Facile fabrication of PVA nanofiber coated with PEDOT as a counter electrodes for dye-sensitized solar cell

Polyvinyl alcohol (PVA) nanofibers coated with poly(3,4-ethylenedioxythiophene) (PEDOT) as a counter electrode (CE) is a promising material to substitute platinum CE for dye-sensitized solar cell due to the high conductivity of PEDOT and high surface area to volume ratio of PVA. PVA nanofibers and P...

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Main Authors: Basri, Nur Amilah Fadlina, Mustafa, Muhammad Norhaffis, Sulaiman, Yusran
Format: Article
Published: Springer 2019
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author Basri, Nur Amilah Fadlina
Mustafa, Muhammad Norhaffis
Sulaiman, Yusran
author_facet Basri, Nur Amilah Fadlina
Mustafa, Muhammad Norhaffis
Sulaiman, Yusran
author_sort Basri, Nur Amilah Fadlina
collection UPM
description Polyvinyl alcohol (PVA) nanofibers coated with poly(3,4-ethylenedioxythiophene) (PEDOT) as a counter electrode (CE) is a promising material to substitute platinum CE for dye-sensitized solar cell due to the high conductivity of PEDOT and high surface area to volume ratio of PVA. PVA nanofibers and PEDOT were prepared through facile techniques of electrospinning and electropolymerization, respectively. Field emission scanning electron microscopy revealed that PEDOT was distributed evenly on PVA nanofibers with porous cauliflower-like structure. PVA/PEDOT nanofibers CE had low charge transfer resistance (Rct) and possessed a good electrocatalytic activity with a low value of peak-to-peak separation (Epp = 0.34 V), thus an improved efficiency of 2.11% was obtained in comparison to platinum (1.14%), PEDOT (1.39%) and PVA nanofibers (0.017%).
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spelling upm.eprints-798522022-11-15T08:54:27Z http://psasir.upm.edu.my/id/eprint/79852/ Facile fabrication of PVA nanofiber coated with PEDOT as a counter electrodes for dye-sensitized solar cell Basri, Nur Amilah Fadlina Mustafa, Muhammad Norhaffis Sulaiman, Yusran Polyvinyl alcohol (PVA) nanofibers coated with poly(3,4-ethylenedioxythiophene) (PEDOT) as a counter electrode (CE) is a promising material to substitute platinum CE for dye-sensitized solar cell due to the high conductivity of PEDOT and high surface area to volume ratio of PVA. PVA nanofibers and PEDOT were prepared through facile techniques of electrospinning and electropolymerization, respectively. Field emission scanning electron microscopy revealed that PEDOT was distributed evenly on PVA nanofibers with porous cauliflower-like structure. PVA/PEDOT nanofibers CE had low charge transfer resistance (Rct) and possessed a good electrocatalytic activity with a low value of peak-to-peak separation (Epp = 0.34 V), thus an improved efficiency of 2.11% was obtained in comparison to platinum (1.14%), PEDOT (1.39%) and PVA nanofibers (0.017%). Springer 2019 Article PeerReviewed Basri, Nur Amilah Fadlina and Mustafa, Muhammad Norhaffis and Sulaiman, Yusran (2019) Facile fabrication of PVA nanofiber coated with PEDOT as a counter electrodes for dye-sensitized solar cell. Journal of Materials Science: Materials in Electronics, 30 (9). pp. 8705-8711. ISSN 0957-4522; ESSN: 1573-482X https://link.springer.com/article/10.1007/s10854-019-01195-2 10.1007/s10854-019-01195-2
spellingShingle Basri, Nur Amilah Fadlina
Mustafa, Muhammad Norhaffis
Sulaiman, Yusran
Facile fabrication of PVA nanofiber coated with PEDOT as a counter electrodes for dye-sensitized solar cell
title Facile fabrication of PVA nanofiber coated with PEDOT as a counter electrodes for dye-sensitized solar cell
title_full Facile fabrication of PVA nanofiber coated with PEDOT as a counter electrodes for dye-sensitized solar cell
title_fullStr Facile fabrication of PVA nanofiber coated with PEDOT as a counter electrodes for dye-sensitized solar cell
title_full_unstemmed Facile fabrication of PVA nanofiber coated with PEDOT as a counter electrodes for dye-sensitized solar cell
title_short Facile fabrication of PVA nanofiber coated with PEDOT as a counter electrodes for dye-sensitized solar cell
title_sort facile fabrication of pva nanofiber coated with pedot as a counter electrodes for dye sensitized solar cell
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AT mustafamuhammadnorhaffis facilefabricationofpvananofibercoatedwithpedotasacounterelectrodesfordyesensitizedsolarcell
AT sulaimanyusran facilefabricationofpvananofibercoatedwithpedotasacounterelectrodesfordyesensitizedsolarcell