Study of rice husk silicate effects on the elastic, physical and structural properties of borotellurite glasses

Successful extraction of high purity SiO₂ (about 99%) from rice husk (waste) was achieved in this work using the cold acid leaching method. Glass series [(TeO₂)0.₇ (B₂O₃)0.₃]1-x (SiO₂)x were fabricated using the rice husk silicate (RHS) by melt-quenching method. The samples were subjected to X-ray d...

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Main Authors: Halimah, Mohamed Kamari, Aliyu, Umar Sa'ad, Chan, Kar Tim, Abdul Latif, Amirah, Azlan, M. N., Abubakar, A. I., Muhammad Hamza, Abdulkarim
Format: Article
Language:English
Published: Elsevier 2019
Online Access:http://psasir.upm.edu.my/id/eprint/82293/1/Study%20of%20rice%20husk.pdf
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author Halimah, Mohamed Kamari
Aliyu, Umar Sa'ad
Chan, Kar Tim
Abdul Latif, Amirah
Azlan, M. N.
Abubakar, A. I.
Muhammad Hamza, Abdulkarim
author_facet Halimah, Mohamed Kamari
Aliyu, Umar Sa'ad
Chan, Kar Tim
Abdul Latif, Amirah
Azlan, M. N.
Abubakar, A. I.
Muhammad Hamza, Abdulkarim
author_sort Halimah, Mohamed Kamari
collection UPM
description Successful extraction of high purity SiO₂ (about 99%) from rice husk (waste) was achieved in this work using the cold acid leaching method. Glass series [(TeO₂)0.₇ (B₂O₃)0.₃]1-x (SiO₂)x were fabricated using the rice husk silicate (RHS) by melt-quenching method. The samples were subjected to X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FTIR) characterization to study the structural nature of the glass system. Density and ultrasonic velocities were measured to obtain the elastic constants for the various silicate proportions in the glass using ultrasonic data obtained from non-destructive ultrasonic probing technique. The elastic moduli calculated from the obtained data were found to have increased with the addition of more RHS in the glass. Other parameters studied include the microhardness (H), Poisson's ratio (σ), softening temperature (ϴD) and fractal bond connectivity (d) and the fluctuation free volume (fugacity, fg). A very unusual occurrence was observed as microhardness value decreases in the glass system as more RHS (SiO₂) is introduced. The quality of the glass in terms of elastic behavior improved with addition of RHS in the borotellurite glass network.
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spelling upm.eprints-822932020-10-16T20:49:26Z http://psasir.upm.edu.my/id/eprint/82293/ Study of rice husk silicate effects on the elastic, physical and structural properties of borotellurite glasses Halimah, Mohamed Kamari Aliyu, Umar Sa'ad Chan, Kar Tim Abdul Latif, Amirah Azlan, M. N. Abubakar, A. I. Muhammad Hamza, Abdulkarim Successful extraction of high purity SiO₂ (about 99%) from rice husk (waste) was achieved in this work using the cold acid leaching method. Glass series [(TeO₂)0.₇ (B₂O₃)0.₃]1-x (SiO₂)x were fabricated using the rice husk silicate (RHS) by melt-quenching method. The samples were subjected to X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FTIR) characterization to study the structural nature of the glass system. Density and ultrasonic velocities were measured to obtain the elastic constants for the various silicate proportions in the glass using ultrasonic data obtained from non-destructive ultrasonic probing technique. The elastic moduli calculated from the obtained data were found to have increased with the addition of more RHS in the glass. Other parameters studied include the microhardness (H), Poisson's ratio (σ), softening temperature (ϴD) and fractal bond connectivity (d) and the fluctuation free volume (fugacity, fg). A very unusual occurrence was observed as microhardness value decreases in the glass system as more RHS (SiO₂) is introduced. The quality of the glass in terms of elastic behavior improved with addition of RHS in the borotellurite glass network. Elsevier 2019-12 Article PeerReviewed text en http://psasir.upm.edu.my/id/eprint/82293/1/Study%20of%20rice%20husk.pdf Halimah, Mohamed Kamari and Aliyu, Umar Sa'ad and Chan, Kar Tim and Abdul Latif, Amirah and Azlan, M. N. and Abubakar, A. I. and Muhammad Hamza, Abdulkarim (2019) Study of rice husk silicate effects on the elastic, physical and structural properties of borotellurite glasses. Materials Chemistry and Physics, 238. art. no. 121891. pp. 1-8. ISSN 0254-0584 10.1016/j.matchemphys.2019.121891
spellingShingle Halimah, Mohamed Kamari
Aliyu, Umar Sa'ad
Chan, Kar Tim
Abdul Latif, Amirah
Azlan, M. N.
Abubakar, A. I.
Muhammad Hamza, Abdulkarim
Study of rice husk silicate effects on the elastic, physical and structural properties of borotellurite glasses
title Study of rice husk silicate effects on the elastic, physical and structural properties of borotellurite glasses
title_full Study of rice husk silicate effects on the elastic, physical and structural properties of borotellurite glasses
title_fullStr Study of rice husk silicate effects on the elastic, physical and structural properties of borotellurite glasses
title_full_unstemmed Study of rice husk silicate effects on the elastic, physical and structural properties of borotellurite glasses
title_short Study of rice husk silicate effects on the elastic, physical and structural properties of borotellurite glasses
title_sort study of rice husk silicate effects on the elastic physical and structural properties of borotellurite glasses
url http://psasir.upm.edu.my/id/eprint/82293/1/Study%20of%20rice%20husk.pdf
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