X-ray photoelectron spectroscopy (XPS) and gamma-ray shielding investigation of boro-silicate glasses contained alkali/alkaline modifier

In the present work, seven glass samples have been prepared utilizing melt-quenching method with composition of 40B₂O₃-10SiO₂-10Al₂O₃-30ZnO-10 (Li₂O/Na₂O/K₂O/MgO/CaO/SrO/BaO) all in mol%. Scanning electron microscope (SEM) and Energy-dispersive X-ray spectroscopy (EDX) have characterized for H3 (K₂O...

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Main Authors: Kaky, Kawa M., Şakar, Erdem, Akbaba, Ugur, Kasapoglu, Ahmet Emre, Sayyed, Mohammed I., Gur, Emre, Baki, Sharudin Omar, Mahdi, Mohd Adzir
Format: Article
Language:English
Published: Elsevier 2019
Online Access:http://psasir.upm.edu.my/id/eprint/82770/1/X-ray%20photoelectron.pdf
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author Kaky, Kawa M.
Şakar, Erdem
Akbaba, Ugur
Kasapoglu, Ahmet Emre
Sayyed, Mohammed I.
Gur, Emre
Baki, Sharudin Omar
Mahdi, Mohd Adzir
author_facet Kaky, Kawa M.
Şakar, Erdem
Akbaba, Ugur
Kasapoglu, Ahmet Emre
Sayyed, Mohammed I.
Gur, Emre
Baki, Sharudin Omar
Mahdi, Mohd Adzir
author_sort Kaky, Kawa M.
collection UPM
description In the present work, seven glass samples have been prepared utilizing melt-quenching method with composition of 40B₂O₃-10SiO₂-10Al₂O₃-30ZnO-10 (Li₂O/Na₂O/K₂O/MgO/CaO/SrO/BaO) all in mol%. Scanning electron microscope (SEM) and Energy-dispersive X-ray spectroscopy (EDX) have characterized for H3 (K₂O) and H7 (BaO), to examine the structural properties. X-ray Photoelectron Spectroscopy (XPS) has shown that the boron (B) element composition is highest after oxygen elements in all the glasses. It has been also observed that incorporation of potassium (K) and strontium (Sr) elements are maximum compared to the other doped elements into the glass. Further, the photon shielding for H1-H7 samples were also studied. We calculated the mass attenuation coefficients (μ/ρ) for the present samples at some energies between 0.015 and 10 MeV. The results revealed that H7 (BaO) sample owns the highest μ/ρ values followed by H6 (SrO) while H1 (Li₂O) has the lowest μ/ρ. Moreover, H7 and H6 samples have higher effective atomic number than the rest of glasses. H7 sample has excellent shielding properties when compared with the other glasses. We found that the composition of the sample affects the attenuation of the glasses and high attenuation can be achieved when we used heavy metal oxides (such as BaO).
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spelling upm.eprints-827702020-10-16T20:05:10Z http://psasir.upm.edu.my/id/eprint/82770/ X-ray photoelectron spectroscopy (XPS) and gamma-ray shielding investigation of boro-silicate glasses contained alkali/alkaline modifier Kaky, Kawa M. Şakar, Erdem Akbaba, Ugur Kasapoglu, Ahmet Emre Sayyed, Mohammed I. Gur, Emre Baki, Sharudin Omar Mahdi, Mohd Adzir In the present work, seven glass samples have been prepared utilizing melt-quenching method with composition of 40B₂O₃-10SiO₂-10Al₂O₃-30ZnO-10 (Li₂O/Na₂O/K₂O/MgO/CaO/SrO/BaO) all in mol%. Scanning electron microscope (SEM) and Energy-dispersive X-ray spectroscopy (EDX) have characterized for H3 (K₂O) and H7 (BaO), to examine the structural properties. X-ray Photoelectron Spectroscopy (XPS) has shown that the boron (B) element composition is highest after oxygen elements in all the glasses. It has been also observed that incorporation of potassium (K) and strontium (Sr) elements are maximum compared to the other doped elements into the glass. Further, the photon shielding for H1-H7 samples were also studied. We calculated the mass attenuation coefficients (μ/ρ) for the present samples at some energies between 0.015 and 10 MeV. The results revealed that H7 (BaO) sample owns the highest μ/ρ values followed by H6 (SrO) while H1 (Li₂O) has the lowest μ/ρ. Moreover, H7 and H6 samples have higher effective atomic number than the rest of glasses. H7 sample has excellent shielding properties when compared with the other glasses. We found that the composition of the sample affects the attenuation of the glasses and high attenuation can be achieved when we used heavy metal oxides (such as BaO). Elsevier 2019 Article PeerReviewed text en http://psasir.upm.edu.my/id/eprint/82770/1/X-ray%20photoelectron.pdf Kaky, Kawa M. and Şakar, Erdem and Akbaba, Ugur and Kasapoglu, Ahmet Emre and Sayyed, Mohammed I. and Gur, Emre and Baki, Sharudin Omar and Mahdi, Mohd Adzir (2019) X-ray photoelectron spectroscopy (XPS) and gamma-ray shielding investigation of boro-silicate glasses contained alkali/alkaline modifier. Results in Physics, 14. pp. 1-8. ISSN 2211-3797 https://www.sciencedirect.com/science/article/pii/S221137971931561X#! 10.1016/j.rinp.2019.102438
spellingShingle Kaky, Kawa M.
Şakar, Erdem
Akbaba, Ugur
Kasapoglu, Ahmet Emre
Sayyed, Mohammed I.
Gur, Emre
Baki, Sharudin Omar
Mahdi, Mohd Adzir
X-ray photoelectron spectroscopy (XPS) and gamma-ray shielding investigation of boro-silicate glasses contained alkali/alkaline modifier
title X-ray photoelectron spectroscopy (XPS) and gamma-ray shielding investigation of boro-silicate glasses contained alkali/alkaline modifier
title_full X-ray photoelectron spectroscopy (XPS) and gamma-ray shielding investigation of boro-silicate glasses contained alkali/alkaline modifier
title_fullStr X-ray photoelectron spectroscopy (XPS) and gamma-ray shielding investigation of boro-silicate glasses contained alkali/alkaline modifier
title_full_unstemmed X-ray photoelectron spectroscopy (XPS) and gamma-ray shielding investigation of boro-silicate glasses contained alkali/alkaline modifier
title_short X-ray photoelectron spectroscopy (XPS) and gamma-ray shielding investigation of boro-silicate glasses contained alkali/alkaline modifier
title_sort x ray photoelectron spectroscopy xps and gamma ray shielding investigation of boro silicate glasses contained alkali alkaline modifier
url http://psasir.upm.edu.my/id/eprint/82770/1/X-ray%20photoelectron.pdf
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