Kinetic and thermodynamic of heterogeneously K₃PO₄/AC-catalysed transesterification via pseudo-first order mechanism and eyring-polanyi equation
The use of carbon-based catalysts has drawn so much interest in biodiesel production due to improved reaction performance. However, there was lack of comprehensive studies in term of its kinetic and thermodynamic perspective. Therefore, a methodical study is essential to uncover the influence of the...
| Main Authors: | , , , , , , , |
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| Format: | Article |
| Language: | English |
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Elsevier
2018
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| Online Access: | http://psasir.upm.edu.my/id/eprint/74787/1/Kinetic%20and%20thermodynamic%20of%20heterogeneously%20K%E2%82%83PO%E2%82%84ACcatalysed%20transesterification%20via%20pseudo-first%20order%20mechanism%20and%20eyring-polanyi%20equation.pdf |
| _version_ | 1825950377452765184 |
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| author | Ahmad Farid, Mohammed Abdillah Hassan, Mohd Ali Yap, Taufiq Yun Hin Ibrahim, Mohd Lokman Hasan, Muhamad Yusuf Mohd Ali, Ahmad Amiruddin Othman, Mohd Ridzuan Shirai, Yoshihito |
| author_facet | Ahmad Farid, Mohammed Abdillah Hassan, Mohd Ali Yap, Taufiq Yun Hin Ibrahim, Mohd Lokman Hasan, Muhamad Yusuf Mohd Ali, Ahmad Amiruddin Othman, Mohd Ridzuan Shirai, Yoshihito |
| author_sort | Ahmad Farid, Mohammed Abdillah |
| collection | UPM |
| description | The use of carbon-based catalysts has drawn so much interest in biodiesel production due to improved reaction performance. However, there was lack of comprehensive studies in term of its kinetic and thermodynamic perspective. Therefore, a methodical study is essential to uncover the influence of the carbon catalyst with respect to reaction rate and yield. This study represents kinetic and thermodynamic of heterogeneously K₃PO₄/AC-catalysed transesterification. It was done correspondingly via pseudo-first order mechanism and Eyring-Polanyi equation, whereby, under the optimal reaction temperature of 333.15 K, all data have fitted satisfactorily in both models with resulted R² of 0.99, respectively. Activation energy (Ea) and Gibbs free energy (ΔG) were calculated as 34.2 kJ mol⁻¹ and −33.68 kJ mol⁻¹, indicating the reaction was exergonic and spontaneous at high temperature. |
| first_indexed | 2024-03-06T10:13:40Z |
| format | Article |
| id | upm.eprints-74787 |
| institution | Universiti Putra Malaysia |
| language | English |
| last_indexed | 2024-03-06T10:13:40Z |
| publishDate | 2018 |
| publisher | Elsevier |
| record_format | dspace |
| spelling | upm.eprints-747872020-12-10T21:13:17Z http://psasir.upm.edu.my/id/eprint/74787/ Kinetic and thermodynamic of heterogeneously K₃PO₄/AC-catalysed transesterification via pseudo-first order mechanism and eyring-polanyi equation Ahmad Farid, Mohammed Abdillah Hassan, Mohd Ali Yap, Taufiq Yun Hin Ibrahim, Mohd Lokman Hasan, Muhamad Yusuf Mohd Ali, Ahmad Amiruddin Othman, Mohd Ridzuan Shirai, Yoshihito The use of carbon-based catalysts has drawn so much interest in biodiesel production due to improved reaction performance. However, there was lack of comprehensive studies in term of its kinetic and thermodynamic perspective. Therefore, a methodical study is essential to uncover the influence of the carbon catalyst with respect to reaction rate and yield. This study represents kinetic and thermodynamic of heterogeneously K₃PO₄/AC-catalysed transesterification. It was done correspondingly via pseudo-first order mechanism and Eyring-Polanyi equation, whereby, under the optimal reaction temperature of 333.15 K, all data have fitted satisfactorily in both models with resulted R² of 0.99, respectively. Activation energy (Ea) and Gibbs free energy (ΔG) were calculated as 34.2 kJ mol⁻¹ and −33.68 kJ mol⁻¹, indicating the reaction was exergonic and spontaneous at high temperature. Elsevier 2018-11 Article PeerReviewed text en http://psasir.upm.edu.my/id/eprint/74787/1/Kinetic%20and%20thermodynamic%20of%20heterogeneously%20K%E2%82%83PO%E2%82%84ACcatalysed%20transesterification%20via%20pseudo-first%20order%20mechanism%20and%20eyring-polanyi%20equation.pdf Ahmad Farid, Mohammed Abdillah and Hassan, Mohd Ali and Yap, Taufiq Yun Hin and Ibrahim, Mohd Lokman and Hasan, Muhamad Yusuf and Mohd Ali, Ahmad Amiruddin and Othman, Mohd Ridzuan and Shirai, Yoshihito (2018) Kinetic and thermodynamic of heterogeneously K₃PO₄/AC-catalysed transesterification via pseudo-first order mechanism and eyring-polanyi equation. Fuel, 232. 653 - 658. ISSN 0016-2361; ESSN: 1873-7153 https://www.sciencedirect.com/science/article/abs/pii/S0016236118310494 10.1016/j.fuel.2018.06.029 |
| spellingShingle | Ahmad Farid, Mohammed Abdillah Hassan, Mohd Ali Yap, Taufiq Yun Hin Ibrahim, Mohd Lokman Hasan, Muhamad Yusuf Mohd Ali, Ahmad Amiruddin Othman, Mohd Ridzuan Shirai, Yoshihito Kinetic and thermodynamic of heterogeneously K₃PO₄/AC-catalysed transesterification via pseudo-first order mechanism and eyring-polanyi equation |
| title | Kinetic and thermodynamic of heterogeneously K₃PO₄/AC-catalysed transesterification via pseudo-first order mechanism and eyring-polanyi equation |
| title_full | Kinetic and thermodynamic of heterogeneously K₃PO₄/AC-catalysed transesterification via pseudo-first order mechanism and eyring-polanyi equation |
| title_fullStr | Kinetic and thermodynamic of heterogeneously K₃PO₄/AC-catalysed transesterification via pseudo-first order mechanism and eyring-polanyi equation |
| title_full_unstemmed | Kinetic and thermodynamic of heterogeneously K₃PO₄/AC-catalysed transesterification via pseudo-first order mechanism and eyring-polanyi equation |
| title_short | Kinetic and thermodynamic of heterogeneously K₃PO₄/AC-catalysed transesterification via pseudo-first order mechanism and eyring-polanyi equation |
| title_sort | kinetic and thermodynamic of heterogeneously k₃po₄ ac catalysed transesterification via pseudo first order mechanism and eyring polanyi equation |
| url | http://psasir.upm.edu.my/id/eprint/74787/1/Kinetic%20and%20thermodynamic%20of%20heterogeneously%20K%E2%82%83PO%E2%82%84ACcatalysed%20transesterification%20via%20pseudo-first%20order%20mechanism%20and%20eyring-polanyi%20equation.pdf |
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