S-Quinolin-2-ylmethyldithiocarbazate
In the title compound, C11H11N2S2, there is an intramolecular N—H N [2.778 (2) A ° ] hydrogen bond linking the quinoline N atom and the imino N atom. The planar quinoline ring system forms an angle of 67.7 (1) with the dithiocarbazate group. Bond angles for both S—C—S [115.66 (8)] and N—C—S [119.05...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English English |
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International Union of Crystallography
2007
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| Online Access: | http://psasir.upm.edu.my/id/eprint/7516/1/S-Quinolin-2-ylmethyldithiocarbazate.pdf |
| _version_ | 1796967342528266240 |
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| author | How, Fiona Ni Foong Watkin, David J. Crouse, Karen Anne Mohamed Tahir, Mohamed Ibrahim |
| author_facet | How, Fiona Ni Foong Watkin, David J. Crouse, Karen Anne Mohamed Tahir, Mohamed Ibrahim |
| author_sort | How, Fiona Ni Foong |
| collection | UPM |
| description | In the title compound, C11H11N2S2, there is an intramolecular N—H N [2.778 (2) A ° ] hydrogen bond linking the quinoline N atom and the imino N atom. The planar quinoline ring system forms an angle of 67.7 (1) with the dithiocarbazate group. Bond angles for both S—C—S [115.66 (8)] and N—C—S [119.05 (11)] are comparable with cis–trans S-methyldithiocarbazate but differ from those found in trans–cis Smethyldithiocarbazate and trans–cis S-benzyldithiocarbazate.This is due to the N—H N hydrogen bond that exists only in the cis–trans conformation found for the title compound. |
| first_indexed | 2024-03-06T07:12:28Z |
| format | Article |
| id | upm.eprints-7516 |
| institution | Universiti Putra Malaysia |
| language | English English |
| last_indexed | 2024-03-06T07:12:28Z |
| publishDate | 2007 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | upm.eprints-75162013-05-27T07:35:21Z http://psasir.upm.edu.my/id/eprint/7516/ S-Quinolin-2-ylmethyldithiocarbazate How, Fiona Ni Foong Watkin, David J. Crouse, Karen Anne Mohamed Tahir, Mohamed Ibrahim In the title compound, C11H11N2S2, there is an intramolecular N—H N [2.778 (2) A ° ] hydrogen bond linking the quinoline N atom and the imino N atom. The planar quinoline ring system forms an angle of 67.7 (1) with the dithiocarbazate group. Bond angles for both S—C—S [115.66 (8)] and N—C—S [119.05 (11)] are comparable with cis–trans S-methyldithiocarbazate but differ from those found in trans–cis Smethyldithiocarbazate and trans–cis S-benzyldithiocarbazate.This is due to the N—H N hydrogen bond that exists only in the cis–trans conformation found for the title compound. International Union of Crystallography 2007 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/7516/1/S-Quinolin-2-ylmethyldithiocarbazate.pdf How, Fiona Ni Foong and Watkin, David J. and Crouse, Karen Anne and Mohamed Tahir, Mohamed Ibrahim (2007) S-Quinolin-2-ylmethyldithiocarbazate. Acta Crystallographica Section E: Structure Reports Online, 63 (7). pp. 3137-3138. ISSN 1600-5368 http://dx.doi.org/10.1107/S1600536807024609 10.1107/S1600536807024609 English |
| spellingShingle | How, Fiona Ni Foong Watkin, David J. Crouse, Karen Anne Mohamed Tahir, Mohamed Ibrahim S-Quinolin-2-ylmethyldithiocarbazate |
| title | S-Quinolin-2-ylmethyldithiocarbazate |
| title_full | S-Quinolin-2-ylmethyldithiocarbazate |
| title_fullStr | S-Quinolin-2-ylmethyldithiocarbazate |
| title_full_unstemmed | S-Quinolin-2-ylmethyldithiocarbazate |
| title_short | S-Quinolin-2-ylmethyldithiocarbazate |
| title_sort | s quinolin 2 ylmethyldithiocarbazate |
| url | http://psasir.upm.edu.my/id/eprint/7516/1/S-Quinolin-2-ylmethyldithiocarbazate.pdf |
| work_keys_str_mv | AT howfionanifoong squinolin2ylmethyldithiocarbazate AT watkindavidj squinolin2ylmethyldithiocarbazate AT crousekarenanne squinolin2ylmethyldithiocarbazate AT mohamedtahirmohamedibrahim squinolin2ylmethyldithiocarbazate |