Benzyl N0-[1-(3-pyridyl)ethylidene]-hydrazinecarbodithioate
The title compound, C15H5N2S2, crystallizes as a trans–cis conformer. The thione sulfur is in a trans position with the methyl pyridyl fragment with respect to the C—N bond but adopts a cis position with the benzyl ring across the C—S bond. The dihedral angle between the planar quinoline ring a...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English English |
| Published: |
International Union of Crystallography
2007
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| Online Access: | http://psasir.upm.edu.my/id/eprint/7515/1/Benzyl_N0-%5B1-%283-pyridyl%29ethylidene%5D-.pdf |
| _version_ | 1825944221983440896 |
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| author | How, Fiona Ni Foong Watkin, David J. Crouse, Karen Anne Mohamed Tahir, Mohamed Ibrahim |
| author_facet | How, Fiona Ni Foong Watkin, David J. Crouse, Karen Anne Mohamed Tahir, Mohamed Ibrahim |
| author_sort | How, Fiona Ni Foong |
| collection | UPM |
| description | The title compound, C15H5N2S2, crystallizes as a trans–cis
conformer. The thione sulfur is in a trans position with the
methyl pyridyl fragment with respect to the C—N bond but
adopts a cis position with the benzyl ring across the C—S
bond. The dihedral angle between the planar quinoline ring
and the dithiocarbazate unit is 103.70 (1). The inclination of the dithiocarbazate unit with the benzyl group is 17.20 (1).There are strong – stacking interactions between pairs of dithiocarbazate units and also pairs of pyridine rings [3.27 (5)and 3.28 (5) A ° , respectively]. A long-distance intermolecular N—H N hydrogen bond [3.171 (2) A ° ] also stabilizes the structure. |
| first_indexed | 2024-03-06T07:12:28Z |
| format | Article |
| id | upm.eprints-7515 |
| institution | Universiti Putra Malaysia |
| language | English English |
| last_indexed | 2024-03-06T07:12:28Z |
| publishDate | 2007 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | upm.eprints-75152013-05-27T07:35:21Z http://psasir.upm.edu.my/id/eprint/7515/ Benzyl N0-[1-(3-pyridyl)ethylidene]-hydrazinecarbodithioate How, Fiona Ni Foong Watkin, David J. Crouse, Karen Anne Mohamed Tahir, Mohamed Ibrahim The title compound, C15H5N2S2, crystallizes as a trans–cis conformer. The thione sulfur is in a trans position with the methyl pyridyl fragment with respect to the C—N bond but adopts a cis position with the benzyl ring across the C—S bond. The dihedral angle between the planar quinoline ring and the dithiocarbazate unit is 103.70 (1). The inclination of the dithiocarbazate unit with the benzyl group is 17.20 (1).There are strong – stacking interactions between pairs of dithiocarbazate units and also pairs of pyridine rings [3.27 (5)and 3.28 (5) A ° , respectively]. A long-distance intermolecular N—H N hydrogen bond [3.171 (2) A ° ] also stabilizes the structure. International Union of Crystallography 2007 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/7515/1/Benzyl_N0-%5B1-%283-pyridyl%29ethylidene%5D-.pdf How, Fiona Ni Foong and Watkin, David J. and Crouse, Karen Anne and Mohamed Tahir, Mohamed Ibrahim (2007) Benzyl N0-[1-(3-pyridyl)ethylidene]-hydrazinecarbodithioate. Acta Crystallographica Section E: Structure Reports Online, 63 (3). pp. 3023-3024. ISSN 1600-5368 http://dx.doi.org/10.1107/S1600536807025056 10.1107/S1600536807025056 English |
| spellingShingle | How, Fiona Ni Foong Watkin, David J. Crouse, Karen Anne Mohamed Tahir, Mohamed Ibrahim Benzyl N0-[1-(3-pyridyl)ethylidene]-hydrazinecarbodithioate |
| title | Benzyl N0-[1-(3-pyridyl)ethylidene]-hydrazinecarbodithioate |
| title_full | Benzyl N0-[1-(3-pyridyl)ethylidene]-hydrazinecarbodithioate |
| title_fullStr | Benzyl N0-[1-(3-pyridyl)ethylidene]-hydrazinecarbodithioate |
| title_full_unstemmed | Benzyl N0-[1-(3-pyridyl)ethylidene]-hydrazinecarbodithioate |
| title_short | Benzyl N0-[1-(3-pyridyl)ethylidene]-hydrazinecarbodithioate |
| title_sort | benzyl n0 1 3 pyridyl ethylidene hydrazinecarbodithioate |
| url | http://psasir.upm.edu.my/id/eprint/7515/1/Benzyl_N0-%5B1-%283-pyridyl%29ethylidene%5D-.pdf |
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