed text en http://psasir.upm.edu.my/id/eprint/72863/1/Green%20biofuel%20production%20via%20catalytic%20pyrolysis%20of%20Waste%20Cooking%20Oil%20using%20Malaysian%20Dolomite%20catalyst.pdf Raja Shahruzzaman, Raja Mohamad Hafriz and Ali, Salmiaton and Yunus, Robiah and Yap, Taufiq Yun Hin (2018) Green biofuel production via catalytic pyrolysis of Waste Cooking Oil using Malaysian Dolomite catalyst. Bulletin of Chemical Reaction Engineering and Catalysis, 13 (3). 489 - 501. ISSN 1978-2993 https://ejournal2.undip.ac.id/index.php/bcrec/article/view/1956 10.9767/bcrec.13.3.1956.489-501
spellingShingle Raja Shahruzzaman, Raja Mohamad Hafriz
Ali, Salmiaton
Yunus, Robiah
Yap, Taufiq Yun Hin
Green biofuel production via catalytic pyrolysis of Waste Cooking Oil using Malaysian Dolomite catalyst
title Green biofuel production via catalytic pyrolysis of Waste Cooking Oil using Malaysian Dolomite catalyst
title_full Green biofuel production via catalytic pyrolysis of Waste Cooking Oil using Malaysian Dolomite catalyst
title_fullStr Green biofuel production via catalytic pyrolysis of Waste Cooking Oil using Malaysian Dolomite catalyst
title_full_unstemmed Green biofuel production via catalytic pyrolysis of Waste Cooking Oil using Malaysian Dolomite catalyst
title_short Green biofuel production via catalytic pyrolysis of Waste Cooking Oil using Malaysian Dolomite catalyst
title_sort green biofuel production via catalytic pyrolysis of waste cooking oil using malaysian dolomite catalyst
url http://psasir.upm.edu.my/id/eprint/72863/1/Green%20biofuel%20production%20via%20catalytic%20pyrolysis%20of%20Waste%20Cooking%20Oil%20using%20Malaysian%20Dolomite%20catalyst.pdf
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