Modified waste egg shell derived bifunctional catalyst for biodiesel production from high FFA waste cooking oil: a review

Global energy crisis are as a result of gradual depletion of fossil fuel reserves, coupled with population growth in developing countries. Besides, fossil fuels are not environmentally benign as they are associated with problems, i.e. global warming, high toxicity and non biodegradability, hence it...

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Main Authors: Mansir, Nasar, Siow, Hwa Teo, Rashid, Umer, Saiman, Mohd Izham, Yen, Ping Tan, Alsultan, G. Abdulkareem, Yap, Taufiq Yun Hin
Format: Article
Language:English
Published: Elsevier 2018
Online Access:http://psasir.upm.edu.my/id/eprint/75012/1/Modified%20waste%20egg%20shell%20derived%20bifunctional%20catalyst%20for%20biodiesel%20production%20from%20high%20FFA%20waste%20cooking%20oil%20a%20review.pdf
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author Mansir, Nasar
Siow, Hwa Teo
Rashid, Umer
Saiman, Mohd Izham
Yen, Ping Tan
Alsultan, G. Abdulkareem
Yap, Taufiq Yun Hin
author_facet Mansir, Nasar
Siow, Hwa Teo
Rashid, Umer
Saiman, Mohd Izham
Yen, Ping Tan
Alsultan, G. Abdulkareem
Yap, Taufiq Yun Hin
author_sort Mansir, Nasar
collection UPM
description Global energy crisis are as a result of gradual depletion of fossil fuel reserves, coupled with population growth in developing countries. Besides, fossil fuels are not environmentally benign as they are associated with problems, i.e. global warming, high toxicity and non biodegradability, hence it is considered as non sustainable source of energy. Without doubt, biofuel-based energy is a promising long-term energy source that can reduce the over dependence on fossil fuels as a result of feedstocks availability and renewability. However, biodiesel production from vegetable oil using the traditional homogeneous catalytic system is no longer defensible by industries in the near future, particularly due to food-fuel rivalry and ecological problems related to the conventional homogeneous catalytic system. This review presents a comprehensive step by step process of converting waste cooking oil (WCO) to biodiesel, using modified waste egg shell catalyst. The modified waste egg shell derived bi-functional catalyst could easily be removed from the fatty acid methyl esters (FAME) with limited environmental effects. The new modified catalytic system is able to convert the high free fatty acid (FFA) content waste cooking oil to FAME efficiently under moderate reaction conditions. Utilization of waste cooking oil as a feedstock for biodiesel production will reduce the food security issues that stem the biodiesel production from food-grade oil. Moreover, it will reduce the total production cost of the FAME due to its low cost. The major objective of this article is to demonstrate the current state of the use of heterogeneous bifunctional acid/base catalyst to produce biodiesel from green and non-edible waste cooking oil. At the end of the article, perspectives and future developments are also presented.
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spelling upm.eprints-750122020-04-20T16:16:51Z http://psasir.upm.edu.my/id/eprint/75012/ Modified waste egg shell derived bifunctional catalyst for biodiesel production from high FFA waste cooking oil: a review Mansir, Nasar Siow, Hwa Teo Rashid, Umer Saiman, Mohd Izham Yen, Ping Tan Alsultan, G. Abdulkareem Yap, Taufiq Yun Hin Global energy crisis are as a result of gradual depletion of fossil fuel reserves, coupled with population growth in developing countries. Besides, fossil fuels are not environmentally benign as they are associated with problems, i.e. global warming, high toxicity and non biodegradability, hence it is considered as non sustainable source of energy. Without doubt, biofuel-based energy is a promising long-term energy source that can reduce the over dependence on fossil fuels as a result of feedstocks availability and renewability. However, biodiesel production from vegetable oil using the traditional homogeneous catalytic system is no longer defensible by industries in the near future, particularly due to food-fuel rivalry and ecological problems related to the conventional homogeneous catalytic system. This review presents a comprehensive step by step process of converting waste cooking oil (WCO) to biodiesel, using modified waste egg shell catalyst. The modified waste egg shell derived bi-functional catalyst could easily be removed from the fatty acid methyl esters (FAME) with limited environmental effects. The new modified catalytic system is able to convert the high free fatty acid (FFA) content waste cooking oil to FAME efficiently under moderate reaction conditions. Utilization of waste cooking oil as a feedstock for biodiesel production will reduce the food security issues that stem the biodiesel production from food-grade oil. Moreover, it will reduce the total production cost of the FAME due to its low cost. The major objective of this article is to demonstrate the current state of the use of heterogeneous bifunctional acid/base catalyst to produce biodiesel from green and non-edible waste cooking oil. At the end of the article, perspectives and future developments are also presented. Elsevier 2018 Article PeerReviewed text en http://psasir.upm.edu.my/id/eprint/75012/1/Modified%20waste%20egg%20shell%20derived%20bifunctional%20catalyst%20for%20biodiesel%20production%20from%20high%20FFA%20waste%20cooking%20oil%20a%20review.pdf Mansir, Nasar and Siow, Hwa Teo and Rashid, Umer and Saiman, Mohd Izham and Yen, Ping Tan and Alsultan, G. Abdulkareem and Yap, Taufiq Yun Hin (2018) Modified waste egg shell derived bifunctional catalyst for biodiesel production from high FFA waste cooking oil: a review. Renewable and Sustainable Energy Reviews, 83 (pt. 3). 3645 - 3655. ISSN 1364-0321 10.1016/j.rser.2017.10.098
spellingShingle Mansir, Nasar
Siow, Hwa Teo
Rashid, Umer
Saiman, Mohd Izham
Yen, Ping Tan
Alsultan, G. Abdulkareem
Yap, Taufiq Yun Hin
Modified waste egg shell derived bifunctional catalyst for biodiesel production from high FFA waste cooking oil: a review
title Modified waste egg shell derived bifunctional catalyst for biodiesel production from high FFA waste cooking oil: a review
title_full Modified waste egg shell derived bifunctional catalyst for biodiesel production from high FFA waste cooking oil: a review
title_fullStr Modified waste egg shell derived bifunctional catalyst for biodiesel production from high FFA waste cooking oil: a review
title_full_unstemmed Modified waste egg shell derived bifunctional catalyst for biodiesel production from high FFA waste cooking oil: a review
title_short Modified waste egg shell derived bifunctional catalyst for biodiesel production from high FFA waste cooking oil: a review
title_sort modified waste egg shell derived bifunctional catalyst for biodiesel production from high ffa waste cooking oil a review
url http://psasir.upm.edu.my/id/eprint/75012/1/Modified%20waste%20egg%20shell%20derived%20bifunctional%20catalyst%20for%20biodiesel%20production%20from%20high%20FFA%20waste%20cooking%20oil%20a%20review.pdf
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