Ternary functionalised carbon nanofiber/polypyrrole/manganese oxide as high specific energy electrode for supercapacitor
A successful fabrication of ternary functionalised carbon nanofibers/polypyrrole/manganese oxide (f-CNFs/PPy/MnO₂) composite was reported. The field emission scanning electron microscopy (FESEM) image had revealed a random distribution of granular PPy and spherical nanoparticles of MnO2 on the surfa...
Main Authors: | , , |
---|---|
Format: | Article |
Language: | English |
Published: |
Elsevier
2019
|
Online Access: | http://psasir.upm.edu.my/id/eprint/82154/1/Ternary%20functionalised%20carbon%20nanofiberpolypyrrolemanganese%20oxide%20as%20high%20specific%20energy%20electrode%20for%20supercapacitor.pdf |
_version_ | 1825951535628025856 |
---|---|
author | Mohd Abdah, Muhammad Amirul Aizat Abdul Rahman, Norizah Sulaiman, Yusran |
author_facet | Mohd Abdah, Muhammad Amirul Aizat Abdul Rahman, Norizah Sulaiman, Yusran |
author_sort | Mohd Abdah, Muhammad Amirul Aizat |
collection | UPM |
description | A successful fabrication of ternary functionalised carbon nanofibers/polypyrrole/manganese oxide (f-CNFs/PPy/MnO₂) composite was reported. The field emission scanning electron microscopy (FESEM) image had revealed a random distribution of granular PPy and spherical nanoparticles of MnO2 on the surface of f-CNFs. The measured contact angle of f-CNFs indicated superhydrophilic nature which can enhance the surface wettability and ionic diffusion. The ternary f-CNFs/PPy/MnO₂ composite displayed a remarkable specific capacitance of 409.88 F/g compared with f-CNFs/MnO₂ (322.96 F/g) and f-CNFs/PPy (290.83 F/g). The electrochemical properties of f-CNFs/PPy/MnO₂ had contributed to the appreciable specific energy of 42.53 Wh/kg at a specific power of 297.32 W/kg. The assembled f-CNFs/PPy/MnO₂ composite also showed low resistance of charge transfer (Rct) value (3.40 Ω) with a better cycle life (86.30% capacitance retention over 3000 cycles). Hence, ternary f-CNFs/PPy/MnO₂ can be suggested as a high-performance electrode for supercapacitor. |
first_indexed | 2024-03-06T10:31:27Z |
format | Article |
id | upm.eprints-82154 |
institution | Universiti Putra Malaysia |
language | English |
last_indexed | 2024-03-06T10:31:27Z |
publishDate | 2019 |
publisher | Elsevier |
record_format | dspace |
spelling | upm.eprints-821542021-02-01T20:00:58Z http://psasir.upm.edu.my/id/eprint/82154/ Ternary functionalised carbon nanofiber/polypyrrole/manganese oxide as high specific energy electrode for supercapacitor Mohd Abdah, Muhammad Amirul Aizat Abdul Rahman, Norizah Sulaiman, Yusran A successful fabrication of ternary functionalised carbon nanofibers/polypyrrole/manganese oxide (f-CNFs/PPy/MnO₂) composite was reported. The field emission scanning electron microscopy (FESEM) image had revealed a random distribution of granular PPy and spherical nanoparticles of MnO2 on the surface of f-CNFs. The measured contact angle of f-CNFs indicated superhydrophilic nature which can enhance the surface wettability and ionic diffusion. The ternary f-CNFs/PPy/MnO₂ composite displayed a remarkable specific capacitance of 409.88 F/g compared with f-CNFs/MnO₂ (322.96 F/g) and f-CNFs/PPy (290.83 F/g). The electrochemical properties of f-CNFs/PPy/MnO₂ had contributed to the appreciable specific energy of 42.53 Wh/kg at a specific power of 297.32 W/kg. The assembled f-CNFs/PPy/MnO₂ composite also showed low resistance of charge transfer (Rct) value (3.40 Ω) with a better cycle life (86.30% capacitance retention over 3000 cycles). Hence, ternary f-CNFs/PPy/MnO₂ can be suggested as a high-performance electrode for supercapacitor. Elsevier 2019-05 Article PeerReviewed text en http://psasir.upm.edu.my/id/eprint/82154/1/Ternary%20functionalised%20carbon%20nanofiberpolypyrrolemanganese%20oxide%20as%20high%20specific%20energy%20electrode%20for%20supercapacitor.pdf Mohd Abdah, Muhammad Amirul Aizat and Abdul Rahman, Norizah and Sulaiman, Yusran (2019) Ternary functionalised carbon nanofiber/polypyrrole/manganese oxide as high specific energy electrode for supercapacitor. Ceramics International, 45 (7; Pt. A). pp. 8433-8439. ISSN 0272-8842 10.1016/j.ceramint.2019.01.152 |
spellingShingle | Mohd Abdah, Muhammad Amirul Aizat Abdul Rahman, Norizah Sulaiman, Yusran Ternary functionalised carbon nanofiber/polypyrrole/manganese oxide as high specific energy electrode for supercapacitor |
title | Ternary functionalised carbon nanofiber/polypyrrole/manganese oxide as high specific energy electrode for supercapacitor |
title_full | Ternary functionalised carbon nanofiber/polypyrrole/manganese oxide as high specific energy electrode for supercapacitor |
title_fullStr | Ternary functionalised carbon nanofiber/polypyrrole/manganese oxide as high specific energy electrode for supercapacitor |
title_full_unstemmed | Ternary functionalised carbon nanofiber/polypyrrole/manganese oxide as high specific energy electrode for supercapacitor |
title_short | Ternary functionalised carbon nanofiber/polypyrrole/manganese oxide as high specific energy electrode for supercapacitor |
title_sort | ternary functionalised carbon nanofiber polypyrrole manganese oxide as high specific energy electrode for supercapacitor |
url | http://psasir.upm.edu.my/id/eprint/82154/1/Ternary%20functionalised%20carbon%20nanofiberpolypyrrolemanganese%20oxide%20as%20high%20specific%20energy%20electrode%20for%20supercapacitor.pdf |
work_keys_str_mv | AT mohdabdahmuhammadamirulaizat ternaryfunctionalisedcarbonnanofiberpolypyrrolemanganeseoxideashighspecificenergyelectrodeforsupercapacitor AT abdulrahmannorizah ternaryfunctionalisedcarbonnanofiberpolypyrrolemanganeseoxideashighspecificenergyelectrodeforsupercapacitor AT sulaimanyusran ternaryfunctionalisedcarbonnanofiberpolypyrrolemanganeseoxideashighspecificenergyelectrodeforsupercapacitor |